Abstract:
PROBLEM TO BE SOLVED: To provide a cholesteric layer material having improved color stability, and a method for manufacturing it and its use. SOLUTION: A cholesteric layer material, having at least one kind of cholesteric layer three-dimensionally cross-linked and aligned, is used. The cholesteric layer cross-linked will not show visible color slippages.
Abstract:
The invention relates to pyrazolone pigments of general formula (I), wherein the radicals R , R , R and R independently represent hydrogen, chlorine, methyl or ethyl, whereby at least one of the radicals R - R is different from hydrogen. The inventive pigments are characterised by a CIELAB colour angle of 80 - 85 DEG , a chroma of 58 - 62 and a luminosity >/= 87 (measuring angle 45 DEG , standard illuminant D65).
Abstract:
The invention relates to a method for producing the quaterrylene-3,4:13,14-tetracarboxy diimides of general formula (I), wherein R, R' independently represent hydrogen or optionally substituted C 1 -C 30 alkyl, C 3 -C 8 cycloalkyl or aryl or hetaryl. The inventive method is characterized by reacting the perylene-3,4-dicarboximide of the general formula (IIa) in the presence of a base resistant, high-boiling, organic solvent and an alkali-containing or alkaline earth-containing base with the perylene-3,4-dicarboximide of the general formula (IIb), wherein X represents hydrogen, bromine or chlorine.
Abstract:
The invention relates to 9-cyano-substituted perylene-3,4-dicarboxylic acid monoimides (I) where the variables have the following meanings: X = a chemical bond, optionally substituted C1-C30 alkylenes, C5-C8 cycloalkylenes, arylenes, heteroarylenes, C1-C20 alkylarylenes, C1-C20 alkylheteroarylenes, aryl- or heteroaryl-C1-C20 alkylenes, Y = a functional group Y', or a polymerisable group P, or X-Y together = a group R, Y' = amino, hydroxy, -COOH, -SO3H, chlorine or bromine, P = a group (II), A, B independently = H, C1-C6 alkyl, phenyl, or together form a cyclopentene or cyclohexene ring, which comprise the double bond to which A and B are bonded, Q = a chemical bond, a -O-, -NR -, -S-, -OCO-, -OCOO-, -OCONR -, -NR CO-, -NR COO-, -NR CONR -, -CO-, -COO-, -CONR -, -SO2-O-, -SO2NR -, -O-SO2- or -NR SO2- group, n = 0, 1, 2 or 3 and R = H, optionally-substituted C1-C30 alkyl, C5-C8 cycloalkyl, aryl or heteroaryl.
Abstract:
The current invention relates to a perylene-3,4-dicarboxylic anhydride, substituted in the 9-position, of the general formula III wherein Z is bromine or cyano, and processes for preparing 9-bromoperylene-3,4-dicarboxylic anhydride and 9-cyanoperylene-3,4-dicarboxylic anhydride.
Abstract:
A platelet-shaped cholesteric multilayer pigment which comprises the layer sequence A/B/ and if desired C,whereA and C independently of one another are at least one partly light-permeable absorption layer, andB is at least one cholesteric layer.
Abstract:
An adhesive layer (B) forms the interlayer between similar or different cholesteric layers (A1) and (A2) in a cholesteric laminate material with the layer sequence A1/B/A2. Independent claims are also included for: (i) a process for the production of cholesteric laminate material by: (a) coating a base with a first coating material which is hardened to form layer (A1); (b) coating (A1) with a second material containing heat- and/or pressure-activated adhesive(s) to form a laminate A1/B with adhesive layer (B); (c) coating another base with a third coating material which is hardened to form layer (A2); (d) laminating (A2) with (A1/B) under elevated pressure and/or temperature to form laminate A1/B/A2; (e) stripping off the second base; and optionally (f) stripping off the first base; (ii) a process for the production of multilayer cholesteric flake pigments with the layer sequence A1/B/A2 by milling the above material to a particle size of up to 200 microns; (iii) cholesteric flake pigments obtained by this process; and (iv) compositions and coating materials containing these multilayer pigments.
Abstract:
The invention relates to pyrazolone pigments of general formula (I), wherein the radicals R , R , R and R independently represent hydrogen, chlorine, methyl or ethyl, whereby at least one of the radicals R -R is different from hydrogen. The inventive pigments are characterised by a CIELAB colour angle of 80-85°, a chroma of 58-62 and a luminosity >=87 (measuring angle 45°, standard illuminant D65).
Abstract:
The invention relates to pyrazolone pigments of general formula (I), wherein the radicals R , R , R and R independently represent hydrogen, chlorine, methyl or ethyl, whereby at least one of the radicals R -R is different from hydrogen. The inventive pigments are characterised by a CIELAB colour angle of 80-85°, a chroma of 58-62 and a luminosity >=87 (measuring angle 45°, standard illuminant D65).
Abstract:
Cholesteric laminate material, comprises at least one 3-dimensionally crosslinked, oriented cholesteric layer (I) which shows no color shift that can be induced by external stimuli. Independent claims are also included for the following: (a) cholesteric pigment comprising layer(s) (I) with an average particle size of 5-50 mu m and thickness of 0.2-5 mu m; (b) compositions containing the pigment(s); (c) polarizers, comprising the laminate and optionally a substrate foil; (d) broad band polarizers comprising laminates with a total thickness of about 2-50 mu m (without substrate film) and 3-20 cholesteric layers with attuned reflection maxima; and (e) the production of the laminate with layer(s) (I).