公开(公告)号：WO03039254A8

公开(公告)日：2004-05-21

申请号：PCT/EP0212401

申请日：2002-11-06

Applicant: BASF AG ,  SYMYX TECHNOLOGIES INC ,  KOLTZENBURG SEBASTIAN ,  SCHROF WOLFGANG ,  SEUFERT MICHAEL ,  HEGER ROBERT ,  LEHMANN STEPHAN ,  KARDORFF UWE ,  ZAGAR CYRILL ,  BRATZ MATTHIAS ,  CARLSON ERIC D ,  CHANG HAN TING ,  KUEBLER SIGRID C

Inventor： KOLTZENBURG SEBASTIAN ,  SCHROF WOLFGANG ,  SEUFERT MICHAEL ,  HEGER ROBERT ,  LEHMANN STEPHAN ,  KARDORFF UWE ,  ZAGAR CYRILL ,  BRATZ MATTHIAS ,  CARLSON ERIC D ,  CHANG HAN TING ,  KUEBLER SIGRID C

IPC: A01N43/38 ,  A01N25/04 ,  A01N25/10 ,  A01N37/32 ,  A01N37/46 ,  C08F220/60

CPC classification number: A01N25/10 ,  A01N37/32 ,  A01N37/46 ,  A01N25/12 ,  A01N25/04 ,  A01N2300/00 ,  A01N25/14

Abstract: The invention relates to a solid crop protection formulation comprising a) cinidon-ethyl as a crop protection agent; b) at least one random radical copolymer comprising as polymerized units at least one hydrophilic and at least one hydrophobic monomer; and c) optionally further additives, wherein at least 50 % of the dispersed cinidon-ethyl particles in said solid crop protection formulation are in an X-ray amorphous state and an aqueous dispersion formulation thereof. Additionally, the invention relates to processes for preparing said formulations and the use of said formulations in agriculture. Further, the invention relates to a random radical copolymer essentially consisting of as polymerized units a) 5 to 95 % by weight of styrene as component A; b) 5 to 95 % by weight of DMAPMAM (dimethylaminopropyl methacrylic amide) as component B; c) 0 to 98 % by weight of methyl acrylate and/or vinyl acetate as component C.

Abstract translation: 本发明涉及一种固体作物保护制剂，其包含a）作为作物保护剂的cinidon-ethyl; b）至少一种含有至少一种亲水和至少一种疏水单体作为聚合单元的无规自由基共聚物; 和c）任选的其它添加剂，其中所述固体作物保护制剂中至少50％的分散的cinidon-ethyl颗粒是X射线非晶态，以及其水分散体制剂。 此外，本发明涉及制备所述制剂的方法和所述制剂在农业中的用途。 此外，本发明涉及一种基本上由作为聚合单元a）5至95重量％的作为组分A的苯乙烯组成的无规自由基共聚物; b）5至95重量％的作为组分B的DMAPMAM（二甲基氨基丙基甲基丙烯酰胺）; c）0至98重量％的丙烯酸甲酯和/或作为组分C的乙酸乙烯酯。

公开(公告)号：WO03029784A2

公开(公告)日：2003-04-10

申请号：PCT/EP0210910

申请日：2002-09-27

Applicant: BASF AG ,  SCHROF WOLFGANG ,  MUELLER THORSTEN ,  KOLTZENBURG SEBASTIAN ,  KRONER MATTHIAS ,  LEHMANN STEPHAN ,  HADELER JOACHIM

Inventor： SCHROF WOLFGANG ,  MUELLER THORSTEN ,  KOLTZENBURG SEBASTIAN ,  KRONER MATTHIAS ,  LEHMANN STEPHAN ,  HADELER JOACHIM

