3.
    发明专利
    未知

    公开(公告)号:DE59703819D1

    公开(公告)日:2001-07-19

    申请号:DE59703819

    申请日:1997-09-12

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/05000 Sec. 371 Date Mar. 25, 1999 Sec. 102(e) Date Mar. 25, 1999 PCT Filed Sep. 12, 1997 PCT Pub. No. WO98/13412 PCT Pub. Date Apr. 2, 1998A process for preparing thermoplastics or polymer blends comprising (A) from 5 to 95% of a water-moist elastomer component containing up to 60% of residual water, (B) from 5 to 95% of a thermoplastic polymer, (C) from 0 to 95% of a further polymer, and (D) from 0 to 70% of additives, said process comprising mixing the components A to D in an extruder with mechanical dewatering of component A, wherein the extruder has at least two rotating screws and, in the conveying direction, is essentially composed of a metering section into which component A is fed, a squeeze section which serves for dewatering component A and contains a retarding element and an associated dewatering orifice which is present upstream of the retarding element by a distance corresponding to at least one screw diameter, a feed section in which the thermoplastic polymer B is introduced as a melt into the extruder, a plastication section with mixing or kneading elements, a devolatilization section with an orifice and in which the remaining water is removed as steam, and a discharge zone.

    5.
    发明专利
    未知

    公开(公告)号:BR9712121A

    公开(公告)日:1999-08-31

    申请号:BR9712121

    申请日:1997-09-12

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/05000 Sec. 371 Date Mar. 25, 1999 Sec. 102(e) Date Mar. 25, 1999 PCT Filed Sep. 12, 1997 PCT Pub. No. WO98/13412 PCT Pub. Date Apr. 2, 1998A process for preparing thermoplastics or polymer blends comprising (A) from 5 to 95% of a water-moist elastomer component containing up to 60% of residual water, (B) from 5 to 95% of a thermoplastic polymer, (C) from 0 to 95% of a further polymer, and (D) from 0 to 70% of additives, said process comprising mixing the components A to D in an extruder with mechanical dewatering of component A, wherein the extruder has at least two rotating screws and, in the conveying direction, is essentially composed of a metering section into which component A is fed, a squeeze section which serves for dewatering component A and contains a retarding element and an associated dewatering orifice which is present upstream of the retarding element by a distance corresponding to at least one screw diameter, a feed section in which the thermoplastic polymer B is introduced as a melt into the extruder, a plastication section with mixing or kneading elements, a devolatilization section with an orifice and in which the remaining water is removed as steam, and a discharge zone.

    PROCESS FOR PRODUCING THERMOPLASTICS

    公开(公告)号:CA2266420A1

    公开(公告)日:1998-04-02

    申请号:CA2266420

    申请日:1997-09-12

    Applicant: BASF AG

    Abstract: A process is disclosed for producing thermoplastics modified to be impactresistant or polymer blends containing such modified thermoplastics. The thermoplastics or polymer blends contain: (A) 5 to 95 wt % of at least one water-wet elastomer component A which contains up to 60 wt % residual water; (B) 5 to 95 wt % of at least one thermoplastic polymer B; (C) 0 to 95 wt % of at least another polymer C; and (D) 0 to 70 wt % additives D. The elastomer component A is mixed with the thermoplastic polymer B, if available with the other polymer C and if available with the additives D in a screw-machine while mechanically dewatering the elastomer component A. The process is characterised in that components A, B, C and D are supplied to an extruder with at least two screws that rotate in the same or opposite directions and have a diameter Dscrew. Seen in the feeding direction (downstream), the extruder substantially consists of at least one dosing section in which the elastomer component A is supplied to the extruder by a dosing device; at least one squeezing section for dewatering the elastomer component A having at least one pressure element and at least a corresponding dewatering opening located upstream of the (first) pressure element at a distance therefrom equal to at least one screw diameter Dscrew; at least one feeding section in which the thermoplastic polymer B is fed into the extruder as a molten mass; at least one plasticising section fitted with mixing and/or kneading elements; at least one degassing section with at least one degassing hole in which the residual water is removed as steam; and an extraction zone. The water expelled through the dewatering openings is partially or totally present in the liquid phase, and components C and/or are supplied together or separately, either together with components A and/or B or separately from A and B in one or more of the above-mentioned extruder sections.

