9-CYANO-SUBSTITUTED PERYLENE-3,4-DICARBOXYLIC ACID MONOIMIDES AS DYESTUFFS
    2.
    发明申请
    9-CYANO-SUBSTITUTED PERYLENE-3,4-DICARBOXYLIC ACID MONOIMIDES AS DYESTUFFS 审中-公开
    9-氰基取代的苝-3,4-二酰亚胺染料

    公开(公告)号:WO2004029028A3

    公开(公告)日:2005-04-21

    申请号:PCT/EP0309946

    申请日:2003-09-08

    Abstract: The invention relates to 9-cyano-substituted perylene-3,4-dicarboxylic acid monoimides (I) where the variables have the following meanings: X = a chemical bond, optionally substituted C1-C30 alkylenes, C5-C8 cycloalkylenes, arylenes, heteroarylenes, C1-C20 alkylarylenes, C1-C20 alkylheteroarylenes, aryl- or heteroaryl-C1-C20 alkylenes, Y = a functional group Y', or a polymerisable group P, or X-Y together = a group R, Y' = amino, hydroxy, -COOH, -SO3H, chlorine or bromine, P = a group (II), A, B independently = H, C1-C6 alkyl, phenyl, or together form a cyclopentene or cyclohexene ring, which comprise the double bond to which A and B are bonded, Q = a chemical bond, a -O-, -NR -, -S-, -OCO-, -OCOO-, -OCONR -, -NR CO-, -NR COO-, -NR CONR -, -CO-, -COO-, -CONR -, -SO2-O-, -SO2NR -, -O-SO2- or -NR SO2- group, n = 0, 1, 2 or 3 and R = H, optionally-substituted C1-C30 alkyl, C5-C8 cycloalkyl, aryl or heteroaryl.

    Abstract translation: 9-氰基取代的苝-3,4-二酰亚胺(I)与所述变量的含义如下:X为化学键; 任选取代的C1-C30亚烷基,C5-C8亚环烷基,亚芳基,hetarylene,C1-C20-烷基亚芳,C1-C20-Alkylhetarylen,芳基或杂芳基C1-C20亚烷基; Y是官能团Y“或可聚合 基团P; 或X-Y一起形成基团R; Y“是氨基,羟基,-COOH,-SO 3 H,氯或溴; P表示(II)中,A,B独立地是氢,C1-C6烷基,苯基或一起形成环戊烯 或含有双键环己烯环结合到A和B; Q为化学键; 一个-O - , - NR <2> - , - S - , - OCO - , - OCOO - , - OCONR <3> - , - NR <3> CO-,-NR <3> COO - , - NR <3> CONR <4> - , - CO - , - COO - , - CONR <3> - ,-SO 2 - O-,-SO 2 <3> - , - O-SO 2或NR <3> SO2 ; n为0,1,2或3; R是氢; 任选取代的C1-C30烷基,C5-C8环烷基,芳基或杂芳基。

    METHOD FOR CONVERTING PERYLEN-3,4:9,10-TETRACARBOXYLIC ACID DIIMIDES INTO A FORM SUITABLE FOR USE AS A FLUORESCENT DYE

    公开(公告)号:AU2003236705A1

    公开(公告)日:2003-12-31

    申请号:AU2003236705

    申请日:2003-06-06

    Applicant: BASF AG

    Abstract: A process for converting perylene-3,4:9,10-tetracarboximides of the general formula I in which R1 and R2 are each unbranched, branched or cyclic C1-C8-alkyl to a form suitable for use as fluorescent dyes, which comprises a) dissolving or suspending the perylene-3,4:9,10-tetracarboximides whose molecules have a molecular volume of ≦̸230 Å3 in an organic or inorganic solvent at from 0 to 250° C., b1) cooling the solution obtained in step a) to or below the crystallization temperature and, in the case of an organic solvent, if desired at the same time removing excess solvent until the first crystals form, or, in the case of an inorganic solvent, adding water or dilute aqueous solutions of the solvent until the first crystals form, and maintaining the solution at this temperature for further crystallization or b2) cooling the suspension obtained in step a) to or below the crystallization temperature when the temperature in step a) was above the crystallization temperature, and maintaining the suspension at this temperature for further crystallization, c) isolating the solvate crystals formed in step b) and d) then removing the solvent from the solvate crystals, and also novel crystalline forms of perylene-3,4:9,10-tetracarboxylic diimides.

    7.
    发明专利
    未知

    公开(公告)号:DE50301761D1

    公开(公告)日:2005-12-29

    申请号:DE50301761

    申请日:2003-06-06

    Applicant: BASF AG

    Abstract: A process for converting perylene-3,4:9,10-tetracarboximides of the general formula I in which R1 and R2 are each unbranched, branched or cyclic C1-C8-alkyl to a form suitable for use as fluorescent dyes, which comprises a) dissolving or suspending the perylene-3,4:9,10-tetracarboximides whose molecules have a molecular volume of ≦̸230 Å3 in an organic or inorganic solvent at from 0 to 250° C., b1) cooling the solution obtained in step a) to or below the crystallization temperature and, in the case of an organic solvent, if desired at the same time removing excess solvent until the first crystals form, or, in the case of an inorganic solvent, adding water or dilute aqueous solutions of the solvent until the first crystals form, and maintaining the solution at this temperature for further crystallization or b2) cooling the suspension obtained in step a) to or below the crystallization temperature when the temperature in step a) was above the crystallization temperature, and maintaining the suspension at this temperature for further crystallization, c) isolating the solvate crystals formed in step b) and d) then removing the solvent from the solvate crystals, and also novel crystalline forms of perylene-3,4:9,10-tetracarboxylic diimides.

    8.
    发明专利
    未知

    公开(公告)号:DE10218618A1

    公开(公告)日:2003-11-06

    申请号:DE10218618

    申请日:2002-04-25

    Applicant: BASF AG

    Abstract: A process for preparing perylene-3,4:9,10-tetracarboxylic dianhydride, comprising: dimerizing a naphthalene-1,8-dicarboximide of the formula IIa; reoxidizing the resulting alkali metal salt of the leuco form of the perylene-3,4:9,10-tetracarboxylic diimide of the formula Ia; hydrolyzing the diimide to the tetraalkali metal salt of perylene-3,4:9,10-tetracarboxylic acid in the presence of an inert organic solvent, of an alkali metal base and of water; and subjecting the tetraalkali metal salt of perylene-3,4:9,10-tetracarboxylic acid to the action of an aqueous inorganic acid to convert it into perylene-3,4:9,10-tetracarboxylic dianhydride; wherein R3 is cyclohexyl or phenyl which may each be substituted by up to three C1-C4-alkyl radicals, and the dimerizing is in a substantially homogeneous reaction medium consisting essentially of an apolar aprotic organic solvent and an alkali metal base.

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