IPC: G01N11/00 ,  G01N3/00 ,  G01N3/06 ,  G01N3/42

CPC classification number: G01N3/42 ,  G01N2203/0092 ,  G01N2203/0682

Abstract: The invention relates to a method for combined analysis of the hardening of hardenable liquid or viscous formulations, wherein (a) n hardenable formulations are provided in parallel in n containers, and (b) at least one degree of hardening is determined for each of the n formulations, wherein a measuring tip is inserted into the formulation with a determined amount of force and the maximum penetration depth thus obtained is taken as a measure of the degree of hardening of said formulations, and (c) one or several parameters characterizing the hardening kinetics are determined for a respective composition of the formulations from the measured values for the depths of penetration at various times after the production of the formulations . Preferably, steps (a) - (c) are carried out on several occasions and by analyzing the large number of individual values of the parameters characterizing the hardening characteristics thus obtained, it is possible to ascertain the dependency of the characteristic parameter(s) in relation to the composition of the formulations, whereupon the composition of the formulations can be optimized with regard to the hardening behavior thereof.

Abstract translation: 本发明涉及一种方法，用于在其中设置在平行于正固化配方可固化液体或粘性制剂的固化的组合研究ÑBehäitern的（a）和（b）固化的程度anjeder所述n制剂至少一次测定， 通过测量末端以一定的力刺穿制剂和达到制剂的固化度的最大穿透深度AIS度量被测量，和制备所述制剂的后（c）对于每个由用于在不同时间的穿透深度的测量值的制剂的组合物的 或固化参数的动力学的多个特征被确定第二十 根据所述步骤（a）（c）是优选进行多次，它是由这样获得的大量的一种或硬化参数的动力学特性的个体值的分析来确定是的函数，或制剂的组合物的特征参数 由此制剂的组合物可以相对于它们的固化行为进行优化。

公开(公告)号：WO0214377A3

公开(公告)日：2002-06-20

申请号：PCT/EP0109469

申请日：2001-08-16

Applicant: BASF AG ,  SYMYX TECHNOLOGIES INC

Inventor： SCHROF WOLFGANG ,  SEUFERT MICHAEL ,  HEGER ROBERT ,  IDEN RUEDIGER ,  HORN DIETER ,  KOLTZENBURG SEBASTIAN ,  NIELSEN RALPH B ,  CARLSON ERIC ,  CHANG HAN-TING ,  PETRO MIROSLAV ,  KUEBLER SIGRID

IPC: B82B3/00 ,  C08F2/00 ,  C08F212/08 ,  B01J19/00

CPC classification number: C08F2/00 ,  C08F212/08 ,  C08F220/06 ,  C08F226/06

Abstract: Disclosed is a method of making an array of n nanoparticular dispersion formulations, wherein said nanoparticular dispersion formulations each comprise -at least one nanodispersant, -at least one application media, -an active ingredient said method comprising the following steps: c) making said array of n nanoparticular dispersion formulations by c1) a parallelized solid solution route, or c2) a parallelized general precipitation route, or c3) a parallelized reactive precipitation route, d) parallelized, rapid serial or semi-parallel characterizing of said obtained n nanoparticular dispersion formulations; an array of at least 8 different nanoparticular dispersion formulations; a method of making an array of m nanodipersants by a parallel polymerization process; an array of at least 8 different nanodispersants; a method of making an array of n solid solutions by a parallelized solid solution route; and an array of at least 8 different.

Abstract translation: 公开了制备n个纳米颗粒分散体制剂阵列的方法，其中所述纳米颗粒分散体制剂各自包含至少一个纳米分散剂 - 至少一种施用介质 - 活性成分，所述方法包括以下步骤：c）制备所述阵列 通过c1）平行化固溶体途径，或c2）平行化的一般沉淀途径，或c3）平行化的反应沉淀途径，d）所述获得的n个纳米颗粒分散体配方的平行，快速连续或半平行表征 ; 至少8种不同的纳米粒子分散体配方的阵列; 通过平行聚合方法制备m纳米二极体阵列的方法; 至少8种不同的纳米分散剂阵列; 通过并行固溶途径制备n个固溶体阵列的方法; 和至少8个不同的阵列。

公开(公告)号：WO2006111327A2

公开(公告)日：2006-10-26

申请号：PCT/EP2006003429

申请日：2006-04-13

Applicant: BASF AG ,  KOLTZENBURG SEBASTIAN ,  DOMBO PETER ,  OETTER GUENTER ,  KRUEGER CHRISTIAN ,  SCHROF WOLFGANG ,  BRATZ MATTHIAS

