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    1.
    发明专利
    未知

    公开(公告)号：DE3779013D1

    公开(公告)日：1992-06-17

    申请号：DE3779013

    申请日：1987-08-12

    Applicant: BASF AG

    Inventor： FISCHER ROMAN DR ,  MUELLER HERBERT DR

    IPC: C07C209/16 ,  C07C211/07

    Abstract: In the prodn. of trialkylamines (I) by reacting prim. alcohols (II) with NH3 in the presence of a hydrogenation/dehydrogenation catalyst (III), the novel features are that: a) the process is operated in the liquid phase; b) the NH3:(II) molar ratio = at least 1:4; c) the reaction is carried out in the presence of the water formed in the reaction; and d) (III) contains only Cu as catalytic hydrogenating/dehydrogenating metal.

    2.
    发明专利
    未知

    公开(公告)号：DE3724239A1

    公开(公告)日：1989-02-02

    申请号：DE3724239

    申请日：1987-07-22

    Applicant: BASF AG

    Inventor： FISCHER ROMAN DR ,  MERCKER HANS JOCHEN DR ,  MUELLER HERBERT DR

    IPC: C07D295/02 ,  B01J23/62 ,  C07C213/02 ,  C07C215/08 ,  C07D267/10 ,  C07D267/22 ,  C07D273/01

    Abstract: Aliphatic N,N-dialkylsubstituted aminoalcohols I … … (A = aliphatic bridging member containing at least 2 carbon atoms; R , R = C1-C6-alkyl groups which can be linked to give a 5- or 6-membered ring), are prepared by reaction of a diol II… HO-A-OH (II> with a secondary amine III … … in the presence of a hydrogenation/dehydrogenation catalyst and in the presence of hydrogen and a basic alkali metal compound or alkaline earth metal compound in liquid phase at elevated temperature and under elevated pressure by carrying out the reaction… a) at 150 to 250 DEG C,… b) under a total pressure of 40 to 250 bar,… c) under a hydrogen partial pressure of 2 to 60 bar,… d) in the presence of a hydrogenation/dehydrogenation catalyst based on copper and… e) in the presence of 1 to 20% by weight of water, relative to the amount of the reaction mixture.

    High-molecular non-polymeric alpha,beta-unsatd - aldehydes prepn - by alkylation of alpha,beta-unsatd aldehydes with
    4.
    发明专利
    High-molecular non-polymeric alpha,beta-unsatd - aldehydes prepn - by alkylation of alpha,beta-unsatd aldehydes with 未知

    公开(公告)号：DE2249372A1

    公开(公告)日：1974-04-25

    申请号：DE2249372

    申请日：1972-10-09

    Applicant: BASF AG

    Inventor： GOETZ NORBERT DR ,  FISCHER ROMAN DR

    IPC: C07C45/70 ,  C07C45/71 ,  C07C47/20

    Abstract: The prepn. of high-molecular aldehydes (I) by the reaction of II with III: R9-CR8=CR7-CR5R6-CR3R4-CR2=CR1-CHO (I) R9-CR5=CR7-CR5R6-OR10 (II) C(H)R3R4-CR2=CR1-CHO (III) is carried out at increased temp. and between normal press. and 250 atmos. excess, in liquid phase. In the formulae, R1 and R2 are H, 1-4C alkyl or (alkyl-substd.) phenyl, R3, R5 and R7 are H or 1-4C alkyl, R4 is H or an (un)satd., (un)branched 1-12C (cyclo)aliphatic gp., R8 is 1-4C alkyl or, if R9 is phenyl, is H, R9 is an (un)branched, (un)satd. 1-12C (cyclo)aliphatic gp. in which C-C bonds may be interrupted by O or -O-CO-, or may be (alkyl-substd.) phenyl, and R10 is H or the acyl residue from a 1-5C carboxylic acid. I are raw materials for natural prods. and perfumes, e.g. beta-ionone, farnesol and phytol.

    Alpha, beta-unsatd ketone prodn - by reaction between primary alcohols and ketonesin presence of catalysts in liqui
    7.
    发明专利
    Alpha, beta-unsatd ketone prodn - by reaction between primary alcohols and ketonesin presence of catalysts in liqui 未知

    公开(公告)号：DE2148610A1

    公开(公告)日：1973-04-05

    申请号：DE2148610

    申请日：1971-09-29

    Applicant: BASF AG

    Inventor： FISCHER ROMAN DR ,  GOETZ NORBERT DR

    IPC: C07C45/71 ,  C07C49/20

    Abstract: Prodn. of alpha,beta-unsatd. ketones of formula: R1-CH=C(R2)-CO-R3 (in which R1, R2 and R3 are opt. branched, opt. satd. aliphatic hydrocarbyl, cycloaliphatic radicals or aromatic radicals, which may be substd. with alkoxy gps.; or R2 is H; or R2 and R3 form together an alkylene bridge) by reaction between R1-CH2OH and R2 - CH2 - CO - R3 is improved in that the reaction is effected in the presence of a catalyst, in particular ZnO (pref.) and/or CdO and/or MnO in the liquid phase at 150-290 degrees C (pref. 180-280 degrees C). This method is esp. suitable for the prodn. of high mol.wt. ketones having multiple number of unsatd. bonds used as aroma agents, and valuable inters. such as pseudoionone. High yields selective w.r.t. alpha,beta-unsatd. ketones are obtd.

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