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公开(公告)号:DK1572613T3
公开(公告)日:2006-12-18
申请号:DK03785691
申请日:2003-12-01
Applicant: BASF AG
Inventor: MAYWALD VOLKER , HOFFMANN NICO , KEIL MICHAEL , VOGELBACHER UWE JOSEF , WEVERS JAN HENDRIK
IPC: C07C45/46 , C07C45/81 , C07C49/84 , C07C51/363 , C07C51/60
Abstract: A process for preparing benzophenones of the formula I, where X may be chlorine, hydroxyl, methoxy or C 1 -C 6 -alkylcarbonyloxy, and Y may be chlorine or bromine, by reacting an acid chloride of the formula II where X and Y are as defined above with 3,4,5-trimethoxytoluene, which comprises carrying out the reaction in the presence of a) an aromatic hydrocarbon as a diluent and b) from 0.01 to 0.2 mol % of an iron catalyst, based on the acid chloride, c) at a temperature between 60° C. and the boiling point of the particular diluent.
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公开(公告)号:BRPI0316844B1
公开(公告)日:2016-03-08
申请号:BR0316844
申请日:2003-12-01
Applicant: BASF AG
Inventor: WEVERS JAN HENDRIK , KEIL MICHAEL , HOFFMANN NICO , VOGELBACHER UWE JOSEF , MAYWALD VOLKER
IPC: C07C45/81 , C07C45/46 , C07C49/84 , C07C51/363 , C07C51/60
Abstract: "processo para preparar benzofenonas". um processo para preparar benzofenonas de fórmula i, em que x pode ser cloro, hidroxila, metoxi ou c~ 1~-c~ 6~-alquilcarbonilóxi, e y pode ser cloro ou bromo, reagindo um cloreto ácido de fórmula ii em que x e y são como definidos acima com 3,4,5-trimetoxitolueno, que compreende efetuar a reação na presença de a) um hidrocarboneto aromático como um diluente e b) de 0,0 1 a 0,2 % molar de um catalisador contendo ferro, com base no cloreto ácido, c) em temperatura entre 60 c e o ponto de ebulição do diluente usado.
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公开(公告)号:CA2508714C
公开(公告)日:2011-04-05
申请号:CA2508714
申请日:2003-12-01
Applicant: BASF AG
Inventor: MAYWALD VOLKER , HOFFMANN NICO , KEIL MICHAEL , VOGELBACHER UWE JOSEF , WEVERS JAN HENDRIK
IPC: C07C45/46 , C07C45/81 , C07C49/84 , C07C51/363 , C07C51/60
Abstract: Disclosed is a method for producing benzophenones of formula I, wherein X can represent chlorine, hydroxy, methoxy, or C1-C6 alkylcarbonyloxy while Y represents chlorine or bromine, by reacting an acid chloride of formula II, wherein X and Y have the meaning mentioned above, with 3,4,5-trimethoxytoluene. The inventive method is characterized by the fact that the reaction is carried out in the presence of a) an aromatic hydrocarbon as a thinner, and b) 0.01 to 0.2 mole percent of an iron catalyst, the percentage being in relation to the acid chloride, c) at a temperature ranging between 60oC and the boiling point of the respective thinner.
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公开(公告)号:AU2003294750B2
公开(公告)日:2010-04-01
申请号:AU2003294750
申请日:2003-12-01
Applicant: BASF AG
Inventor: KEIL MICHAEL , WEVERS JAN HENDRIK , HOFFMANN NICO , VOGELBACHER UWE JOSEF , MAYWALD VOLKER
IPC: C07C45/46 , C07C45/81 , C07C51/363 , C07C51/60
Abstract: A process for preparing benzophenones of the formula I, where X may be chlorine, hydroxyl, methoxy or C 1 -C 6 -alkylcarbonyloxy, and Y may be chlorine or bromine, by reacting an acid chloride of the formula II where X and Y are as defined above with 3,4,5-trimethoxytoluene, which comprises carrying out the reaction in the presence of a) an aromatic hydrocarbon as a diluent and b) from 0.01 to 0.2 mol % of an iron catalyst, based on the acid chloride, c) at a temperature between 60° C. and the boiling point of the particular diluent.