Inventor： KOLTZENBURG SEBASTIAN ,  DOMBO PETER ,  OETTER GUENTER ,  KRUEGER CHRISTIAN ,  SCHROF WOLFGANG ,  BRATZ MATTHIAS

IPC: A01N25/10 ,  A01N25/14 ,  A01N43/653 ,  A01N47/24 ,  A01N47/38 ,  A01P3/00 ,  C08F228/02

CPC classification number: C08F220/60 ,  A01N25/10 ,  A01N25/14 ,  A01N43/653 ,  C08F220/18 ,  C08F220/38 ,  A01N2300/00

Abstract: The invention relates to preparations, in particular plant-protective preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active plant-protective substance (active substance 2) whose water solubility at a temperature of 20 °C is less than 20 g/l., c) at least one type of copolymer CP consisting of M monomers comprising a) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and ß) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant-protective substance 2 ranges from 1:10 to 10:1. Said invention also relates to novel copolymers CP which are embodied in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerisation incorporated form, a) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group, ß1) at least one type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20 °C is less than 30 g/l and ß2) at least one type of neutral monoethylenically unsaturated monomer M2b whose water solubility at a temperature of 20 °C is greater than 50 g/l.

Abstract translation: 本发明涉及一种制剂，在用于作物保护特定制剂，其包含至少两个彼此不同的植物保护剂的混合物，其特征在于，a）从所述组conazoles的（活性成分1）至少一种活性物质被选择，和b）至少一个另外的作物保护活性化合物（活性成分2） 水在20℃下具有低于20克/升，其中，还含有c）至少一个烯属不饱和单体M共聚物CP建立起来，其中所述单体M的溶解度a）至少一种单烯属不饱和单体M1，其具有至少一个磺酸基团，和β）至少 包括中性的，单烯键式不饱和单体M2，其特征在于，活性成分1与至少一个另外的作物保护剂2在范围1：1的比例：10〜10度。 本发明还涉及新型共聚物CP，在至少三个彼此不同的单烯属不饱和单体的晶型M结构聚合物，其包括以共聚形式：a）至少一种单烯属不饱和单体M1，其具有至少一个磺酸基团，SS1）至少一种中性的，单烯键 不饱和单体M2A，其在水中具有在200℃下低于30克/升的溶解度，和SS2）至少一种中性，单烯属不饱和单体M2b的，其具有在20℃下在水中的溶解度高于50克/升。

公开(公告)号：WO2008052835A3

公开(公告)日：2008-06-19

申请号：PCT/EP2007059520

申请日：2007-09-11

Applicant: BOSCH GMBH ROBERT ,  BASF AG ,  BRINZ THOMAS ,  LEWIS JANE ,  TIEFENBACHER MARKUS ,  GEIGER THOMAS ,  BURK TOBIAS ,  WAGNER EVA ,  KOLTZENBURG SEBASTIAN ,  SCHROF WOLFGANG

Inventor： BRINZ THOMAS ,  LEWIS JANE ,  TIEFENBACHER MARKUS ,  GEIGER THOMAS ,  BURK TOBIAS ,  WAGNER EVA ,  KOLTZENBURG SEBASTIAN ,  SCHROF WOLFGANG

IPC: G01N25/72

CPC classification number: G01N25/72

Abstract: The invention relates to a method for evaluating mechanical tests of a coating on a substrate, wherein a mechanical stress is embossed on the coating in a first step (S1), the substrate with the coating is clamped in isothermically in a second step (S2), and an infrared picture of the region where the mechanical stress is embossed in the first step (S1) is taken. In a fourth step (S4), the infrared picture is evaluated. The invention further relates to a device for executing said method.

