公开(公告)号：JPH032757A

公开(公告)日：1991-01-09

申请号：JP4140090

申请日：1990-02-23

Applicant: BASF AG

Inventor： BUORUFUGANGU HIYUMAA ,  BUARUTAA DOBURAA ,  DEIITAA RITOMAN

IPC: G03F7/004 ,  G03F7/027 ,  G03F7/031 ,  G03F7/032

Abstract: PURPOSE: To obtain a photoresist and a relief printing plate having a sharp relief structure by incorporating 0.01-6wt.% of N-nitrosodiphenylamine and/or hydroquinone monomethyl ether into a photopolymerizable recording layer and specifying the weight ratio of these. CONSTITUTION: The photopolymerizable recording layer contains the following compds. (b41) and (b42) at least as a photosensitivity controlling agent (b4) by 0.01-6wt.% of the photopolymerizable recording layer. The compd. (b41) is selected from isoalloxazines and/or alloxazines, while the compd. (b42) is potassium salt of N-nitrocyclohexylhydroxylamine, N-nitrodiphenylamine and/or hydroquinone monomethyl ether. The weight ratio (b41):(b42) is specified to 1:2 to 1:1000. Thereby, a photoresist and a relief printing plate having a sharp relief structure can be obtd.

公开(公告)号：JPH02120864A

公开(公告)日：1990-05-08

申请号：JP23738389

申请日：1989-09-14

Applicant: BASF AG

Inventor： DEIITAA RITOMAN ,  HORUSUTO KOTSUHO

IPC: G03F7/004 ,  G03F7/027

Abstract: PURPOSE: To obtain a well-carved printing plate and a relief plate faithful to the original by incorporating specified lecithin as an auxiliary into a photopolymerizable recording layer by 0.1-10wt.% of the amt. of the layer. CONSTITUTION: This recording material has a photopolymerizable recording layer consisting of a binder, a polymn. initiator, a photopolymerizable olefinically unsatd. compd. compatible with the binder and/or photopolymerizable olefinically unsatd. residues bonding to the polymer binder as side chain groups and/or terminal groups and an auxiliary. One or more kinds of lecithins represented by formula I or II are used as the auxiliary by 0.1-10wt.% of the amt. of the recording layer. In the formulae I, II, each of R and R is 11-18C alkyl or 11-18C alkenyl but at least one of them is alkenyl. An especially superior fine relief structure faithful to the original is obtd.

公开(公告)号：JPH02178302A

公开(公告)日：1990-07-11

申请号：JP28508089

申请日：1989-11-02

Applicant: BASF AG

Inventor： DEIITAA RITOMAN ,  TOOMASU TERUZAA ,  HORUSUTO KOTSUHO ,  BUORUFUGANGU HIYUMAA ,  MARUTEIN MAISUTAA

IPC: G03F7/027 ,  C08F2/46 ,  C08F2/48 ,  C08F2/50 ,  G03F7/00 ,  G03F7/031 ,  G03F7/032

公开(公告)号：JPH028851A

公开(公告)日：1990-01-12

申请号：JP6400289

申请日：1989-03-17

Applicant: BASF AG

Inventor： BUORUFUGANGU HIYUMAA ,  BERUNTO BURONSUTERUTO ,  DEIITAA RITOMAN ,  MANFUREETO TSUYURUGAA

IPC: G03F7/027 ,  C08F2/50 ,  G03F7/00 ,  G03F7/095 ,  G03F7/11

Abstract: PURPOSE: To improve the adhesiveness of a relief layer to a carrier material and to shorten the exposure time when the printing plate is produced by incorporating a specified partially polymerized aryl glycidyl ether (meta)acrylate or using an intermediate layer formed there form. CONSTITUTION: An intermediate layer is deposited on a carrier, and further a photosensitive relief forming layer formed from the mixture of a polymer binder, photopplymerizable ethylenic unsaturated compd., photopolymerization initiator and thermopolymerization initiator is deposited. At least a partially polymerized compd. shown by formula I is further incorporated. In the formula, R is hydrogen or alkyls having 1-10 carbon atoms, R is hydrogen or methyl, X is -C2 H2 -, -(CH4 -CH2 -O)n -C2 H4 -, -(CHCH3 -CH2 O)n -CHCH3 -CH2 , etc., and (n) is 1 to 8. As a result the adhesiveness of the relief layer is remarkably improved, and the exposure time is drastically shortened when the printing plate is produced.

