公开(公告)号：WO2007104603A3

公开(公告)日：2007-12-13

申请号：PCT/EP2007050906

申请日：2007-01-30

Applicant: BASF AG ,  KUEHLING KLAUS ,  HAASS FRANK

Inventor： KUEHLING KLAUS ,  HAASS FRANK

IPC: C01B19/00 ,  C04B35/515 ,  H01L35/16 ,  H01L35/22

CPC classification number: C01B19/002 ,  C01B19/007 ,  C01P2006/32 ,  C01P2006/40 ,  H01L35/16 ,  H01L35/22 ,  H01L35/34 ,  Y02P20/129

Abstract: The invention relates to a p- or n-conductive semi-conductor material composed of a ternary compound of general formula (I) Pb x Ge y Te z (I), wherein the indices x, y and z correspond to one of the following relationships: (a) x = 1 - y; z = 1; 0,05

Abstract translation: 公开的是从通式（I）的三元化合物一个p型或n型半导体材料的Pb _{X 锗ý碲ž（I） 其中索引x，y和z对应于以下关系之一：（a）x = 1-y; z = 1; 0.05}

公开(公告)号：WO2005114755A3

公开(公告)日：2006-05-11

申请号：PCT/EP2005005345

申请日：2005-05-17

Applicant: BASF AG ,  STERZEL HANS-JOSEF ,  KUEHLING KLAUS

Inventor： STERZEL HANS-JOSEF ,  KUEHLING KLAUS

IPC: H01L35/16 ,  H01L35/22

CPC classification number: H01L35/16 ,  C01B19/002 ,  C01B19/007 ,  C01P2002/50 ,  C01P2006/40 ,  H01L35/22

Abstract: The invention relates to thermoelectric generators or Peltier arrays which comprise a telluride as the thermoelectrically active semiconducting element. The inventive generators or Peltier arrays are characterized in that the positively polarized atoms of the crystal lattice of the telluride are partially replaced by silicon and/or germanium.

Abstract translation: 中描述的热电发电机或珀耳帖安排，碲化物作为热电活性半导体材料。 根据本发明的发电机或珀耳帖装置的特征在于，所述碲的晶格的正极化原子部分与硅和/或锗取代。

公开(公告)号：WO2007039553A3

公开(公告)日：2007-06-07

申请号：PCT/EP2006066867

申请日：2006-09-29

Applicant: BASF AG ,  STERZEL HANS-JOSEF ,  KUEHLING KLAUS

Inventor： STERZEL HANS-JOSEF ,  KUEHLING KLAUS

IPC: G02B5/20

CPC classification number: G02B6/1225 ,  B82Y20/00 ,  G01J1/04 ,  G01J1/0433 ,  G01J1/0488 ,  G01J5/06 ,  G01J2001/0276 ,  Y10T428/26 ,  Y10T428/269

Abstract: The invention relates to photonic crystals, which comprise units have a refractive index of more that 3 and units having a refractive index of less than 1.6 in a periodic sequence and distances of the individual units from 1 - 20 µm. The invention also relates to the use of said photonic crystals.

Abstract translation: 本发明涉及的光子晶体中，具有大于3的折射率的单元，并且在周期性序列和1至20微米的单个的单元的间隔有具有小于1.6的折射率单位，以及使用这些光子晶体。

公开(公告)号：WO2006027250A3

公开(公告)日：2006-06-15

申请号：PCT/EP2005009675

申请日：2005-09-08

Applicant: BASF AG ,  KUEHLING KLAUS ,  STERZEL HANS-JOSEF

Inventor： KUEHLING KLAUS ,  STERZEL HANS-JOSEF

IPC: H01L35/22

CPC classification number: H01L35/22

Abstract: A thermoelectric generator or a Peltier arrangement with a mixed oxide as thermoelectric material is disclosed, whereby the mixed oxide comprises the elements titanium, oxygen, sulphur and Me, where Me = calcium, strontium or barium.

Abstract translation: 本发明公开一种热电发电机或具有混合氧化物作为热电材料，其中，所述复合氧化物包含的元素钛，氧，硫的珀耳帖装置和Me我=钙，锶或钡。

公开(公告)号：WO2005114757A3

公开(公告)日：2006-06-08

申请号：PCT/EP2005005344

申请日：2005-05-17

Applicant: BASF AG ,  STERZEL HANS-JOSEF ,  KUEHLING KLAUS

Inventor： STERZEL HANS-JOSEF ,  KUEHLING KLAUS

IPC: H01L35/18 ,  H01L35/22

CPC classification number: H01L35/18 ,  H01L35/22

Abstract: The invention relates to ternary semiconducting alloys and thermoelectric generators and Peltier arrays comprising the same and to methods for producing the ternary semiconducting alloys. The ternary semiconducting alloys have band gaps smaller 0.8 eV. The ternary semiconducting alloy is derived from two binary parent compounds and one element of the ternary semiconducting alloy is contained in both binary parent compounds.

