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    Verfahren zur Herstellung von 4-Pentensäureestern.
    3.
    发明公开
    Verfahren zur Herstellung von 4-Pentensäureestern. 失效
    一种用于4-戊烯酸酯的制备方法。

    公开(公告)号：EP0206142A1

    公开(公告)日：1986-12-30

    申请号：EP86108022

    申请日：1986-06-12

    Applicant: BASF AG

    Inventor： HOELDERICH WOLFGANG DR ,  FISCHER ROLF DR ,  MALSCH KLAUS-DIETER DR ,  LENDLE HUBERT DR

    IPC: C07C69/155 ,  B01J29/00 ,  C07B61/00 ,  C07C67/333 ,  C07C69/52 ,  C07C69/533

    CPC classification number: C07C67/333 ,  C07C69/533

    Abstract: Verfahren zur Herstellung von 4-Pentensäureestern durch Isomerisierung, wobei man isomere Pentensäureester bei erhöhter Temperatur in Gegenwart von Zeolithen mit einem Gehalt an Metallen der achten Gruppe des Periodischen Systems behandelt und 4-Pentensäureester aus dem Reaktionsgemisch abdestilliert und die Zeolithe einen Gehalt an Eisen, Cobalt und/oder Nickel haben.

    Abstract translation: 一种用于通过异构化制备的4-戊烯酸酯处理，得到同分异构的戊烯酸酯在升高的温度下在沸石的存在下用第八组周期表中的金属的含量处理，并从反应混合物中蒸馏4-戊酯和沸石具有的铁，钴含量 和/或镍有。

    5.
    发明专利
    未知

    公开(公告)号：DE3640296A1

    公开(公告)日：1988-06-01

    申请号：DE3640296

    申请日：1986-11-25

    Applicant: BASF AG

    Inventor： LENDLE HUBERT DR ,  PANITZ PAUL ,  SEYFERT WILFRIED DR ,  STOPS PETER

    IPC: B01J38/00 ,  C07B61/00 ,  C07B63/00 ,  C07C67/38 ,  C07C67/48 ,  C07C67/54 ,  C07C67/58 ,  C07C69/40 ,  C07C69/44 ,  C07D213/06 ,  C07D213/16 ,  C07C67/36 ,  C07C69/34

    Abstract: Pyridine or methylpyridines or mixtures thereof are recovered from methyl butanedicarboxylate containing reaction mixtures obtained by reaction of methyl pentenoate with carbon monoxide and methanol in the presence of pyridine, methylpyridines or mixtures thereof and also cobalt catalysts at elevated temperatures and under superatmospheric pressure and subsequent treatment with molecular oxygen containing gases in aqueous acetic acid by (a) separating the reaction mixture on the one hand into an aqueous phase containing cobalt acetate, pyridine, methylpyridines or mixtures thereof, acetic acid and methanol and on the other an organic phase containing methyl butanedicarboxylate, by-products, unconverted methyl pentenoate, acetic acid and also pyridine, methylpyridines or mixtures thereof, (b) extracting the organic phase obtained in step (a) with aqueous acetic acid to obtain an aqueous extract containing pyridine or methylpyridines or mixtures thereof as well as acetic acid, (c) combining the aqueous extract obtained in step (b) with the aqueous phase from step (a) and (d) isolating pyridine, methylpyridines or mixtures thereof by distillation from the aqueous solution produced in step (c) and obtaining a solution of cobalt acetate in aqueous acetic acid.

    8.
    发明专利
    未知

    公开(公告)号：DE3774080D1

    公开(公告)日：1991-11-28

    申请号：DE3774080

    申请日：1987-11-23

    Applicant: BASF AG

    Inventor： LENDLE HUBERT DR ,  PANITZ PAUL ,  SEYFERT WILFRIED DR ,  STOPS PETER

    IPC: B01J38/00 ,  C07B61/00 ,  C07B63/00 ,  C07C67/38 ,  C07C67/48 ,  C07C67/54 ,  C07C67/58 ,  C07C69/40 ,  C07C69/44 ,  C07D213/06 ,  C07D213/16

    Abstract: Prodn. of butanedicarboxylic acid methyl esters (I) is effected by reacting a methyl pentenoate (II) with CO and MeOH in the presence of pyridine and/or picolines (III) and a Co catalyst at elevated temp. and pressure, and treating the reaction mixt. with an O2-contg. gas and aq. HOAc. (III) are recovered by (a) sepg. the reaction mixt. into an aq. phase contg. Co(OAc)2, (III), HOAc and MeOH, and an organic phase contg. (I), by-products, (II), HOAc and (III); (b) extracting (III) from the organic phase with aq. HOAc; (c) combining the extract with the aq. phase; and (d) distilling (III) from the mixt. to leave an aq. soln. contg. Co(OAc)2 and HOAc.

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