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公开(公告)号:DE2747334A1
公开(公告)日:1979-05-03
申请号:DE2747334
申请日:1977-10-21
Applicant: BASF AG
IPC: C25D13/22
Abstract: Novel anodes consist of a mixture of from 30 to 95% by weight of nagnetite, lead dioxide, magnetite/natural graphite mixture or lead dioxide/natural graphite mixture and from 70 to 5% by weight of a plastic. They may be used for the surface-coating of metallic substrates by cathodic electrocoating.
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公开(公告)号:DE3118418A1
公开(公告)日:1982-11-25
申请号:DE3118418
申请日:1981-05-09
Applicant: BASF AG
Inventor: SCHENCK HANS-UWE DIPL CHEM DR , GULBINS ERICH DIPL CHEM DR , KEMPTER FRITZ ERDMANN DIPL CHE , SCHUPP EBERHARD DIPL CHEM DR , BLUM RAINER
Abstract: An aqueous cationic surface-coating system contains an olefinically unsaturated surface-coating binder having basic nitrogen groups, some or all of which are converted into salts with acid, a Co, Mn, Pb, Ce, Zr, Ca, Zn, Fe, Al, Cu, Ni or Cd complex, if appropriate in combination with an inhibitor and/or an initiator which supplies free radicals. This surface-coating system can be used for cathodic electrocoating or for conventional methods of surface-coating.
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公开(公告)号:DE3021300A1
公开(公告)日:1981-12-24
申请号:DE3021300
申请日:1980-06-06
Applicant: BASF AG
Inventor: SCHUPP EBERHARD DIPL CHEM DR , KEMPTER FRITZ ERDMANN DIPL CHE , GULBINS ERICH DIPL CHEM DR
IPC: C08G59/00 , C08G14/06 , C08G59/06 , C08G59/14 , C08G59/18 , C08G59/40 , C08G59/64 , C08L63/00 , C09D5/44 , C09D163/00 , C25D13/06 , C09D5/40
Abstract: A process for the preparation of curable polyadducts, possessing basic nitrogen groups, wherein (A) monophenols and/or polyphenols, which contain groups of the general formula (I): where R1 and R2 are identical or different and each is hydrogen or methyl are reacted with (B) amines having one or more primary and/or secondary amino groups, and the adduct formed is reacted with (C) epoxide compounds having from 1 to 4 epoxide groups per molecule and having a molecular weight of at most 2,500, the ratio of the phenolic hydroxyl groups of (A) to epoxide groups of (C) being from 1:0.5 to 1:2 and the amine (B) being employed in such amount that the resulting polyadduct of (A), (B) and (C) contains from 0.1 to 5% by weight of basic nitrogen, and the use of the products, after protonation with an acid, as binders for the production of coatings, especially for the cathodic electrocoating of metal articles.
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公开(公告)号:DE2845988A1
公开(公告)日:1980-04-24
申请号:DE2845988
申请日:1978-10-23
Applicant: BASF AG
Inventor: KEMPTER FRITZ ERDMANN DIPL CHE , SCHUPP EBERHARD DIPL CHEM DR , GULBINS ERICH DIPL CHEM DR
IPC: C08G18/00 , C08G18/08 , C08G18/65 , C08G18/66 , C08G18/80 , C09D5/44 , C09D175/08 , C25D13/06 , C09D5/40 , C09D3/72
Abstract: A process for the preparation of self-crosslinking, cathodic electrocoating binders by reacting polyether-polyols, which may or may not contain thio groups, with semi-blocked diisocyanates or partially blocked polyisocyanates, wherein the reaction products (A), containing blocked isocyanate groups, are reacted with a polyamine (B), some of whose amino groups may or may not be in the form of ketimine groups, in such a way that one or more amino groups of the polyamine (B) form a urea group with a blocked isocyanate group of the reaction product (A), and the self-cross-linking reaction product of (A) and (B) is converted into a water-dilutable form in the conventional manner by protonization with an acid. The coating binders prepared according to the invention may be used for cathodic electrocoating of metal articles.
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公开(公告)号:DE2942488A1
公开(公告)日:1981-04-30
申请号:DE2942488
申请日:1979-10-20
Applicant: BASF AG
Inventor: SCHUPP EBERHARD DIPL CHEM DR , KEMPTER FRITZ ERDMANN DIPL CHE , GULBINS ERICH DIPL CHEM DR
IPC: C08G59/00 , C08G59/14 , C08G59/56 , C08G59/62 , C09D5/44 , C09D163/00 , C25D13/06 , C08G59/18 , C09D3/80 , C09D5/40
Abstract: The invention concerns polyadducts and their use. The polyadducts, possessing nitrogen-basic groups, have a mean molecular weight of from 500 to 10,000 and contain groups, attached to aromatic rings, of the general formula (I) (I) where R1 and R2 are identical or different and each is hydrogen or methyl. In particular, these polyadducts are used, after protonizing with an acid, as binders for the cathodic electrocoating of metal articles.
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