    PROCESS FOR PRODUCING THERMOPLASTICS

    公开(公告)号:CA2266420C

    公开(公告)日:2003-12-02

    申请号:CA2266420

    申请日:1997-09-12

    Applicant: BASF AG

    Abstract: A process is disclosed for producing thermoplastics modified to be impact-resistant or polymer blends containing such modified thermoplastics, The thermoplastics or polymer blends contain: (A) 5 to 95 wt % of at least one water-wet elastomer component A which contains up to 60 wt % residual water; (B) 5 to 95 wt % of at least one thermoplastic polymer B; (C) 0 to 95 wt % of at least another polymer C; and (D) 0 to 70 wt % additives D. The elastomer component A is mixed with the thermoplastic polymer B, if available with the other polymer C and if available with the additives D in a screw-machine while mechanically dewatering the elastomer component A. The process is characterised in that components A, B, C and D are supplied to an extruder with at least two screws that rotate in the same or opposite directions and have a diameter D screw. Seen in the feeding direction (downstream), the extruder substantially consists of at least one dosing section in which the elastomer component A is supplied to the extruder by a dosing device; at least one squeezing section for dewatering the elastomer component A having at least one pressure element and at least a corresponding dewatering opening located upstream of the (first) pressure element at a distance therefrom equal to at least one screw diameter D screw; at least one feeding section in which the thermoplastic polymer B is fed into the extruder as a molten mass; at least one plasticising section fitted with mixing and/or kneading elements; at least one degassing section with at least one degassing hole in which the residual water is removed as steam; and an extraction zone. The water expelled through the dewatering openings is partially or totally present in the liquid phase, and components C and/or are supplied together or separately, either together with components A and/or B or separately from A and B in one or more of the above-mentioned extruder sections.

    8.
    发明专利
    未知

    公开(公告)号:ES2117890T3

    公开(公告)日:1998-08-16

    申请号:ES96104389

    申请日:1996-03-20

    Applicant: BASF AG

    Abstract: The prepn. of deep draw-modified thermoplastics (T) is by mechanical dewatering of a wet elastomer component (A) contg. up to 50 wt.% residual water and mixing dewatered (A) with a thermoplastic polymer (B) in a screw - by adding (A) to a twin-screw extruder with rotating screws. This extruder contains the following sections (in the direction of flow) : (1) feed for adding (A) to the extruder ; (2) at least one crusher for dewatering (A) that contains one or more barriers each with an opening through which at least some of the water passes as a liq. ; (3) at least one section to which molten (B) is added ; (4) one or more sections with mixing, kneading and / or plasticising devices ; (5) at least one degassing section with one or more gas outlets through which the rest of the water is removed as steam ; and (6) an exit zone. Deep draw-modified moulding materials prepd. by this process are also claimed.

    10.
    发明专利
    未知

    公开(公告)号:ES2104481T3

    公开(公告)日:1997-10-01

    申请号:ES96104464

    申请日:1996-03-21

    Applicant: BASF AG

    Abstract: A process is claimed for the prodn. of impact-modified thermoplastics (I) by (a) mechanical dehydration of a moist elastomer component (A) contg. up to 60 wt% residual water and (b) mixing the dried elastomer obtd. (A') with a thermoplastic polymer (B) in a screw machine. The process is carried out in a twin screw extruder with synchronous double-threaded screws and with the following sequence in the direction of feed: (1) a metering section for introducing component (A) into the extruder via a metering device, (2) squeezing section(s) for removing the water, with accumulator element(s) and associated water outlet(s), (3) section(s) fitted with a feeder screw or with mixing, kneading and/or other plasticising elements, (4) section(s) in which polymer (B) is added as a melt, (5) section(s) fitted with mixing, kneading and/or other plasticising elements, (6) degassing section(s) with gas outlets, in which residual water is removed as vapour, and (7) a discharge zone. The water emerging from the outlets in section (2) is partly or completely in the liq. phase, and the extruder is operated at a screw speed of 50-600 r.p.m., with a mean shear rate of 20-240 s . Also claimed are impact-modified thermoplastic moulding materials (I) obtd. by this process.

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