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    Method for producing polyvinyl alcohol-polyether-graft copolymer through extrusion
    3.
    发明专利
    Method for producing polyvinyl alcohol-polyether-graft copolymer through extrusion 审中-公开
    通过挤出生产聚乙烯醇 - 聚醚 - 共聚物的方法

    公开(公告)号：JP2006176777A

    公开(公告)日：2006-07-06

    申请号：JP2005368439

    申请日：2005-12-21

    Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフトBASF Aktiengesellschaft

    Inventor： GUENTHERBERG NORBERT ,  SEEBECK TANJA ,  LANGE RONALD FRANS MARIA

    IPC: C08F8/12 ,  C08F283/06

    CPC classification number: C08F8/12 ,  B29C47/00 ,  C08F283/06 ,  C08F218/08

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a polyvinyl alcohol-polyether-graft copolymer, by which the product is obtained in a form capable of being advantageously used by an injection molding method or a film extrusion method, and by which the graft copolymer containing the vinyl alcohol in a copolymerized form and having a surely adjustable hydrolysis degree can simply be produced without accompanying a complicated process, especially a steam distillation process and a spray drying process.
    SOLUTION: This method for producing the graft copolymer (P2) having repeating units originated from the vinyl alcohol and having polyether groups comprises reacting a graft copolymer (P1) having repeating units originated from a vinyl alcohol ester and having polyether groups with water and/or at least one 1 to 6C alkanol in the presence of a catalyst in an extruder. Namely, the method for preparing the graft copolymer having repeating units originated from the vinyl alcohol and having the polyether groups comprises reacting the corresponding graft copolymer based on the vinyl alcohol ester with the water and/or at least one 1 to 6C alkanol in the presence of a catalyst in an extruder.
    COPYRIGHT: (C)2006,JPO&NCIPI

    Abstract translation: 待解决的问题：提供一种生产聚乙烯醇 - 聚醚 - 接枝共聚物的方法，通过该方法可以通过注射成型法或薄膜挤出法有利地使用该产品，并且通过 含有共聚形式的乙烯醇并具有可确定的水解度的接枝共聚物可以简单地制备而不伴随复杂的方法，特别是蒸汽蒸馏法和喷雾干燥法。 解决方案：用于制备具有源自乙烯醇并具有聚醚基团的重复单元的接枝共聚物（P2）的方法包括使具有源自乙烯醇酯的具有聚醚基团的重复单元的接枝共聚物（P1）与水 和/或至少一种1至6C链烷醇在催化剂存在下在挤出机中进行。 也就是说，制备具有源自乙烯醇并具有聚醚基团的重复单元的接枝共聚物的方法包括使相应的乙烯醇酯接枝共聚物与水和/或至少一种1至6C链烷醇在存在下反应， 的挤出机中的催化剂。 版权所有（C）2006，JPO＆NCIPI

    5.
    发明专利
    未知

    公开(公告)号：AT361340T

    公开(公告)日：2007-05-15

    申请号：AT04820435

    申请日：2004-12-14

    Applicant: BASF AG

    Inventor： STORK MARTIN ,  WEBER MARTIN ,  GOTTSCHALK AXEL ,  RIECHERS SVEN ,  GUENTHERBERG NORBERT ,  FISCHER WOLFGANG ,  LEBER LUDGER ,  ITTEMANN PETER ,  JUENGLING STEPHAN

    IPC: C08F257/02 ,  C08F279/02 ,  C08F285/00 ,  C08L25/12 ,  C08L33/12 ,  C08L35/06 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02

    Abstract: The present invention relates to thermoplastic molding compositions comprising a mixture of (A) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a methyl methacrylate polymer, (B) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a copolymer obtainable by polymerizing a styrenic monomer and a vinyl cyanide, and (C) from 1 to 40% by weight, based on the sum of components (A), (B) and (C), of a graft copolymer obtainable from (C1) from 60 to 90% by weight, based on (C), of a core obtainable by polymerizing a 1,3-diene and a styrenic monomer, (C2) from 5 to 20% by weight, based on (C), of a first graft shell, and (C3) from 5 to 20% by weight, based on (C), of a second graft shell composed of an alkyl (meth)acrylate polymer, with the proviso that the ratio of (C2) to (C3) is in the range from 2:1 to 1:2.

    Preparation of hardly modified, thermoplastic molded mass comprises preparing thermoplastic solution and rubber dispersion; mixing the solution and dispersion; and evaporating e.g. water and agglomerating e.g. rubber
    6.
    发明专利
    Preparation of hardly modified, thermoplastic molded mass comprises preparing thermoplastic solution and rubber dispersion; mixing the solution and dispersion; and evaporating e.g. water and agglomerating e.g. rubber 未知

    公开(公告)号：DE102005018701A1

    公开(公告)日：2006-10-26

    申请号：DE102005018701

    申请日：2005-04-21

    Applicant: BASF AG

    Inventor： GUENTHERBERG NORBERT ,  CZAUDERNA BERNHARD ,  SAUER MICHAEL ,  BARDON RAINER

    IPC: C08L51/04 ,  C08J3/03 ,  C08J5/02 ,  C08L51/06

    Abstract: Preparation of hardly modified, thermoplastic molded mass comprises preparing a thermoplastic solution through mass-, solution-, emulsion- or suspension polymerization; preparing a rubber dispersion through emulsion polymerization; mixing the thermoplastic solution and the rubber dispersion; and evaporating water and organic solution, emulsion-, suspension and dispersion agent and agglomerating the rubber, and melt mixture of thermoplast and rubber. Preparation of hardly modified, thermoplastic molded mass comprises preparing a thermoplastic solution through mass-, solution-, emulsion- or suspension polymerization; preparing a rubber dispersion through emulsion polymerization; mixing the thermoplastic solution and the rubber dispersion; and evaporating water and organic solution, emulsion-, suspension and dispersion agent and agglomerating the rubber, and melt mixture of thermoplast and rubber (where the mixing and the evaporating steps are carried out simultaneously together or separately in two successive procedure steps; and the evaporation step is carried out in an evaporator or deaerator). An independent claim is included for a hardly modified, thermoplastic molded mass produced by the process.

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