公开(公告)号：DE50100541D1

公开(公告)日：2003-10-02

申请号：DE50100541

申请日：2001-06-21

Applicant: BASF AG

Inventor： GYPSER DR ,  GROTE DR ,  RHEINHEIMER DR ,  ROSE DR ,  CULLMANN DR ,  GEWEHR DR ,  GRAMMENOS DR ,  TORMO I BLASCO DR ,  MUELLER DR ,  SAUTER DR ,  AMMERMANN DR ,  STRATHMANN DR ,  LORENZ DR ,  STIERL DR

IPC: C07C251/80 ,  A01N33/26 ,  A01N37/50 ,  C07C249/16 ,  C07C251/86

Abstract: Hydrazonomethyl-salicylic acid (I) derivatives are new. The hydrazonomethyl-salicylic acid derivatives are compounds of formula (I). X = halo, NO2, CN, 1-4C alkyl, or 1-4C alkoxy; m = 0-3; A = OH, 1-4C alkoxy, NH2, NHCH3, or N(CH3)2; R = phenyl, naphthyl, 3-10C cycloalkyl, 5- or 6-membered heteroaryl or heterocyclyl containing 1-3 N and/or 1 O or S or 1 or 2 O and/or S (each optionally substituted with 1-3 Ra); Ra = CN, NO2, NH2, H2NCO-, H2NCS-, halo, OH, 1-6C alkyl or 1-6C alkoxy (each optionally substituted with halo), 1-6C alkylcarbonyl, 1-6C alkylsulfonyl, 1-6C alkylsulfoxyl, 3-6C cycloalkyl, 1-6C alkoxycarbonyl, 1-6C alkylthio, NH(1-6C alkyl), N(1-6C alkyl)2, 1-6C alkyl-NH-CO-, (1-6C alkyl)2N-CO-, 1-6C alkyl-NH-CS-, (1-6C alkyl)2N-CS-, 2-6C alkenyl, 2-6C alkenyloxy, phenyl, phenoxy, benzyl, benzyloxy, 5- or 6-membered heterocyclyl, heteroaryl or heteroaryloxy, C(=NOR alpha )-OR beta , or OC(R alpha )2-C(R beta )=NOR beta , and cyclic groups are optionally substituted with 1-3 Rb; Rb = CN, NO2, NH2, H2NCO-, H2NCS-, halo, OH, 1-6C alkyl or 1-6C alkoxy (each optionally substituted with halo), 1-6C alkylcarbonyl, 1-6C alkylsulfonyl, 1-6C alkylsulfoxyl, 3-6C cycloalkyl, 1-6C alkoxycarbonyl, 1-6C alkylthio, NH(1-6C alkyl), N(1-6C alkyl)2, 1-6C alkyl-NH-CO-, (1-6C alkyl)2N-CO-, 1-6C alkyl-NH-CS-, (1-6C alkyl)2N-CS-, 2-6C alkenyl, 2-6C alkenyloxy, 3-6C cycloalkenyl, phenyl, phenoxy, phenylthio, benzyl, benzyloxy, 5- or 6-membered heterocyclyl, heteroaryl or heteroaryloxy, or C(=NOR alpha )-OR beta ; R alpha and R beta = H or 1-6C alkyl; R = H, CN, or 1-6C alkyl, 2-6C alkenyl, 2-6C alkynyl, 1-6C haloalkyl, 1-6C alkoxy or 1-6C alkylthio (each optionally substituted with 1 or more halo and/or 1-3 Rc); Rc = halo, CN, NO2, OH; 1-6C alkyl or 1-6C alkoxy (each optionally substituted with halo); 1-6C alkylcarbonyl, 3-6C cycloalkyl, 1-6C alkoxycarbonyl, 1-6C alkylthio, NH(1-6C alkyl), N(1-6C alkyl)2, 2-6C alkenyl, 3-6C alkenyloxy, 3-6C alkynyloxy, or 1-4C alkylenedioxy (optionally halogenated). An Independent claim is also included for the preparation of compounds (I).

公开(公告)号：DE50200390D1

公开(公告)日：2004-06-03

申请号：DE50200390

申请日：2002-10-18

Applicant: BASF AG

Inventor： ROSE DR ,  TORMO I BLASCO DR ,  GEWEHR DR ,  GRAMMENOS DR ,  MUELLER DR ,  RHEINHEIMER DR ,  SCHAEFER DR ,  SCHIEWECK DR ,  GROTE DR ,  GYPSER DR ,  AMMERMANN DR ,  LORENZ DR ,  STIERL DR ,  STRATHMANN DR ,  CARTER DR ,  CURTZE DR

IPC: A01N31/14 ,  A01N31/16 ,  A01N33/10 ,  A01N37/38 ,  A01N37/40 ,  C07B61/00 ,  C07C39/42 ,  C07C41/26 ,  C07C43/23 ,  C07C69/017 ,  C07C69/14 ,  C07C323/19 ,  C07C323/25

Abstract: Polysubstituted 4-methoxy-benzhydryl alcohol or thiol derivatives (I) are new. Polysubstituted 4-methoxy-benzhydryl alcohol or thiol derivatives of formula (I) are new: X = O or S; R , R = halo, CN, NO2, OH, SH, NH2, alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylcarbonyloxy, OCHO, alkylthio, alkenylthio, alkynylthio, mono- or dialkylamino, alkylcarbonyl or CHO (where all hydrocarbyl moieties are optionally mono- or polyhalogenated); R = halo, CN, NO2, OH, SH, NH2, alkyl, alkoxy, haloalkyl or haloalkoxy; R = alkyl, alkenyl or alkynyl (all optionally mono- or polyhalogenated); R , R = OH, alkyl, alkenyl, haloalkyl, haloalkenyl, alkoxy, alkenyloxy, haloalkoxy, haloalkenyloxy, cycloalkyl, cycloalkyl-(1-3C) alkyl, cycloalkoxy or cycloalkyl-(1-3C) alkoxy; and n = 0-2. Unless specified otherwise alkyl moieties have 1-6C, alkenyl or alkynyl moieties 2-6C and cycloalkyl moieties 3-8C. An Independent claim is also included for the preparation of (I).