公开(公告)号：DE3866661D1

公开(公告)日：1992-01-16

申请号：DE3866661

申请日：1988-09-17

Applicant: BASF AG

Inventor： DECKER MARTIN DR ,  FRANZISCHKA WOLFGANG DR ,  WACHE HARRO DR ,  FRANZ DIETER DR

IPC: C07C329/00 ,  C07C329/02

Abstract: Prodn. of chlorothioformate esters of formula R-S-CO-Cl (I) is effected by reacting a thiol of formula R-SH (II) with CoCl2 in the presence of a catalytic amt. of a cyclic tert. amine (III), where R = an organic gp. (III) is a mono- or dialkylated 5- or 6-membered aromatic or nonaromatic heterocyclic cpd. contg. 1 or 2 tert. N atoms, where the alkyl gps. contain a total of 5-20 C atoms.

公开(公告)号：CH601275A5

公开(公告)日：1978-06-30

申请号：CH1202876

申请日：1976-09-22

Applicant: BASF AG

Inventor： GOETZ NORBERT DR ,  ZEEH BERND DR ,  DECKER MARTIN DR ,  HUPFER LEOPOLD DR ,  TOUSSAINT HERBERT DR

IPC: C07D295/02 ,  C07D295/023 ,  C07D295/03 ,  C07D295/033 ,  C07D265/30 ,  C07D295/00

Abstract: A new process for the manufacture of N-substituted tetrahydro-1,4-oxazines, also called morpholines, by conversion of N-substituted bis-(2-hydroxyalkyl)-amines in the presence of catalysts.

公开(公告)号：DE2140151A1

公开(公告)日：1973-02-22

申请号：DE2140151

申请日：1971-08-11

Applicant: BASF AG

Inventor： DECKER MARTIN DR ,  HOFFMANN HERWIG DR ,  MERKEL KARL DR ,  TOUSSAINT HERBERT DR

IPC: C07C255/45 ,  C07C121/42

公开(公告)号：DE1569676B1

公开(公告)日：1970-05-14

申请号：DEB0094526

申请日：1967-09-16

Applicant: BASF AG

Inventor： ROTERMUND GERHARD DR ,  PLATZ ROLF DR ,  DECKER MARTIN DR ,  STECHL HANNS-HELGE DR

IPC: C09B47/04 ,  C09B47/06 ,  C09B47/067

公开(公告)号：AT70049T

公开(公告)日：1991-12-15

申请号：AT88115298

申请日：1988-09-17

Applicant: BASF AG

Inventor： DECKER MARTIN DR ,  FRANZISCHKA WOLFGANG DR ,  WACHE HARRO DR ,  FRANZ DIETER DR

IPC: C07C329/00 ,  C07C329/02

公开(公告)号：DE3762044D1

公开(公告)日：1990-05-03

申请号：DE3762044

申请日：1987-07-02

Applicant: BASF AG

Inventor： DECKER MARTIN DR ,  NEUMAYR FRANZ DR

IPC: C07B61/00 ,  B01J31/00 ,  C07C51/00 ,  C07C51/60 ,  C07C53/50 ,  C07C67/00

Abstract: Chlorocarboxylic acid chlorides of the formula I where R is H or alkyl and n is an integer from 2 to 4, are prepared by reacting a lactone of the formula II with phosgene at elevated temperatures and in the presence of a quaternary ammonium salt.

公开(公告)号：DE3624258A1

公开(公告)日：1988-01-21

申请号：DE3624258

申请日：1986-07-18

Applicant: BASF AG

Inventor： DECKER MARTIN DR ,  NEUMAYR FRANZ DR

IPC: C07B61/00 ,  B01J31/00 ,  C07C51/00 ,  C07C51/60 ,  C07C53/50 ,  C07C67/00

Abstract: Chlorocarboxylic acid chlorides of the formula I where R is H or alkyl and n is an integer from 2 to 4, are prepared by reacting a lactone of the formula II with phosgene at elevated temperatures and in the presence of a quaternary ammonium salt.

公开(公告)号：DE3061369D1

公开(公告)日：1983-01-20

申请号：DE3061369

申请日：1980-12-05

Applicant: BASF AG

Inventor： DECKER MARTIN DR ,  MERKEL KARL DR ,  NEUMAYR FRANZ DR

IPC: C07C51/60

公开(公告)号：DE2217494A1

公开(公告)日：1973-10-25

申请号：DE2217494

申请日：1972-04-12

Applicant: BASF AG

Inventor： MERKEL KARL DR ,  HOFFMANN HERWIG DR ,  DECKER MARTIN DR

IPC: C07C121/34

Abstract: Catalyst produced by reacting methanolamine with ethylene oxide used in the prodn. of methoxypropionitrile from acrylonitrile and methanol according to the Parent patent was found equally effective with respect to reactions of acrylonitrile with mono- or polyhydric alcohols contg. >=2C atoms. The resulting title cpds can be used as inters. in the prodn. of acid amides, amines or diamines, isocyanates, etc. The catalyst is relatively inexpensive.

公开(公告)号：DE2136884A1

公开(公告)日：1973-02-01

申请号：DE2136884

申请日：1971-07-23

Applicant: BASF AG

Inventor： DECKER MARTIN DR ,  HOFFMANN HERWIG DR ,  MERKEL KARL DR ,  TOUSSAINT HERBERT DR ,  VOGES DIETER DR

IPC: C07C13/04 ,  C07C93/04

Abstract: Alkoxypropylamines are prepd. by the catalytic hydrogenation of an alkoxynitrile in the presence of free phosphoric acid (0.1-10 wt. %). The nitrile is obtd. by the reaction of an alcohol with acrylonitrile, in the presence of a base as catalyst. The base is finally neutralised. Pref. the alcohol is a divalent 2-8C straight-chain alcohol e.g. 1,6-hexane diol, and the base is neutralised by phosphoric acid. Hydrogenation occurs at pref. 60-90 degrees C, 100-300 atm. H2 in the presence of 0.2-1.0% H3PO4 to give an improved yield (>95%) and purity (>99%) of prod. The amines can be used as precursors in the mfre. of plastics.