3.
    发明专利
    未知

    公开(公告)号:DE4003174A1

    公开(公告)日:1991-08-08

    申请号:DE4003174

    申请日:1990-02-03

    Applicant: BASF AG

    Abstract: In a process for purifying 7-chlor-quinoline-8-carboxylic acids of formula (I) (where X = H, halogen, lower alkyl group) by recrystallization from lower alcohols miscible with water, the recrystallization is carried out in the presence of small quantities of a base. The quinoline carboxylic acids of formula (I) are useful plant protection agents.

    5.
    发明专利
    未知

    公开(公告)号:DE4217846C1

    公开(公告)日:1993-12-23

    申请号:DE4217846

    申请日:1992-05-29

    Applicant: BASF AG

    Abstract: Described is the preparation of 5-dichloroacetyl-3,3,6-trimethyl-9-oxo-1,5-diazabicyclo[4,3,0]nonane (I) by reacting 3,3,6-trimethyl-9-oxo-1,5-diazabicyclo[4,3,0]nonane (II) with dichloroacetyl chloride in the presence of a solvent and a base. The reaction is carried out in a two-phase system comprising a practically water-insoluble solvent and water, and sodium or potassium hydroxide is added as the base in proportion to the amount of dichloroacetyl chloride consumed so that the aqueous phase has a pH of 7 to 9. The solid product formed is then separated off.

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