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公开(公告)号:CA2508714A1
公开(公告)日:2004-07-01
申请号:CA2508714
申请日:2003-12-01
Applicant: BASF AG
Inventor: VOGELBACHER UWE JOSEF , MAYWALD VOLKER , HOFFMANN NICO , KEIL MICHAEL , WEVERS JAN HENDRIK
IPC: C07C45/46 , C07C45/81 , C07C51/363 , C07C51/60 , C07C49/84
Abstract: Disclosed is a method for producing benzophenones of formula I, wherein X ca n represent chlorine, hydroxy, methoxy, or C1-C6 alkylcarbonyloxy while Y represents chlorine or bromine, by reacting an acid chloride of formula II, wherein X and Y have the meaning mentioned above, with 3,4,5- trimethoxytoluene. The inventive method is characterized by the fact that th e reaction is carried out in the presence of a) an aromatic hydrocarbon as a thinner, and b) 0.01 to 0.2 mole percent of an iron catalyst, the percentage being in relation to the acid chloride, c) at a temperature ranging between 60oC and the boiling point of the respective thinner.
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公开(公告)号:ES2271675T3
公开(公告)日:2007-04-16
申请号:ES03785691
申请日:2003-12-01
Applicant: BASF AG
Inventor: MAYWALD VOLKER , HOFFMANN NICO , KEIL MICHAEL , VOGELBACHER UWE JOSEF , WEVERS JAN HENDRIK
IPC: C07C45/46 , C07C45/81 , C07C49/84 , C07C51/363 , C07C51/60
Abstract: Procedimiento para la obtención de benzofenonas de la fórmula I (Ver fórmula) en la que X puede significar cloro, hidroxi, metoxi o alquilcarboniloxi con 1 a 6 átomos de carbono e Y puede significar cloro o bromo, mediante reacción de un cloruro de ácido de la fórmula II (Ver fórmula) en la que X e Y tienen el significado anteriormente indicado, con 3, 4, 5-trimetoxitolueno, caracterizado porque la reacción se lleva a cabo en presencia de a) un hidrocarburo aromático elegido del grupo formado por: el clorobenceno, el trifluoruro de benceno y el nitrobenceno como diluyente y b) desde un 0, 01 hasta un 0, 2% en moles, referido al cloruro de ácido, de un catalizador de hierro, c) a una temperatura que está comprendida entre 60ºC y el punto de ebullición del diluyente correspondiente.
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公开(公告)号:SI1572613T1
公开(公告)日:2006-10-31
申请号:SI200330423
申请日:2003-12-01
Applicant: BASF AG
Inventor: MAYWALD VOLKER , HOFFMANN NICO , KEIL MICHAEL , VOGELBACHER UWE JOSEF , WEVERS JAN HENDRIK
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公开(公告)号:DE50304687D1
公开(公告)日:2006-09-28
申请号:DE50304687
申请日:2003-12-01
Applicant: BASF AG
Inventor: MAYWALD VOLKER , HOFFMANN NICO , KEIL MICHAEL , VOGELBACHER JOSEF , WEVERS HENDRIK
IPC: C07C45/46 , C07C45/81 , C07C49/84 , C07C51/363 , C07C51/60
Abstract: A process for preparing benzophenones of the formula I, where X may be chlorine, hydroxyl, methoxy or C 1 -C 6 -alkylcarbonyloxy, and Y may be chlorine or bromine, by reacting an acid chloride of the formula II where X and Y are as defined above with 3,4,5-trimethoxytoluene, which comprises carrying out the reaction in the presence of a) an aromatic hydrocarbon as a diluent and b) from 0.01 to 0.2 mol % of an iron catalyst, based on the acid chloride, c) at a temperature between 60° C. and the boiling point of the particular diluent.
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公开(公告)号:PL206020B1
公开(公告)日:2010-06-30
申请号:PL37794303
申请日:2003-12-01
Applicant: BASF AG
Inventor: MAYWALD VOLKER , HOFFMANN NICO , KEIL MICHAEL , VOGELBACHER UWE JOSEF , WEVERS JAN HENDRIK
IPC: C07C45/46 , C07C45/81 , C07C49/84 , C07C51/363 , C07C51/60
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公开(公告)号:ZA200505574B
公开(公告)日:2006-09-27
申请号:ZA200505574
申请日:2005-07-12
Applicant: BASF AG
Inventor: MAYWALD VOLKER , KEIL MICHAEL , VOGELBACHER UWE JOSEF , WEVERS JAN HENDRIK , HOFFMANN NICO
IPC: C07C20060101 , C07C45/46 , C07C45/81 , C07C51/363 , C07C51/60
Abstract: A process for preparing benzophenones of the formula I, where X may be chlorine, hydroxyl, methoxy or C 1 -C 6 -alkylcarbonyloxy, and Y may be chlorine or bromine, by reacting an acid chloride of the formula II where X and Y are as defined above with 3,4,5-trimethoxytoluene, which comprises carrying out the reaction in the presence of a) an aromatic hydrocarbon as a diluent and b) from 0.01 to 0.2 mol % of an iron catalyst, based on the acid chloride, c) at a temperature between 60° C. and the boiling point of the particular diluent.
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