Abstract translation: 本发明涉及一种用于评估基底上的涂层的机械测试的方法，其中在第一步骤（S1）中将机械负载施加至涂层，在第二步骤（S2）中，基底与涂层等温地夹紧 第三步骤（S3）产生施加第一步骤（S1）中的涂层上的机械应力的区域的红外图像，并且在第四步骤（S4）中，评估红外图像。 本发明还涉及用于执行该方法的设备。

公开(公告)号：CR20140539A

公开(公告)日：2015-01-12

申请号：CR20140539

申请日：2014-11-25

Applicant: BASF AG

Inventor： KOLTZENBURG SEBASTIAN ,  DOMBO PETER ,  OETTER GÜNTER ,  KRÜGER CHRISTIAN ,  SCHROF WOLFGANG ,  BRATZ MATTHIAS

IPC: A01N25/10 ,  A01N25/14 ,  A01N43/653 ,  A01N47/24 ,  A01N47/38 ,  A01P3/00 ,  C08F228/02

Abstract: La preparación se refiere a preparaciones, en particular a preparaciones para la fitoprotección, que contienen por lo menos un fungicida de conazol, en particular el epoxiconazol, y por lo menos otro principio activo.

公开(公告)号：MX2007012575A

公开(公告)日：2007-11-16

申请号：MX2007012575

申请日：2006-04-13

Applicant: BASF AG

Inventor： BRATZ MATTHIAS ,  SCHROF WOLFGANG ,  OETTER GUNTER ,  DOMBO PETER ,  KOLTZENBURG SEBASTIAN ,  KRUGER CHRISTIAN

IPC: A01N25/10 ,  A01N25/14 ,  A01N43/653 ,  A01N47/24 ,  A01N47/38 ,  A01P3/00 ,  C08F228/02

Abstract: La invencion se refiere a preparaciones, en particular aquellas destinadas a la fitoproteccion, que contienen una mezcla de por lo menos dos principios activos fitoprotectores diferentes el uno del otro, en las que a) por lo menos uno de los principios activos esta seleccionado de entre el grupo de los conazoles (principio activo 1) y b) el otro principio activo fitoprotector (principio activo 2), que es por lo menos uno, presenta en agua, a 20 degree C, una solubilidad inferior a los 20 g/l, y que contienen asimismo c) por lo menos un copolimero CP sintetizado a base de monomeros M etilenicamente insaturados, comprendiendo los monomeros M () por lo menos un monomero M1 monoetilenicamente insaturado que presenta por lo menos un grupo de acido sulfonico, y () por lo menos un monomero M2 neutro, monoetilenicamente insaturado, hallandose la relacion cuantitativa del principio activo 1 respecto al otro principio activo fitoprotector 2, que es por lo menos uno, dentro de un intervalo entre 1:10 y 10:1. La invencion se refiere ademas a nuevos copolimeros CP, en forma de polimeros sintetizados a base de por lo menos tres monomeros M monoetilenicamente insaturados y distintos entre si, que comprenden, en forma introducida por polimerizacion: () por lo menos un monomero M1, monoetilenicamente insaturado, que presenta por lo menos un grupo de acido solfonico; (1) por lo menos un monomero neutro M2a, monoetilenicamente insaturado, que presenta en agua, a 20 degree C, una solubilidad inferior a los 30 g/l, y (2) por lo menos un monomero neutro M2b, monoetilenicamente insaturado, que presenta en agua, a 20 degree C, una solubilidad superior a los 50 g/l.

公开(公告)号：BRPI0415902A

公开(公告)日：2007-01-16

申请号：BRPI0415902

申请日：2004-10-19

Applicant: BASF AG

Inventor： KOLTZENBURG SEBASTIAN ,  LEHMANN STEPHAN ,  STEINMETZ BERNHARD ,  SCHROF WOLFGANG ,  HADELER JOACHIM ,  MAYER WINFRIED ,  BRATZ MATTHIAS ,  GOEDEL WERNER