Abstract translation: 描述了一种制备三元半导体合金含有它们的三元半导体合金，热电发电机和珀尔帖装置和方法。 三元半导体合金具有小于0.8电子伏特，其中的两个二进制母体化合物的三元半导体合金推导和包含在两个二进制母体化合物的三元半导体合金的元素的带隙。

公开(公告)号：WO2006037498A3

公开(公告)日：2006-08-03

申请号：PCT/EP2005010363

申请日：2005-09-24

Applicant: BASF AG ,  STERZEL HANS-JOSEF ,  KUEHLING KLAUS

Inventor： STERZEL HANS-JOSEF ,  KUEHLING KLAUS

IPC: H01L35/08 ,  B23K20/10

CPC classification number: B23K35/007 ,  B23K20/10 ,  B23K2201/40 ,  H01L35/08

Abstract: The invention relates to contacting, in a temperature stable manner, semi-conductor alloys for use in thermoelectric generators and Peltier arrangements, by means of ultrasonic welding. The invention also relates to a method for the production of thermoelectric modules, preferably using a barrier layer made of borides, nitrides, carbides, phosphides and/or silicides.

Abstract translation: 本发明涉及一种半导体合金用于通过超声波焊接以及用于制造热电模块，优选使用的硼化物，氮化物，碳化物，磷化物和/或硅化物阻挡层的方法在热电发生器和珀尔贴装置使用的热稳定的接合。

公开(公告)号：WO2004090998A3

公开(公告)日：2004-12-16

申请号：PCT/EP2004003786

申请日：2004-04-08

Applicant: BASF AG ,  UNIV MICHIGAN STATE

Inventor： STERZEL HANS-JOSEF ,  KUEHLING KLAUS ,  KANATZIDIS MERCOURI G ,  CHUNG DUCK-YOUNG

IPC: H01L35/16 ,  H01L35/22

CPC classification number: H01L35/16 ,  H01L35/22

Abstract: A thermoelectrically active p- or n-conductive semiconductor material is constituted by a ternary compound of the general formula (Pb1-xGex)Te with x value from 0.16 to 0.5, wherein 0 to 10% by weight of the ternary compound may be replaced by other metals or metal compounds, wherein the semiconductor material has a Seebeck coefficient of at least ±200 µV/K at a temperature of 25 °C.

Abstract translation: 热电活性p型或n导电半导体材料由通式（Pb1-xGex）Te的三元化合物构成，x值为0.16至0.5，其中0至10重量％的三元化合物可以被 其它金属或金属化合物，其中半导体材料在25℃的温度下具有至少±200μV/ K的塞贝克系数。

公开(公告)号：DE10358075A1

公开(公告)日：2005-07-14

申请号：DE10358075

申请日：2003-12-10

Applicant: BASF AG

Inventor： UNGER GABRIELE ,  SCHOENFELDER HENDRIK ,  WATZENBERGER OTTO ,  STERZEL HANS-JOSEF ,  KUEHLING KLAUS

IPC: B01J31/02 ,  C01G49/16

Abstract: Production of iron pentacarbonyl by reaction of iron with carbon monoxide in a suspension is catalyzed by a polysulfide. Production of iron pentacarbonyl by reaction of iron with carbon monoxide in a suspension is catalyzed by a polysulfide of formula (I) RSxR> (I) R and R> are organic residues; and x = 2-10.

公开(公告)号：CA2488625A1

公开(公告)日：2005-06-10

申请号：CA2488625

申请日：2004-11-24

Applicant: BASF AG

Inventor： WATZENBERGER OTTO ,  STERZEL HANS-JOSEF ,  KUEHLING KLAUS ,  UNGER GABRIELE ,  SCHOENFELDER HENDRIK

IPC: B01J31/02 ,  C01G49/16

Abstract: Iron pentacarbonyl is prepared by reacting iron with carbon monoxide in suspension and in the presence of a polysulfide of the general formula RS x R' as a catalyst, where R is an organic radical and x is a number from 2 to 8.

公开(公告)号：DE10142634A1

公开(公告)日：2003-03-20

申请号：DE10142634

申请日：2001-08-31

Applicant: BASF AG

Inventor： STERZEL HANS-JOSEF ,  KUEHLING KLAUS

IPC: H01L35/16 ,  H01L35/22 ,  H01L35/14 ,  H01L35/28

Abstract: Thermoelectric generator or peltier arrangement comprises a thermoelectric semiconductor material made from a p-doped or n-doped semiconductor material of a ternary compound of formula (I), except ternary compounds of formula AlB12 and SiB6, or a mixed oxide of formula (II). MexSAySBz (I) Me = Al, Ti, Zr, V, Nb, Ta, Cr, Mo, W, Fe, Co, Ni, Cu or Ag; SA and SB = B, C, Si, Ge, Sb, Se or Te; and x, y and z = 0.01-1. ((CaO)u.(SrO)v.(BaO)w.(1/2Bi2O3)x)f.(2n+a/2).((k).MenOn/2.(2-k).Men+aO n+a/2) (II) Me = Fe, Cu, V, Mn, Sn, Ti, Mo or W; n = 1-6; a = 1 or 2; f = 0.2-5; k = 0.01-2; and u + v + w + x = 1. Independent claims are also included for: (1) a process for the production of the semiconductor materials comprising sintering or melting together, and sintering mixtures of the elemental powder or sintering mixtures of the oxide powder; and (2) a process for the combinatory production and testing of the semiconductor materials for thermoelectric generators.