公开(公告)号：US3887591A

公开(公告)日：1975-06-03

申请号：US41242173

申请日：1973-11-02

Applicant: BASF AG

Inventor： ELSER WOLFGANG ,  SCHWANTJE GERD

IPC: C07C227/12 ,  C07C229/74 ,  C07D265/12 ,  C09B1/22

CPC classification number: C09B1/22 ,  C07D265/12

Abstract: The production of 1-amino-4-nitroanthraquinone-2-carboxylic esters by reaction of 1,2-dihydro-6-nitro-7,8-diphthaloyl-3,1,4Hbenzoxazone-4 with an alcohol in the presence of an acid catalyst. Pure carboxylic esters are immediately obtained in a high yield previous isolation of the carboxylic acid.

Abstract translation: 通过1,2-二氢-6-硝基-7,8-二邻苯二甲酰基-3,1,4H-苯并恶嗪-4与醇在存在下反应生产1-氨基-4-硝基蒽醌-2-羧酸酯 酸催化剂。 立即以高产率先前分离羧酸得到纯羧酸酯。

公开(公告)号：US3923806A

公开(公告)日：1975-12-02

申请号：US44894774

申请日：1974-03-07

Applicant: BASF AG

Inventor： BOCK GUSTAV ,  ELSER WOLFGANG

IPC: C09B57/04 ,  C07D239/62

CPC classification number: C09B57/04

Abstract: IN WHICH BOTH R''s are alkyl, phenyl or phenalkyl (the radical R bearing other substituents if desired) and X is the radical of a methyleneactive compound. The dyes dye fibers of linear polyesters brilliant greenish yellow to bluish red shades.

Disperse dyes of the formula:

Abstract translation: 分散染料的配方：

公开(公告)号：US3925427A

公开(公告)日：1975-12-09

申请号：US48641874

申请日：1974-07-08

Applicant: BASF AG

Inventor： ELSER WOLFGANG ,  EILINGSFELD HEINZ ,  SCHOCH WERNER

IPC: C09B1/00 ,  C07C225/36 ,  C09B1/50 ,  C09B1/54 ,  C07C97/26

CPC classification number: C09B1/545 ,  C09B1/50

Abstract: A process for the manufacture of blue anthraquinonoid disperse dyes based on 1,5(1,8)-diamino-4,8(4,5)-dihydroxyanthraquinone, wherein 1,5(1,8)-dinitro-4,8(4,5)-dimethoxy-anthraquinone or mixtures of these compounds are reduced, in 20 to 45% strength by weight oleum, with sulfur at -10* to +50*C in the presence of boric acid, and the product of the reduction is brominated in sulfuric acid or 0 to 5% strength by weight oleum or in organic solvents until the product thus obtained contains 12 to 30% by weight of bromine. Dyes which give deep and, in particular, light-fast dyeings, above all on fibrous materials consisting of linear polyesters, are obtained.

Abstract translation: 一种制备基于1,5（1,8） - 二氨基-4,8（4,5） - 二羟基蒽醌的蓝色蒽醌类分散染料的方法，其中1,5（1,8） - 二硝基-4,​​8（ 4,5） - 二甲氧基 - 蒽醌或这些化合物的混合物在20-45％重量的发烟硫酸中与硫在-10℃至+ 50℃下在硼酸存在下还原，并且还原产物 在硫酸中溴化，或0〜5％重量的发烟硫酸或有机溶剂，直到由此获得的产物含有12至30重量％的溴。 得到深色的染料，特别是轻度染色，尤其是由线性聚酯组成的纤维材料上。

公开(公告)号：US3892784A

公开(公告)日：1975-07-01

申请号：US45178574

申请日：1974-03-18

Applicant: BASF AG

Inventor： ELSER WOLFGANG ,  SCHMIDT HELMUT

IPC: C07C50/34 ,  C07C45/00 ,  C07C46/00 ,  C07C67/00 ,  C07C49/68

CPC classification number: C07C46/00 ,  C07C50/34

Abstract: An improved process for the manufacture of Alpha -methyl ethers of anthraquinone from the corresponding nitroanthraquinones by reacting the nitro compound with methanol in the presence of at least the stoichiometric amount of anhydrous or virtually anhydrous potassium carbonate with heating. Pure Alpha -methyl ethers are obtained in high space-time yields. The Alpha nitroanthraquinones used may, if desired, be mixtures such as are obtained in the mononitration or dinitration of anthraquinone.

