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公开(公告)号：WO03106544A8
公开(公告)日：2005-01-06
申请号：PCT/EP0305952
申请日：2003-06-06
Applicant: BASF AG , DIETZEN FRANZ-JOSEF , EHRMANN GERD , SCHMIED BERNHARD , LAUN MARTIN , HAHN KLAUS , RUCH JOACHIM , ALLMENDINGER MARKUS , HOLOCH JAN , DATKO ACHIM
Inventor： DIETZEN FRANZ-JOSEF , EHRMANN GERD , SCHMIED BERNHARD , LAUN MARTIN , HAHN KLAUS , RUCH JOACHIM , ALLMENDINGER MARKUS , HOLOCH JAN , DATKO ACHIM
CPC classification number: C08J9/16 , B29C44/3461 , C08J2325/04
Abstract: The invention relates to a method for producing expandable polystyrene with a molecular weight Mw in excess of 170,000 g/mol. According to the invention, a styrene polymer melt containing an expanding agent and having a temperature of at least 120 DEG C is passed through a spinneret comprising bores, whose diameter at the spinneret exit measures a maximum 1.5 mm, and is then granulated. The invention also relates to expandable styrene polymers (EPS) with a molecular weight Mw of more than 170,000 g/mol and between 0.05 and 1.5 wt. % inherent moisture.
Abstract translation: 一种用于在具有分子量Mw超过17万克/摩尔，在那里它促进具有至少120℃的温度的含热发泡剂的苯乙烯聚合物熔体穿过模具板的孔的直径是在喷嘴出口处至多1.5mm膨胀苯乙烯聚合物的制备过程中， 然后造粒。，以及具有分子量Mw超过17万克/摩尔的与水内0.05〜1.5重量％的可膨胀苯乙烯聚合物（EPS）。
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公开(公告)号：WO03025051A2
公开(公告)日：2003-03-27
申请号：PCT/EP0209924
申请日：2002-09-05
Applicant: BASF AG , DATKO ACHIM , HAHN KLAUS , LARBIG HARALD , BATSCHEIDER KARL-HEINZ
Inventor： DATKO ACHIM , HAHN KLAUS , LARBIG HARALD , BATSCHEIDER KARL-HEINZ
CPC classification number: C08J9/0061 , C08J9/20 , C08J2203/14 , C08J2325/06 , C08J2491/00 , C08K5/01 , C08L25/06
Abstract: The invention relates to a method for the production of bead-shaped expanded polystyrene by suspension polymerisation of styrol in the presence of 1 to 5 wt. % of a hydrocarbon with 4 to 6 C atoms and 0.5 to 3.5 wt. % of a saturated aliphatic hydrocarbon with a boiling point above 70°C, but in the absence of a chain initiator, giving rise to a reduction in the molecular weight of the polystyrene.
Abstract translation: 本发明涉及一种通过在1存在下的苯乙烯的悬浮聚合perlförmigem膨胀聚苯乙烯的制备方法，以5重量碳原子数4〜6的烃基的％，且o为5至3.5重量的饱和脂肪族的％ 沸点高于70℃的烃，但在不存在链转移剂的情况下，其引起聚苯乙烯的分子碳水化合物的减少。
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公开(公告)号：AT386059T
公开(公告)日：2008-03-15
申请号：AT01130035
申请日：2001-12-18
Applicant: BASF AG
Inventor： DATKO ACHIM , DODEL PETER , HAHN KLAUS
Abstract: Preparation of styrene polymers containing a propellant by polymerisation of styrene with comonomers, in aqueous suspension, with addition, (at start or during polymerisation) of amphiphilic organic emulsifying agent containing hydrophilic and hydrophobic groups, or a polymer carrying a polar group, (miscible in water), so the suspended styrene droplets contain finely distributed water particles.
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公开(公告)号：MXPA06014440A
公开(公告)日：2007-03-21
申请号：MXPA06014440
申请日：2005-06-09
Applicant: BASF AG
Inventor： HAHN KLAUS , DATKO ACHIM , ALLMENDINGER MARKUS
Abstract: La invencion se refiere a materiales de espuma de particula de polimero de estireno teniendo una densidad de menos de 25 g/l, que tienen una conductividad termica ?, determinada a 10 degree C de conformidad con DIN 52612, bajo 32 mW/m*K, y a metodos para la produccion de los mismos.
