Thixotropic polyester resins
    9.
    发明专利

    公开(公告)号:GB994297A

    公开(公告)日:1965-06-02

    申请号:GB1574364

    申请日:1964-04-16

    Applicant: BASF AG

    Abstract: A thixotropic polyester resin composition comprises (1) at least one resinous ethylenically unsaturated polymerizable polyester, (2) at least one liquid monomeric ethylenically unsaturated polymerizable compound and (3) at least one substance which imparts thixotropy, wherein at least one substance (3) is a polyurethane free or substantially free from ethylenically unsaturated groups, radicals of fatty acids having more than nine carbon atoms, radicals of adducts of such fatty acids, isocyanate groups and containing reacting like isocyanate groups, said polyurethane containing connected by urethane bonds, radicals of at least one dibasic carbamic acid and radicals of at least one dihydric hydroxyl compound, and said polyurethane when mixed with components (1) and (2) gives a homogeneous and clear solution or a pseudo solution. The polyurethane may additionally contain radicals of at least one monobasic, tribasic and/or higher basic carbamic acid and/or radicals of at least one monohydric, trihydric and/or higher hydric hydroxyl compound. The polyurethane preferably has a mean molecular weight of 500 to 3000 and contains on average two to eight urethane groups per molecule. In addition to the polyurethane, a normal thixotropic substance may be added. In the examples a polyester formed from maleic and phthalic anhydrides and propanediol-1,2 is mixed with styrene and a finely-ground polyurethane obtained from toluylene-2,4-diisocyanate, toluylene - 2,6 - diisocyanate, hexanediol-1,6 and 2-ethyl hexanol and the mixture is polymerized using cyclohexanone peroxide and cobalt naphthenate.

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