IPC: A01N25/04 ,  A01N25/30 ,  A01N47/24

Abstract: New active agent formulations contain active agent(s) (A); random radical copolymer(s) (B), derived from sulfoalkyl (meth)acrylate or N-sulfoalkyl-(meth)acrylamide monomer(s) (I) (and/or their salts), (meth)acrylate ester or N-substituted (meth)acrylamide monomer(s) (II) and optionally further monomers; and optionally further additives (C). New active agent formulations contain active agent(s) (A); random radical copolymer(s) (B), derived from olefinically unsaturated sulfonic acid(s) of formula (I) (and/or their salts), monomer(s) of formula H 2C=C(R 4>)-CO-YR 6> (II) and optionally further monomers; and optionally further additives (C). n : 0-10; X, Y : O or NR 5>; R 1>, R 4>H or Me; R 2>, R 3>H or 1-6C alkyl; R 5>, R 6>H, alkyl, aryl, alkylaryl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl (where aryl groups are optionally substituted). Independent claims are included for: (1) the preparation of aqueous dispersions, by contacting the formulations with aqueous systems (optionally in presence of additives) and dispersion conventionally; (2) the preparation of the formulations, by dissolving (A) - (C) and optionally further additives in an organic solvent (or dissolving the components separately in organic solvents then mixing the solutions), then conventionally removing the solvent; and (3) an alternative preparation of the formulations, by forming an aqueous solution of (B); dissolving (A), (C) (if present) and optionally further additives in water-miscible organic solvent(s); mixing the solutions; applying energy to form a dispersion; and conventionally removing the solvent. [Image].

公开(公告)号：CA2604496A1

公开(公告)日：2006-10-26

申请号：CA2604496

申请日：2006-04-13

Applicant: BASF AG

Inventor： BRATZ MATTHIAS ,  SCHROF WOLFGANG ,  KRUEGER CHRISTIAN ,  OETTER GUENTER ,  DOMBO PETER ,  KOLTZENBURG SEBASTIAN

IPC: A01N25/10 ,  A01N25/14 ,  A01N43/653 ,  A01N47/24 ,  A01N47/38 ,  A01P3/00 ,  C08F228/02

Abstract: The invention relates to preparations, in particular plant-protective preparations which contain a mixture of at least two different active plant- protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active plant- protective substance (active substance 2) whose water solubility at a temperature of 20 ~C is less than 20 g/l., c) at least one type of copolymer CP consisting of M monomers comprising .alpha.) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and .beta.) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant-protective substance 2 ranges from 1: 10 to 10:1. Said invention also relates to novel copolymers CP which are embodi ed in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerisation incorporated form, .alpha.) at least one type of monoethylenically unsaturat ed monomer M1 comprising at least one sulphonic acid group, .beta.1) at least o ne type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20 ~C is less than 30 g/l and .beta.2) at lea st one type of neutral monoethylenically unsaturated monomer M2b whose water solubility at a temperature of 20 ~C is greater than 50 g/l.

公开(公告)号：AU2006237133A1

公开(公告)日：2006-10-26

申请号：AU2006237133

申请日：2006-04-13

Applicant: BASF AG

Inventor： SCHROF WOLFGANG ,  KOLTZENBURG SEBASTIAN ,  DOMBO PETER ,  KRUGER CHRISTIAN ,  OETTER GUNTER ,  BRATZ MATTHIAS

IPC: A01N25/10 ,  A01N25/14 ,  A01N43/653 ,  A01N47/24 ,  A01N47/38 ,  A01P3/00 ,  C08F228/02

Abstract: Mixture (Q) comprises at least two plant protective active agent comprising at least a fungicidal active agent of conazole group (1), at least one plant protection active agent (2), exhibiting solubility in water of 20g/l at 20[deg]C and optionally a copolymer obtained form an ethylenic unsaturated monomer (M) of at least monoethylenic unsaturated monomer (M1) with at least one sulfonic acid group and at least neutral group, and monoethylenic unsaturated monomer (M2). The ratio of (1) and (2) is 1:10-10:1. An independent claim is included for a copolymer comprising a polymer formed from monoethylenic unsaturated monomers (M), at least a monoethylenic unsaturated monomer (M1) with at least one sulfonic acid and at least 1 neutral group and monoethylenic unsaturated monomers (M2a) and (M2b), exhibiting a solubility of less than 50 g/l at 20[deg]C. ACTIVITY : Fungicide. In a test for determining pathogenic fungicidal activity, results showed that a 1:3 mixture (32 ppm) of epoxiconazole and pyraclostrobin reduced the development of the fungus to 2%. MECHANISM OF ACTION : None given.