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公开(公告)号：BR0311480A
公开(公告)日：2005-03-15
申请号：BR0311480
申请日：2003-06-06
Applicant: BASF AG
Inventor： DIETZEN FRANZ-JOSEF , EHRMANN GERD , SCHMIED BERNHARD , LAUN MARTIN , HAHN KLAUS , RUCH JOACHIM , ALLMENDINGER MARKUS , HOLOCH JAN , DATKO ACHIM
IPC: C08J9/00 , B29B9/10 , B29B11/10 , B29C44/34 , B29C48/345 , B29K25/00 , B29K105/04 , C08J9/16
Abstract: A process for the preparation of expandable styrene polymers having a molecular weight Mw of greater than 170,000 g/mol, which comprises conveying a blowing agent-containing styrene polymer melt having a temperature of at least 120° C. through a die plate with holes whose diameter at the die exit is at most 1.5 mm, and subsequently granulating the extrudate, and expandable styrene polymers (EPS) having a molecular weight Mw of more than 170,000 g/mol with 0.05 to 1.5% by weight of internal water.
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Patent Agency Ranking
公开(公告)号：BRPI0512006A
公开(公告)日：2008-02-06
申请号：BRPI0512006
申请日：2005-06-09
Applicant: BASF AG
Inventor： DATKO ACHIM , HAHN KLAUS , ALLMENDINGER MARKUS
Abstract: Expanded styrene polymers which have a density of less than 25 g/l and a thermal conductivity λ, determined at 10° C. in accordance with DIN 52612, of less than 32 mW/m*K, and also a process for producing them.
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公开(公告)号：DE102004028768A1
公开(公告)日：2005-12-29
申请号：DE102004028768
申请日：2004-06-16
Applicant: BASF AG
Inventor： DATKO ACHIM , HAHN KLAUS , ALLMENDINGER MARKUS
Abstract: Expanded styrene polymers which have a density of less than 25 g/l and a thermal conductivity λ, determined at 10° C. in accordance with DIN 52612, of less than 32 mW/m*K, and also a process for producing them.
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公开(公告)号：AU2003236710A8
公开(公告)日：2003-12-31
申请号：AU2003236710
申请日：2003-06-06
Applicant: BASF AG
Inventor： LAUN MARTIN , DATKO ACHIM , SCHMIED BERNHARD , DIETZEN FRANZ-JOSEF , HAHN KLAUS , RUCH JOACHIM , ALLMENDINGER MARKUS , EHRMANN GERD
IPC: C08J9/00 , B29B9/10 , B29B11/10 , B29C44/34 , B29C48/345 , B29K25/00 , B29K105/04 , C08J9/16
Abstract: A process for the preparation of expandable styrene polymers having a molecular weight Mw of greater than 170,000 g/mol, which comprises conveying a blowing agent-containing styrene polymer melt having a temperature of at least 120° C. through a die plate with holes whose diameter at the die exit is at most 1.5 mm, and subsequently granulating the extrudate, and expandable styrene polymers (EPS) having a molecular weight Mw of more than 170,000 g/mol with 0.05 to 1.5% by weight of internal water.
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公开(公告)号：DE10150405A1
公开(公告)日：2003-04-17
申请号：DE10150405
申请日：2001-10-11
Applicant: BASF AG
Inventor： DATKO ACHIM , HAHN KLAUS , LEHNEN UWE-JOHANNES , ZOELLNER KNUT
Abstract: In the preparation of expanded polystyrene(EPS) in the presence of graphite particles and at least two peroxides which are broken down to radicals during the first stage of aqueous suspension polymerization, early polymerizate formation occurs and hinders a critical decrease in viscosity when the temperature rises, although the peroxides are not sufficiently stable unless cooled to room temperature. In the preparation of expanded polystyrene(EPS) in the presence of peroxides which are broken down to radicals during the first stage of aqueous suspension polymerization early polymerizate formation occurs and a critical decrease in viscosity when the temperature rises is hindered, although the peroxides are not sufficiently stable unless cooled to room temperature. The styrene mixture with up to 20% by wt. of comonomers in aqueous suspension is polymerized in the presence 0.1-25 wt.% of graphite particles and at least two organic peroxides breaking down at different temperatures.
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公开(公告)号：DE50302746D1
公开(公告)日：2006-05-11
申请号：DE50302746
申请日：2003-06-06
Applicant: BASF AG
Inventor： DIETZEN FRANZ-JOSEF , EHRMANN GERD , SCHMIED BERNHARD , LAUN MARTIN , HAHN KLAUS , RUCH JOACHIM , HOLOCH JAN , ALLMENDINGER MARKUS , DATKO ACHIM
IPC: C08J9/00 , C08J9/16 , B29B9/10 , B29B11/10 , B29C44/34 , B29C48/345 , B29K25/00 , B29K105/04
Abstract: A process for the preparation of expandable styrene polymers having a molecular weight Mw of greater than 170,000 g/mol, which comprises conveying a blowing agent-containing styrene polymer melt having a temperature of at least 120° C. through a die plate with holes whose diameter at the die exit is at most 1.5 mm, and subsequently granulating the extrudate, and expandable styrene polymers (EPS) having a molecular weight Mw of more than 170,000 g/mol with 0.05 to 1.5% by weight of internal water.
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