公开(公告)号：DE1296642B

公开(公告)日：1969-06-04

申请号：DEB0083963

申请日：1965-10-01

Applicant: BASF AG

Inventor： KOENIG ,  KARL-HEINZ DR ,  POMMER ,  HORST DR

IPC: C07C227/08

公开(公告)号：DE1294950B

公开(公告)日：1969-05-14

申请号：DEB0090068

申请日：1966-11-30

Applicant: BASF AG

Inventor： KERBER ,  HORST DR ,  HAGEN ,  WERNER DR ,  SCHROEDER ,  WOLFGANG DR

IPC: C07C27/22 ,  C07C29/16 ,  C07C45/50 ,  C07C45/78

Abstract: 1,195,877. Separation of vaporous aldehydes obtained in the oxo process. BADISCHE ANILIN- & SODA FABRIK A.G. 29 Nov., 1967 [30 Nov., 1966], No. 54282/67. Heading C2C. Vaporous aldehydes are separated from offgas formed in the oxo process, by scrubbing the offgas with an oxonation product boiling above 95‹ C. and/or a hydrogenated oxonation product boiling above 95‹ C. Preferably 0À1-2 kg. of the scrubbing material is used per cubic metre of offgas to be scrubbed. Examples recover (a) propionaldehyde by scrubbing the oxo product obtained from ethylene, carbon monoxide and water with a mixture comprising npropanol, para-propionaldehyde and higher boiling condensation products of propionaldehyde, (b) n - butyraldehyde and isobutyraldehyde. Valeraldehyde is also particularly suitable for separation by the method of the invention.

公开(公告)号：DE1293154B

公开(公告)日：1969-04-24

申请号：DEB0093975

申请日：1967-08-16

Applicant: BASF AG

Inventor： PASEDACH ,  HEINRICH DR ,  HOFFMANN ,  WERNER DR ,  POMMER ,  HORST DR

IPC: C07C29/17 ,  C07C29/42 ,  C11B9/00

公开(公告)号：DE1286020B

公开(公告)日：1969-01-02

申请号：DEB0095456

申请日：1967-11-17

Applicant: BASF AG

Inventor： POMMER ,  HORST DR ,  MUELLER ,  HERBERT DR ,  OVERWIEN ,  HERMANN DR

IPC: C07C45/71 ,  C07C49/203

公开(公告)号：DE1301806B

公开(公告)日：1969-08-28

申请号：DEB0095929

申请日：1967-12-20

Applicant: BASF AG

Inventor： KERBERT ,  HORST DR ,  HOHENSCHUTZ ,  HEINZ DR ,  RAUCH ,  KONRAD DR ,  SCHEIDMEIR ,  WALTER DR

IPC: C07C27/22 ,  C07C29/80

公开(公告)号：DE1297597B

公开(公告)日：1969-06-19

申请号：DEB0093850

申请日：1967-08-08

Applicant: BASF AG

Inventor： FISCHER ,  ROMAN DR ,  POMMER ,  HORST DR

IPC: C07C20060101 ,  C07C69/145

公开(公告)号：DE1290122B

公开(公告)日：1969-03-06

申请号：DEB0088584

申请日：1966-08-23

Applicant: BASF AG

Inventor： BAUMEISTER ,  WILHELM DR ,  HOHENSCHUTZ ,  HEINZ DR ,  KERBER ,  HORST DR ,  SCHEIDMEIR ,  WALTER DR

IPC: C07C29/88 ,  C07C31/04

公开(公告)号：DE1286019B

公开(公告)日：1969-01-02

申请号：DEB0091039

申请日：1967-02-04

Applicant: BASF AG

Inventor： POMMER ,  HORST DR ,  REIF ,  WERNER DR ,  PASEDACH ,  HEINRICH DR ,  HOFFMANN

IPC: C07C45/67

公开(公告)号：DE1286018B

公开(公告)日：1969-01-02

申请号：DEB0091038

申请日：1967-02-04

Applicant: BASF AG

Inventor： POMMER ,  HORST DR ,  REIF ,  WERNER DR ,  PASEDACH ,  HEINRICH DR ,  HOFFMANN

IPC: C07C45/67 ,  C07C49/20 ,  C07C403/00

Abstract: Production of beta -ionone by reaction of 3,7-dimethylocten-(7)-yn-(1)-ol-(3) with a lower alkanol ester of acetoacetic acid at a temperature of from 100 DEG to 400 DEG C and treating the reaction mixture with an acid catalyst at a temperature of from 100 DEG to 400 DEG C and cyclizing the 6,10-dimethylundecatrien-(3,5,10)-one-(2) obtained by contacting with concentrated sulfuric acid at temperatures of from -30 to +20 DEG C.