公开(公告)号：US3896053A

公开(公告)日：1975-07-22

申请号：US36794973

申请日：1973-06-07

Applicant: BASF AG

Inventor： BROECKER FRANZ JOSEF ,  HENERS JUERGEN ,  MAROSI LASZLO ,  SCHWARZMANN MATTHIAS ,  LAURER PETER RUDOLF

IPC: B01J23/72 ,  B01J23/74 ,  B01J23/745 ,  C11C3/12 ,  B01J11/22

CPC classification number: B01J23/745 ,  B01J23/72 ,  B01J23/74 ,  C11C3/12

Abstract: The double salt Ni6Al2(OH)16 - CO3 - 4H2O is obtained from an aqueous solution containing nickel and aluminum salts by precipitation with alkali metal carbonate or bicarbonate. This double salt (catalyst precursor) is dried, calcined and reduced. There is thus obtained a catalyst which is suitable for the selective hydrogenation of fats and oils.

公开(公告)号：AT270134T

公开(公告)日：2004-07-15

申请号：AT01969739

申请日：2001-09-19

Applicant: BASF AG

Inventor： KAIBEL GERD ,  OOST CARSTEN ,  STROEZEL MANFRED ,  MEYER GERALD ,  TRUEBENBACH PETER ,  SARTOR KARL-HEINZ ,  HENERS JUERGEN

IPC: B01D3/14 ,  B01D3/32 ,  B01D3/42 ,  C07B63/00 ,  C10G7/00 ,  C10G7/02 ,  C10G7/12

Abstract: A process is proposed for the separation of C 5+ cuts by distillation into a low-boiler (A), a medium-boiler (B) and a high-boiler fraction (C) in one or more dividing-wall columns (TK), in which a dividing wall (T) is arranged in the longitudinal direction of the column with formation of an upper, common column region ( 1 ), a lower, common column region ( 6 ), a feed part ( 2, 4 ) with rectifying section ( 2 ) and stripping section ( 4 ), and a withdrawal part ( 3, 5 ) with rectifying section ( 5 ) and stripping section ( 3 ), with feed of the C 5+ cut (A, B, C) into the central region of the feed part ( 2, 4 ), discharge of the high-boiler fraction (C) from the bottom of the column, discharge of the low-boiler fraction (A) via the top of the column, and discharge of the medium-boiler fraction (B) from the central region of the withdrawal part ( 3, 5 ), wherein the dividing ratio of the liquid reflux at the upper end of the dividing wall (T) is set in such a way that the proportion of high-boiling key components in the liquid reflux over the stripping section ( 3 ) of the withdrawal part at the upper end of the dividing wall (T) is from 10 to 80%, preferably from 30 to 50%, of the limit value allowed in the medium-boiler fraction (B), and wherein the heating power in the evaporator at the bottom of the dividing-wall column (TK) is set in such a way that the concentration of the low-boiling key components in the liquid at the lower end of the dividing wall (T) is from 10 to 80%, preferably from 30 to 50%, of the limit value allowed in the medium-boiler fraction (B).

公开(公告)号：DE50102763D1

公开(公告)日：2004-08-05

申请号：DE50102763

申请日：2001-09-19

Applicant: BASF AG

Inventor： KAIBEL GERD ,  OOST CARSTEN ,  STROEZEL MANFRED ,  MEYER GERALD ,  TRUEBENBACH PETER ,  SARTOR KARL-HEINZ ,  HENERS JUERGEN

IPC: B01D3/14 ,  B01D3/32 ,  B01D3/42 ,  C07B63/00 ,  C10G7/00 ,  C10G7/02 ,  C10G7/12

Abstract: A process is proposed for the separation of C 5+ cuts by distillation into a low-boiler (A), a medium-boiler (B) and a high-boiler fraction (C) in one or more dividing-wall columns (TK), in which a dividing wall (T) is arranged in the longitudinal direction of the column with formation of an upper, common column region ( 1 ), a lower, common column region ( 6 ), a feed part ( 2, 4 ) with rectifying section ( 2 ) and stripping section ( 4 ), and a withdrawal part ( 3, 5 ) with rectifying section ( 5 ) and stripping section ( 3 ), with feed of the C 5+ cut (A, B, C) into the central region of the feed part ( 2, 4 ), discharge of the high-boiler fraction (C) from the bottom of the column, discharge of the low-boiler fraction (A) via the top of the column, and discharge of the medium-boiler fraction (B) from the central region of the withdrawal part ( 3, 5 ), wherein the dividing ratio of the liquid reflux at the upper end of the dividing wall (T) is set in such a way that the proportion of high-boiling key components in the liquid reflux over the stripping section ( 3 ) of the withdrawal part at the upper end of the dividing wall (T) is from 10 to 80%, preferably from 30 to 50%, of the limit value allowed in the medium-boiler fraction (B), and wherein the heating power in the evaporator at the bottom of the dividing-wall column (TK) is set in such a way that the concentration of the low-boiling key components in the liquid at the lower end of the dividing wall (T) is from 10 to 80%, preferably from 30 to 50%, of the limit value allowed in the medium-boiler fraction (B).

公开(公告)号：DE10046609A1

公开(公告)日：2002-04-04

申请号：DE10046609

申请日：2000-09-20

Applicant: BASF AG

Inventor： KAIBEL GERD ,  OOST CARSTEN ,  STROEZEL MANFRED ,  MEYER GERALD ,  TRUEBENBACH PETER ,  SARTOR KARL-HEINZ ,  HENERS JUERGEN

IPC: B01D3/14 ,  B01D3/32 ,  B01D3/42 ,  C07B63/00 ,  C10G7/00 ,  C10G7/02 ,  C10G7/12 ,  C07C7/04 ,  B01D3/00

Abstract: The invention relates to a method for carrying out the distillative separation of C5+ cuts into a low boiler fraction (A), a medium boiler fraction (B) and into a high boiler fraction (C) inside one or more partition columns (TK). A partition (T) is arranged inside said partition column(s) in a longitudinal direction of the column(s) while forming an upper common column area (1), a lower common column area (6), a feed part (2, 4) having a reinforcing part (2) and stripping part (4), as well as while forming a withdrawal part (3, 5) also having a reinforcing part (5) and stripping part (3). The inventive method involves the following steps: supplying the C5+ cuts (A, B, C) in the middle area of the feed part (2, 4); discharging the high boiler fraction (C) out of the bottom of the column; discharging the low boiler fraction (A) via the top of the column, and; discharging the middle boiler fraction (B) out of the middle area of the withdrawal part (3, 5). The dividing up ratio of the liquid reflux at the upper end of the partition (T) is set such that the proportion of high-boiling key constituents in the liquid reflux above the stripping part (3) of the withdrawal part at the upper end of the partition (T) ranges from 10 to 80 %, preferably, from 30 to 50 % of the limiting value permitted in the middle boiler fraction (B). In addition, the heating capacity in the bottom evaporator of the partition column (TK) is set such that the concentration of the light-boiling key constituents in the liquid at the lower end of the partition (T) ranges from 10 to 80 %, preferably, from 30 to 50 % of the limiting value permitted in the middle boiler fraction (B).