Abstract translation: 在至少化学计量量的无水或几乎无水的碳酸钾存在下，通过加热使硝基化合物与甲醇反应，从相应的硝基蒽醌制备蒽醌的α-甲基醚的改进方法。 以高空时收率获得纯α-甲基醚。 如果需要，所用的α-硝基蒽醌可以是诸如在蒽醌的一硝化或二硝化中获得的混合物。

公开(公告)号：IT7927538D0

公开(公告)日：1979-11-23

申请号：IT2753879

申请日：1979-11-23

Applicant: BASF AG

Inventor： MENSCH SIEGFRIED ,  EPPLE GERHARD ,  ELSER WOLFGANG

IPC: C09B1/58 ,  C09B1/62 ,  D06P3/60 ,  D06P3/82 ,  D06P

Abstract: Uniformly dyed water-swellable cellulosic fibers which have been produced by contacting water-swellable cellulosic fibers successively or simultaneously with water, with ethylene glycol, propylene glycol or derivatives of these and with an essentially water-insoluble dye of the formula where Y is unsubstituted or substituted phenyl or naphthyl or an unsubstituted or substituted saturated or unsaturated 5-membered or 6-membered heterocyclic radical, two of the three radicals X are hydroxyl and the remaining radical X is where A is chlorine, bromine, cyano, nitro, an aliphatic, cycloaliphatic, araliphatic or aromatic radical and n is 0, 1, 2 or 3 and where, if n>1, the radicals are identical or different. Deep reddish blue to green dyeings or prints are obtained. The dyeings have very good fastness characteristics.

公开(公告)号：IT1193229B

公开(公告)日：1988-06-15

申请号：IT2590279

申请日：1979-09-20

Applicant: BASF AG

Inventor： NEUMANN PETER ,  ELSER WOLFGANG ,  BOCK GUSTAV

IPC: C07D20060101 ,  C07D

Abstract: New isoindoline derivs. are of formula (I) (in which R1 and R2 are methyl or ethyl.) Used for mass colouring of thermoplastics in red shades they give strong shades which are very stable to high temps., eg. up to 300 degrees C in polystyrene, in comparison with nearest cpd fromcondensn. of 1-amino 3-imino isoindolenine with 2 mols 2-cyano-methyl benzimidazole, which is only stable to 220 PC.

公开(公告)号：IT1127258B

公开(公告)日：1986-05-21

申请号：IT2753879

申请日：1979-11-23

Applicant: BASF AG

Inventor： MENSCH SIEGFRIED ,  EPPLE GERHARD ,  ELSER WOLFGANG

IPC: C09B1/58 ,  C09B1/62 ,  D06P3/60 ,  D06P3/82 ,  D06P

Abstract: Uniformly dyed water-swellable cellulosic fibers which have been produced by contacting water-swellable cellulosic fibers successively or simultaneously with water, with ethylene glycol, propylene glycol or derivatives of these and with an essentially water-insoluble dye of the formula where Y is unsubstituted or substituted phenyl or naphthyl or an unsubstituted or substituted saturated or unsaturated 5-membered or 6-membered heterocyclic radical, two of the three radicals X are hydroxyl and the remaining radical X is where A is chlorine, bromine, cyano, nitro, an aliphatic, cycloaliphatic, araliphatic or aromatic radical and n is 0, 1, 2 or 3 and where, if n>1, the radicals are identical or different. Deep reddish blue to green dyeings or prints are obtained. The dyeings have very good fastness characteristics.

公开(公告)号：FR2463137A1

公开(公告)日：1981-02-20

申请号：FR7920617

申请日：1979-08-13

Applicant: BASF AG

Inventor： NEUMANN PETER ,  ELSER WOLFGANG ,  BOCK GUSTAV

IPC: C08K5/3447 ,  C09B57/04 ,  C07D403/14 ,  C08K5/34 ,  C08L101/00

Abstract: New isoindoline derivs. are of formula (I) (in which R1 and R2 are methyl or ethyl.) Used for mass colouring of thermoplastics in red shades they give strong shades which are very stable to high temps., eg. up to 300 degrees C in polystyrene, in comparison with nearest cpd fromcondensn. of 1-amino 3-imino isoindolenine with 2 mols 2-cyano-methyl benzimidazole, which is only stable to 220 PC.