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公开(公告)号:DE3160077D1
公开(公告)日:1983-03-24
申请号:DE3160077
申请日:1981-04-10
Applicant: BASF AG
Inventor: GIMPEL JUERGEN DR , FEUERHERD KARL-HEINZ DR , SCHENCK HANS-UWE DR
IPC: C08F26/00 , C08F246/00 , C08G18/08 , C08G18/72 , C08L33/00 , C09D5/44 , C09D175/00 , C25D13/06 , C09D3/727
Abstract: Surface-coating binders based on a copolymer which contains tertiary amino groups, blocked isocyanate groups, hydroxyl groups and ether groups and which, due to partial or complete salification with an acid, is water-soluble or water-dispersible. This copolymer contains, as copolymerized units, one or more olefinically unsaturated compounds possessing a tertiary amino group, an N-(1-alkenyl) isocyanate blocked with a CH-, OH- or NH-acidic blocking agent, an adduct of an epoxy resin based on bisphenol A and epichlorohydrin, and having a molecular weight of from 380 to 3,500, with an olefinically unsaturated alcohol of 3 to 20 carbon atoms, and one or more other copolymerizable olefinically unsaturated compounds, and has a mean molecular weight of from 1,000 to 20,000. The novel surface-coating binder is used for the cathodic electrocoating of metallic articles.
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公开(公告)号:AT19254T
公开(公告)日:1986-05-15
申请号:AT83108873
申请日:1983-09-08
Applicant: BASF AG
Inventor: GIMPEL JUERGEN DR , SCHWENDEMANN VOLKER DR , GULBINS ERICH DR
IPC: C08F299/00 , C08F290/00 , C08F299/02 , C08G18/00 , C09D5/44 , C09D175/00 , C09D3/48
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公开(公告)号:DE3245296A1
公开(公告)日:1984-06-14
申请号:DE3245296
申请日:1982-12-08
Applicant: BASF AG
Inventor: GIMPEL JUERGEN DR , SPOOR HERBERT DR , OSTERLOH ROLF DR , SANDER HANS DR
Abstract: The invention relates to the use of an isocyanate group-containing copolymer of from 5 to 60% by weight of an N-(1-alkenyl) isocyanate and from 95 to 40% by weight of at least one (meth)acrylate, some of which may be replaced by further copolymerisable, olefinically unsaturated compounds containing no OH-, CH-, NH- or SH-acidic groups, the copolymer having a mean molecular weight of from 500 to 10000, in combination with hydroxyl group-containing polyacrylates and/or polyesters as a binder for polyurethane paints.
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公开(公告)号:DE3245295A1
公开(公告)日:1984-06-14
申请号:DE3245295
申请日:1982-12-08
Applicant: BASF AG
Inventor: GIMPEL JUERGEN DR , SPOOR HERBERT DR , OSTERLOH ROLF DR , SANDER HANS DR
Abstract: The invention relates to the use of an isocyanate group-containing copolymer of from 5 to 60% by weight of an N-(1-alkenyl) isocyanate and from 95 to 40% by weight of at least one (meth)acrylate, some of which may be replaced by further copolymerisable, olefinically unsaturated compounds containing no OH-, CH-, NH- or SH-acidic groups, the copolymer having a mean molecular weight of from 500 to 10000, in combination with low-molecular-weight diols and/or polyols as a binder for polyurethane paints, in particular for automotive refinish paints.
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公开(公告)号:DE3225874A1
公开(公告)日:1984-01-12
申请号:DE3225874
申请日:1982-07-10
Applicant: BASF AG
Inventor: GULBINS ERICH DR , KEMPTER FRITZ ERDMANN DR , GIMPEL JUERGEN DR
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公开(公告)号:AT13066T
公开(公告)日:1985-05-15
申请号:AT82110861
申请日:1982-11-24
Applicant: BASF AG
Inventor: GIMPEL JUERGEN DR , JAECKEL KLAUS-PETER DR , SANDER HANS DR
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公开(公告)号:DE3260930D1
公开(公告)日:1984-11-15
申请号:DE3260930
申请日:1982-03-23
Applicant: BASF AG
Inventor: GIMPEL JUERGEN DR , FEUERHERD KARL-HEINZ DR
IPC: C08G18/72 , C08G18/80 , C09D5/46 , C09D133/06 , C09D3/80
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公开(公告)号:DE3234491A1
公开(公告)日:1984-03-22
申请号:DE3234491
申请日:1982-09-17
Applicant: BASF AG
Inventor: GIMPEL JUERGEN DR , SCHWENDEMANN VOLKER DR , GULBINS ERICH DR
IPC: C08F299/00 , C08F290/00 , C08F299/02 , C08G18/00 , C09D5/44 , C09D175/00 , C08F220/00 , C08F222/22 , C08F220/10 , C08F220/36 , C09D3/72 , C09D3/58 , C09D3/80 , C09D5/40
Abstract: Surface coating binders which contain tertiary amino groups, blocked isocyanate groups, hydroxyl groups and ether groups and are water-soluble or water-dispersible as a result of partial or complete salt formation with an acid are prepared by copolymerization of a mixture comprising (A) an olefinically unsaturated compound which contains a tertiary amino group, (B) an N-(1-alkenyl)-isocyanate which is blocked with a CH-, OH- or NH-acidic blocking agent and (C) an adduct of an epoxy resin based on bisphenol A and epichlorohydrin, and an olefinically unsaturated carboxylic acid of 3 to 20 carbon atoms, a secondary amine and, if required, a saturated monocarboxylic acid of 1 to 20 carbon atoms, with or without one or more copolymerizable, olefinically unsaturated compounds not mentioned under (A), (B) and (C). These surface coating binders are particularly useful as self-crosslinking or externally crosslinking binders for the cathodic electrocoating of metal articles.
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公开(公告)号:DE3060966D1
公开(公告)日:1982-11-25
申请号:DE3060966
申请日:1980-05-16
Applicant: BASF AG
Inventor: GIMPEL JUERGEN DR , HARTMANN HEINRICH DR , SCHENK HANS-UWE DR
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公开(公告)号:DE3060699D1
公开(公告)日:1982-09-16
申请号:DE3060699
申请日:1980-05-16
Applicant: BASF AG
Inventor: GIMPEL JUERGEN DR , HARTMANN HEINRICH DR , SCHENCK HANS-UWE DR
IPC: C08F246/00 , C08L33/00 , C09D5/44 , C09D133/00 , C25D13/06 , C09D3/727 , C09D5/40
Abstract: Surface-coating binders based on a copolymer which contains tertiary amino groups and blocked isocyanate groups and is water-soluble or water-dispersible as a result of being at least partially salified with an acid. The copolymer contains, as copolymerized units, an olefinically unsaturated compound which possesses a tertiary amino group, an N-(1-alkenyl)-isocyanate which is blocked with a CH-, OH- or NH-acidic blocking agent, and another olefinically unsaturated compound, with or without one or more copolymerizable olefinically unsaturated compounds which possess hydrogen atoms which are reactive toward isocyanate groups, and has a mean molecular weight of from 1,000 to 20,000. The novel surface-coating binders are used for the cathodic electrocoating of metallic articles.
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