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公开(公告)号:DE2412032A1
公开(公告)日:1975-10-16
申请号:DE2412032
申请日:1974-03-13
Applicant: BASF AG
Inventor: LAMM GUNTHER DIPL CHEM DR
IPC: C09B31/065 , C09B31/06
Abstract: Water-soluble disazo dyes are of formula (I): A3 and A4 are H or SO3H; A2 and B' are as A3 or methyl; A' is as A2 or OH, Cl, OCH2CH2OSO3H or SO2NHCH2CH2SO3H; B2 is H or CH3; one of R' and R2 is 2-4C alkyl substd. with OH, CN, carbamoyl, carbalkoxy, carboxyl, N-substd. carbamoyl, acetyl, pyrrolidonyl, or: or is acetyl, propionyl or benzoyl, and the other is 1-4C n-alkyl; R3 is H, or 1-2C alkyl and at least one SO3H gp. is present). The novel cpds. are used for dyeing or printing of natural and esp. synthetic polyamides in brownish-yellow to brown shades. Good fastness esp. to light and wet treatments, with good levelling behaviour are obtd. The cpds. have high solubility as required for continuous dyeing.
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公开(公告)号:DE3201268A1
公开(公告)日:1983-07-28
申请号:DE3201268
申请日:1982-01-16
Applicant: BASF AG
IPC: C09B29/039 , C09B29/00 , C09B29/42 , D06P1/18 , D06P3/60 , C09B29/045 , D06P1/04
Abstract: A compound having the formula: I where X is hydrogen, chlorine or bromine, B is hydrogen, methyl, ethyl or propyl, and one of the radicals R1 or R2 is phenyl which is unsubtituted or mono- or poly-substituted by chlorine, methyl, ethyl, t-butyl, phenoxy, methoxy, ethoxy, propoxy or butoxy, and the other is C2-C8-alkyl which is unsubstituted or substituted by C1-C8-alkoxy or phenyl, or is allyl, cyclopentyl, cyclohexyl, methylcyclohexyl, The compounds of formula (I) are used as dyes, preferably for cellulose and cellulose-containing fabrics.
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公开(公告)号:DE2513337A1
公开(公告)日:1976-10-07
申请号:DE2513337
申请日:1975-03-26
Applicant: BASF AG
Inventor: MARTINEK JOSEF , LAMM GUNTHER DIPL CHEM DR
IPC: C07D333/38
Abstract: In the prodn. of thiophen derivs. (I) of formula: (in which R is 1-17C alkyl, 1-8C alkoxymethyl, cyclohexyl or opt. MeO-, Me-, Cl- or NO2-substd. phenyl; X is CN, CONH2 or Z; Z is carboxylic ester) by reacting cpds. (II) of the formula R-COCH2-Z with cpds. (III) of the formula X-CH2CN and S in the presence of organic bases (IV), the reaction is carried out at first at max. 35 degrees C and then ring closure is effected, after formation of the intermediate (V) of the formula HS-CHZ-CR=CX-CN by heating above 35 degrees C. Z pref. is derived from 1-8C alcohols and phenols, kesp. 1-6C alkanols. (I) are used as diazo components. High yields of light-coloured prods. are obtd.
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公开(公告)号:DE2409754A1
公开(公告)日:1975-10-16
申请号:DE2409754
申请日:1974-03-01
Applicant: BASF AG
Abstract: Thermoplastics are coloured with dyes of formula (I): where A' is a gp. A or a gp. (II) D is the residue of a diazo component, R is H, alkyl or (methyl)phenyl, X is H, carbamoyl or CN, Z is a (cyclo) alkylene, aralkylene or arylene gp., where the alkylene gp. may be interrupted by O, S or N-substd. imino, and A is H, (substd.) (cyclo)alkyl, aralkyl, phenyl or acyl or may together form a 5-7 membered heterocyclic ring with N. (I) are used for dyeing thermoplastics in bulk at is not >300 degrees C, e.g polystyrene, hard PVC, polyethylene, polyamides, polyesters, polycarbonates, styrene-butadiene copolymers and ABS copolymers. (I) are stable to heat. They have up to 3.5 x the colour strength of dyes normally used for dyeing in bulk.
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公开(公告)号:DE2309638A1
公开(公告)日:1974-09-12
申请号:DE2309638
申请日:1973-02-27
Applicant: BASF AG
IPC: C07D213/74 , C07D213/82 , C07D213/85 , C09B29/42 , C09B31/153 , C09B39/00 , C09B29/36
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公开(公告)号:DE2309637A1
公开(公告)日:1974-09-05
申请号:DE2309637
申请日:1973-02-27
Applicant: BASF AG
Inventor: LAMM GUNTHER DIPL CHEM DR
Abstract: Title dyes of formula (I): (where A is -SO2- or -OSO2-; n is 1 or 2; Z is H, Cl or Br; R is alkoxypropylamino or opt. substd. C4-C12 alkyl-amino and where A is -SO2- also opt. substd. C5-C10 cycloalkylamino) are pref. prepd. by diazotizing amine (II) and coupling to 2,6-dihydroxy-3-cyano-4-methyl pyridine.
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公开(公告)号:DE2801951A1
公开(公告)日:1979-07-19
申请号:DE2801951
申请日:1978-01-18
Applicant: BASF AG
Inventor: LAMM GUNTHER DIPL CHEM DR
IPC: C09B31/153 , C09B31/14
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公开(公告)号:DE2734927A1
公开(公告)日:1979-02-22
申请号:DE2734927
申请日:1977-08-03
Applicant: BASF AG
IPC: C08K5/00 , C08K5/23 , C08K5/35 , C08L67/00 , C08L77/00 , C09B29/01 , C09B29/42 , C09B29/36 , C09B39/00
Abstract: An azo dye of the general formula (1) where A is cyano or carbamoyl, R is hydrogen, alkyl or phenyl, R1 is hydrogen, bromine, chlorine or nitro, R2 is hydrogen, chlorine, bromine, nitro, methyl, trifluoromethyl, sulfamoyl, N-monoalkyl- or N,N-dialkylsulfamoyl (where alkyl is of 1 to 4 carbon atoms), or a sulfonic acid phenyl ester, methylphenyl ester, chlorophenyl ester or methoxyphenyl ester group, R3 is hydrogen or alkyl of 1 to 8 carbon atoms which may be interrupted by oxygen and may be substituted by hydroxyl, pyrrolidonyl, phthalimidyl, alkoxy of 1 to 8 carbon atoms, allyloxy, benzyloxy, phenylethoxy, phenoxy, methylphenoxy, chlorophenoxy, methoxyphenoxy, or optionally substituted arylsulfonyl, or is benzyl, phenylethyl or cyclohexyl, or is phenyl which is unsubstituted or substituted by chlorine, bromine, nitro, methyl, ethyl, methoxy, ethoxy, phenoxy or dialkylamino (where alkyl is of 1 to 4 carbon atoms), or is naphthyl, pyridyl, thienyl or furyl, the substituents B1 independently of one another are hydrogen or an aliphatic, cycloaliphatic, araliphatic, aromatic, heterocyclic or acyl radical and B2 is hydrogen or an aliphatic radical. The dyes may be used for dyeing synthetic fibers, especially polyesters, and cellulose/polyester union fabrics, and give very fast dyeings.
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