公开(公告)号：DE1619371A1

公开(公告)日：1970-07-30

申请号：DE1619371

申请日：1967-07-06

Applicant: BASF AG

Inventor： DAEUBLE DR MANFRED ,  HIRT DR REINHARD ,  WELZEL DR GERHARD ,  WITSCH DR HEINZ-GUENTER ,  DIECK KLAUS

IPC: D04H1/488 ,  D04H1/587 ,  D04H1/645 ,  D06P3/00

公开(公告)号：DE1619342A1

公开(公告)日：1970-10-01

申请号：DE1619342

申请日：1966-07-02

Applicant: BASF AG

Inventor： RICHTER DR PAUL ,  WEIGOLD SIEGFRIED ,  DAEUBLE DR MANFRED ,  WUERZ DR ALBRECHT

IPC: D06P3/82

公开(公告)号：DE1619367A1

公开(公告)日：1969-07-03

申请号：DE1619367

申请日：1967-05-20

Applicant: BASF AG

Inventor： LUEBCKE DR ENNO ,  KAUFMANN DR OTTO ,  WITSCH DR HEINZ-GUENTER ,  BAYEW DR DIMITER ,  DAEUBLE DR MANFRED

IPC: C09B45/04 ,  C09B45/14 ,  C09B67/24 ,  C09B67/26 ,  D06P3/04 ,  D06P3/24 ,  D06P

公开(公告)号：DE1619357A1

公开(公告)日：1970-08-27

申请号：DE1619357

申请日：1966-12-29

Applicant: BASF AG

Inventor： KAUFMANN DR OTTO ,  PFITZNER DR HELMUT ,  LUDSTECK DR DIETER ,  WITSCH DR HEINZ-GUENTER ,  DAEUBLE DR MANFRED

IPC: C09B45/04 ,  C09B45/14 ,  C09B67/24 ,  C09B67/26 ,  D06P3/04 ,  D06P3/24 ,  D06P

公开(公告)号：DE1280209B

公开(公告)日：1968-10-17

申请号：DEB0078394

申请日：1964-09-04

Applicant: BASF AG

Inventor： DAEUBLE DR MANFRED ,  MERTENS DR HEINRICH ,  SPAETH DR AUGUST ,  THEILIG DIETMAR

IPC: D06P1/613 ,  D06P3/16

公开(公告)号：DE1265699B

公开(公告)日：1968-04-11

申请号：DEB0055451

申请日：1959-11-07

Applicant: BASF AG

Inventor： ENDER DR WILLIBALD ,  WUERZ DR ALBRECHT ,  SCHOENPFLUG DR ERNST ,  DAEUBLE DR MANFRED ,  MARKGRAF OTTO ,  BLESER FRANZ ERICH

IPC: D06P1/613 ,  D06P1/651 ,  D06P3/30 ,  D06P3/32

公开(公告)号：DE1248608B

公开(公告)日：1967-08-31

申请号：DEB0069815

申请日：1962-11-30

Applicant: BASF AG

Inventor： BONITZ DR ECKHARD ,  DAEUBLE DR MANFRED

IPC: C08K5/00 ,  D06P1/44 ,  D06P1/52 ,  D06P1/651 ,  D06P3/79 ,  D06P5/22

Abstract: Moulded articles of polyolefins are dyed or printed with water-insoluble dyes that are soluble in organic solvents from aqueous dispersion or organic solution with either simultaneous or prior treatment with a dispersion or solution of a silicon hydrocarbon compound, an alkysiloxane, arylsiloxane, alkylarylsiloxane, alkylpolysiloxane, arylpolysiloxane, alkylarylpolysiloxane or an ester or polyester of silicic acid which silicon compounds are soluble in hydrocarbons. In Example 6 moulded articles of polyethylene are dyed with an aqueous liquor containing polydimethylsiloxane, a dispersed anthraquinone dye and surfactants and in Example 7 the same articles are printed with a solution in methylene chloride of hexyl-azo-naphthalene, tetraethylsilicate, nickel - II - oleate, triethanolamine and a linear polymer from ethyltriethoxysilane (80%) and phenyltriethoxysilane (10%).ALSO:Polyolefin materials are dyed or printed with water-insoluble dyes, which are soluble in organic solvents, from aqueous dispersion or organic solution in a process wherein the material is pretreated with a dispersion or solution of a silicon hydrocarbon compound, an alkylsiloxane, arylsiloxane, alkylarylsiloxane, alkylpolysiloxane, arylpolysiloxane, alkylarylpolysiloxane or an ester or polyester of silicic acid which silicon compounds are soluble in hydrocarbons, or wherein the dyeing or printing is carried out with the co-employment of any of the said silicon compounds. The so-treated material may then be subjected to a heat treatment. The polysiloxanes may be formed in situ with the help of catalysts, e.g. acids, bases or metal salts. The preferred polysiloxanes cross-link when the dye is fixed, again preferably in the presence of metal salts. Examples are given.