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公开(公告)号:DE102005005946A1
公开(公告)日:2006-08-17
申请号:DE102005005946
申请日:2005-02-10
Applicant: BASF AG
Inventor: WISSEL KATHRIN , MAASE MATTHIAS , HUTTENLOCH OLIVER , FLAJS TONI , KUHL MELANIE
IPC: C07F9/50
Abstract: Method for producing tertiary phosphines by reacting a compound of the general formula (I) in which A is R 1 or L 2 , B is R 2 or L 3 , the R 1 and R 2 radicals are each independently an organic radical having in each case from 1 to 30 carbon atoms, where the R 1 and R 2 radicals may also be joined together; and the leaving groups L 1 to L 3 are each independently halogen, alkyloxy having from 1 to 10 carbon atoms or aryloxy having from 6 to 10 carbon atoms (a) with an alkali metal in an organic aprotic solvent and (b) a compound of the general formula (II) L 4 -R 3 (II) in which the R 3 radical is an organic radical having in each case from 1 to 30 carbon atoms; and the leaving group L 4 is halogen, alkyloxy having from 1 to 10 carbon atoms or aryloxy having from 6 to 10 carbon atoms, in which the resulting reaction mixture is hydrolyzed with an aqueous base which has a pH of >= 10 and the organic phase is removed from the aqueous phase.