Abstract:
PROBLEM TO BE SOLVED: To produce an impact-resistant thermoplastic resin composed of a wet elastomer component and a fragile thermoplastic polymer in an industrially simple manner by one treatment process if possible. SOLUTION: An elastomer component A is supplied to a twin-screw extruder formed from a distribution section, a crushing section, a, section supplying a thermoplastic polymer B to the extruder, a section equipped with a mixing element, a kneading element and/or a separate plasticizing element, a degassing section and a feed-out zone in a feed direction and equipped with screws rotated in the same way and the water discharged from a dehydration opening is allowed to be present as a liquid phase partially or wholly. Therefore, the residual water contained in rubber partially dehydrated at first is already removed as water in the first crushing section and the feed amt. of rubber is 3-8wt.% of the amt. of the wet rubber in the first crushing section and below 1wt.% in a second crushing section.
Abstract:
PROBLEM TO BE SOLVED: To provide a method for producing a polyvinyl alcohol-polyether-graft copolymer, by which the product is obtained in a form capable of being advantageously used by an injection molding method or a film extrusion method, and by which the graft copolymer containing the vinyl alcohol in a copolymerized form and having a surely adjustable hydrolysis degree can simply be produced without accompanying a complicated process, especially a steam distillation process and a spray drying process. SOLUTION: This method for producing the graft copolymer (P2) having repeating units originated from the vinyl alcohol and having polyether groups comprises reacting a graft copolymer (P1) having repeating units originated from a vinyl alcohol ester and having polyether groups with water and/or at least one 1 to 6C alkanol in the presence of a catalyst in an extruder. Namely, the method for preparing the graft copolymer having repeating units originated from the vinyl alcohol and having the polyether groups comprises reacting the corresponding graft copolymer based on the vinyl alcohol ester with the water and/or at least one 1 to 6C alkanol in the presence of a catalyst in an extruder. COPYRIGHT: (C)2006,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To manufacture impact resistant thermoplastic in a single step as far as possible by supplying elastomer composition containing residual moisture up to specific wt.% to a biaxial extruder having double threaded screws rotating in the same direction so that the moisture from a dehydration part partly or entirely becomes a liquid state. SOLUTION: The zones of a biaxial extruder are arranged as follows toward the axial direction of the extruder. The zones include the metering supply zone 2 of elastomer composition A containing the residual moisture up to 60wt.%, first compression zone 3, second compression zone 3', intermediate site feeding screw zone 0, zone 4 supplied with melted material of thermoplastic B, first plasticizing zone 5, second plasticizing zone 5', first deaerating zone 6, second deaerating zone 6' and discharge zone 7. The two screws of the extruder are formed as deeply engraved threads and double threads. The extruder is operated by the number of revolutions of the screw from 50 to 600min , and shearing speed of 20 to 240s .
Abstract:
The present invention relates to thermoplastic molding compositions comprising a mixture of (A) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a methyl methacrylate polymer, (B) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a copolymer obtainable by polymerizing a styrenic monomer and a vinyl cyanide, and (C) from 1 to 40% by weight, based on the sum of components (A), (B) and (C), of a graft copolymer obtainable from (C1) from 60 to 90% by weight, based on (C), of a core obtainable by polymerizing a 1,3-diene and a styrenic monomer, (C2) from 5 to 20% by weight, based on (C), of a first graft shell, and (C3) from 5 to 20% by weight, based on (C), of a second graft shell composed of an alkyl (meth)acrylate polymer, with the proviso that the ratio of (C2) to (C3) is in the range from 2:1 to 1:2.
Abstract:
Preparation of hardly modified, thermoplastic molded mass comprises preparing a thermoplastic solution through mass-, solution-, emulsion- or suspension polymerization; preparing a rubber dispersion through emulsion polymerization; mixing the thermoplastic solution and the rubber dispersion; and evaporating water and organic solution, emulsion-, suspension and dispersion agent and agglomerating the rubber, and melt mixture of thermoplast and rubber. Preparation of hardly modified, thermoplastic molded mass comprises preparing a thermoplastic solution through mass-, solution-, emulsion- or suspension polymerization; preparing a rubber dispersion through emulsion polymerization; mixing the thermoplastic solution and the rubber dispersion; and evaporating water and organic solution, emulsion-, suspension and dispersion agent and agglomerating the rubber, and melt mixture of thermoplast and rubber (where the mixing and the evaporating steps are carried out simultaneously together or separately in two successive procedure steps; and the evaporation step is carried out in an evaporator or deaerator). An independent claim is included for a hardly modified, thermoplastic molded mass produced by the process.
Abstract:
The present invention relates to thermoplastic molding compositions comprising a mixture of (A) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a methyl methacrylate polymer, (B) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a copolymer obtainable by polymerizing a styrenic monomer and a vinyl cyanide, and (C) from 1 to 40% by weight, based on the sum of components (A), (B) and (C), of a graft copolymer obtainable from (C1) from 60 to 90% by weight, based on (C), of a core obtainable by polymerizing a 1,3-diene and a styrenic monomer, (C2) from 5 to 20% by weight, based on (C), of a first graft shell, and (C3) from 5 to 20% by weight, based on (C), of a second graft shell composed of an alkyl (meth)acrylate polymer, with the proviso that the ratio of (C2) to (C3) is in the range from 2:1 to 1:2.
Abstract:
A process for the production of impact-resistant plastics involves: (a) making crosslinked rubber particles from a monomer mixture (1) containing at least 50 wt.% conjugated diene; (b) adding the rubber particles to another monomer mixture (2) containing at least 85 (preferably at least 90, most preferably at least 98) wt.% styrene and (c) polymerizing mixture 2. An Independent claim is also included for impact resistant plastics obtained by this process.
Abstract:
Particulate rubber-elastic graft copolymers (I), suitable for the qualitative improvement of macro-mol. base materials (B), comprise (a) a graft core of rubber-elastic polymer Pk with an average particle dia. of 1-100 microns, and (b) one or more shells, with the outer shell consisting of a polymer (Pa) which is entirely or partly compatible with material (B). Also claimed is (i) a process for the prodn. of (I); (ii) moulding materials consisting of base materials (B) contg. polymers (I); (iii) moulded prods. obtd. from materials (ii).