公开(公告)号：JPH03170932A

公开(公告)日：1991-07-24

申请号：JP21913890

申请日：1990-08-22

Applicant: BASF AG

Inventor： DEIITAA RITOMAN

IPC: G03F7/033

Abstract: PURPOSE: To improve brittleness and flocculating power by incorporating PVA resin consisting of two kinds of materials, a water-soluble monofunctional ethylenic unsatd. photopolymerizable monomer, a multifunctional ethylenic unsatd. photopolymerizable monomer and a photopolymn. initiator. CONSTITUTION: This photopolymerizable mixture forming a photopolymerizable recording layer contains at least two kinds of partially saponified poly(vinyl alcohol-alkanecarboxylic ester) as a binder, a water-soluble monofunctional ethylenic unsatd. photopolymerizable monomer, a multifunctional ethylenic unsatd. photopolymerizable monomer and a photopolymn. initiator. Since no brittleness and high flocculating power are ensured, cracking is not caused at the time of storage and pollution and the bleeding of the components are prevented in the case of storage at a high temp. over a long period of time.

公开(公告)号：JPH02282256A

公开(公告)日：1990-11-19

申请号：JP3404490

申请日：1990-02-16

Applicant: BASF AG

Inventor： DEIITAA RITOMAN ,  HORUSUTO KOTSUHO

IPC: G03F7/00 ,  G03F7/038 ,  G03F7/40

Abstract: PURPOSE: To easily produce a relief printing plate of which the relief layer has a non-tacky adhesive surface by subjecting the photopolymerized relief layer to a post processing with a basic post-processing soln. at the production. CONSTITUTION: This process produces the relief printing plate of which the photopolymerized relief layer has the non-tacky adhesive surface by subjecting a photopolymerizable relief forming recording layer (A) contg. (a1 ) at least one kind of acid base-contg. polymer binders, (a2 ) at least one kind of olefiinic unsatd. photopolymerized monomers having compatibility with these binders (a1 ) and (a3 ) at least one kind of photopolymn. initiators to exposure in accordance with the images, washing (developing) the non-exposed (non-photopolymerized) regions of the exposed recording layer (A) with a developer and subjecting the photopolymerized relief layer generated in such a manner to post-processing with the post-processing liquid. The process is constituted to use the basic post-processing soln. in the post-processing stage. The occurrence of the deterioration in the relief layer is prevented by the tacky adhesiveness of the surface of the relief printing plate obtd. in the process by such constitution. An excellent printing effect is obtd. even with an extremely large number of printing sheets.

公开(公告)号：JPS63317501A

公开(公告)日：1988-12-26

申请号：JP13453388

申请日：1988-06-02

Applicant: BASF AG

Inventor： GEERUHARUTO HOFUMAN ,  BUORUFUGANGU HIYUMAA ,  HORUSUTO KOTSUHO ,  DEIITAA RITOMAN

IPC: C08F8/00 ,  C08F2/48 ,  C08F8/44 ,  C08F290/00 ,  C08F299/00

公开(公告)号：JPH028849A

公开(公告)日：1990-01-12

申请号：JP6400189

申请日：1989-03-17

Applicant: BASF AG

Inventor： EERITSUHI BETSUKU ,  BERUNTO BURONSUTERUTO ,  BUORUFUGANGU HIYUMAA ,  DEIITAA RITOMAN

IPC: C08F2/50 ,  G03F7/00 ,  G03F7/027 ,  G03F7/033 ,  G03F7/095 ,  G03F7/11

Abstract: PURPOSE: To improve the compatibility of a monomer with a polymer binder and flexibility or elasticity by incorporating a specified water-soluble copolymer and a polymerizable ethylenically unsatd. compd. CONSTITUTION: A middle layer is formed on a substrate and a photopolymerizable relief forming layer contg. a mixture of a polymer binder with a polymerizable ethylenically unsatd. compd., a photopolymn. initiator and a thermal polymn. inhibitor is formed on the middle layer. The polymer binder is a water-soluble copolymer or deriv. of PVA and the unsatd. compd. is a compd. represented by formula I, wherein R is H, 1-10C alkyl or 6-10C aryl, R is H or methyl, X is -(CH2 -CH2 -O)n CH-, -C2 H4 , etc., and (n) is 0-8. The compatibility of the monomer with the polymer binder, water developability and flexibility can be improved.