Preparation of cylindrical molded bodies, useful in automobiles e.g. springs, comprises reaction of prepolymers based on methylenediphenyldiisocyanate with cross linking components based on polyetheralcohol, diols, water and catalysts

    公开(公告)号:DE102005008263A1

    公开(公告)日:2006-08-24

    申请号:DE102005008263

    申请日:2005-02-22

    Applicant: BASF AG

    Abstract: Preparation of cylindrical molded bodies (I) based on cellular polyurethane elastomers with determined density, tensile strength, elongation and a tear resistance, comprises reaction of prepolymers (i) with cross linking components (ii) in a molded form, where (i) are isocyanate groups based on methylenediphenyldiisocyanate and polyetherdiol; and (ii) contains polyetheralcohol with a nominal functionality of 2-3; diol with a molecular weight of 62-499 g/mol; water; and catalysts. Preparation of cylindrical molded bodies (I) based on cellular polyurethane elastomers with a density of 350-900 kg/m 3> according to DIN EN ISO 1798, a tensile strength of >= 2 N/mm 2> according to DIN EN ISO 1798, elongation of >= 200% according to DIN EN ISO 1798 and a tear resistance of >= 8 N/mm according to DIN ISO 34-1 B, comprises reaction of prepolymers (i) with cross linking components (ii) in a molded form, where (i) are isocyanate groups based on methylenediphenyldiisocyanate and polyetherdiol with a molecular weight of 1500-3000 g/mol based on propylene oxide and/or ethyleneoxide; and (ii) contains polyetheralcohol with a nominal functionality of 2-3 in relation to isocyanates and a molecular weight of 1500-6000 g/mol based on propylene oxide and/or ethyleneoxide; diol with a molecular weight of 62-499 g/mol; water; and catalysts, where (i) and (ii) are filled in a molded form by means of a high pressure machine, which exhibits a mixing head, into which (i) and (ii) are mixed and obtained product amounts to 15-60 g/s.

    Cylindrical molded bodies, useful in automobile parts e.g. auxiliary springs, buffer, short arm-bearing, comprises cellular polyurethane elastomers with determined density, tensile strength, breach extension and tear resistance

    公开(公告)号:DE102005008242A1

    公开(公告)日:2006-08-24

    申请号:DE102005008242

    申请日:2005-02-22

    Applicant: BASF AG

    Abstract: Cylindrical molded bodies (I) comprises cellular polyurethane elastomers with a density of 300-900 kg/m 3>, a tensile strength of >= 2 N/mm 2>, a breach extension of >= 200% and a tear resistance of >= 8 N/mm, where the cellular polyurethane elastomers are based on reaction of: (i) isocyanate groups of prepolymers based on methylenediphenyldiisocyanate and polyetherdiol; with (ii) cross linking components containing polyetheralcohol; diol with a molecular weight of 62-499 g/mol; water; and catalysts. Cylindrical molded bodies (I) comprises cellular polyurethane elastomers with a density of 300-900 kg/m 3>according to DIN EN ISO 845, a tensile strength of >= 2 N/mm 2>according to DIN EN ISO 1798, a breach extension of >= 200% according to DIN EN ISO 1798 and a tear resistance of >= 8 N/mm according to DIN ISO 34-1 B, where the cellular polyurethane elastomers are based on reaction of: (i) prepolymers exhibiting isocyanate groups based on methylenediphenyldiisocyanate and polyetherdiol with a molecular weight of 1500-3000 g/mol based on propylene oxide and/or ethyleneoxide; with (ii) cross linking components containing polyetheralcohol with a nominal functionality of 2-3 in relation to isocyanates and a molecular weight of 1500-6000 g/mol based on propylene oxide and/or ethyleneoxide; diol with a molecular weight of 62-499 g/mol; water; and catalysts, where the polyol exhibits an average molecular mass of smaller than 3900 g/mol, where the average polyol molecular mass (M(polyol)) is calculated by (M b11xm b11+...+M b1nxm b1n)xW p+(M b21xm b21+...+M b2nxm b2n)xW v/(m b11+...+m b1n)xW p+(m b21+...+m b2n)xW v, where M (polyol) is average polyol molecular mass in g/mol; M b11(and/or M b1n) is molecular mass of polyol b11 (and/or polyol b1n) in (i) in g/mol; m b11(and/or m b1n) is mass proportion of polyol b11 (and/or polyol b1n) in (i) in g/g; W pis mass proportion of (i) in the cylindrical molded article in g/g; M b21(and/or M b2n) is molecular mass of polyol b21 and/or (polyol b2n) in (ii) in g/mol; m b21(and/or m b2n) is mass proportion of polyol b21 (and/or polyol b2n) in (ii) in g/g; and W vis mass proportion of (ii) in the cylindrical molded article in g/g. Independent claims are included for: (1) automobile chassis containing shock absorbers, a hollow cylindrical molded bodies, which is placed on its piston rod; and (2) the preparation of (I).

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