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公开(公告)号:EP0206143A1
公开(公告)日:1986-12-30
申请号:EP86108023
申请日:1986-06-12
Applicant: BASF AG
IPC: C07C69/533 , B01J29/00 , C07B61/00 , C07C67/333 , C07C69/52
CPC classification number: C07C67/333 , Y02P20/582 , C07C69/533
Abstract: Verfahren zur Herstellung von 4-Pentensäureestern durch Isomerisierung, wobei man isomere Pentensäureester bei erhöhter Temperatur mit Zeolithen behandelt und 4-Pentensäureester aus dem Reaktionsgemisch abdestilliert, dadurch gekennzeichnet, daß man Zeolithe des Pentasiltyps verwendet.
Abstract translation: 一种用于由异构化4-戊烯酸酯,其中戊烯酸酯的异构体在高温下与沸石处理的准备和4-戊烯酸的过程从反应混合物,其特征在五硅环型的即使用沸石蒸馏掉。
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公开(公告)号:DE3625261A1
公开(公告)日:1988-02-04
申请号:DE3625261
申请日:1986-07-25
Applicant: BASF AG
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公开(公告)号:DE3602378A1
公开(公告)日:1987-07-30
申请号:DE3602378
申请日:1986-01-28
Applicant: BASF AG
Inventor: HUTMACHER HANS-MARTIN DR , BROECKER FRANZ JOSEF DR , MERGER FRANZ DR , FISCHER ROLF DR , VAGT UWE DR , SCHNEIDER HEINZ-WALTER DR , RICHTER WOLFGANG DR
IPC: C07B61/00 , B01J21/16 , B01J23/00 , B01J23/74 , B01J23/755 , B01J25/02 , C07C67/00 , C07C227/00 , C07C227/04 , C07C227/08 , C07C229/04 , C07C229/08 , C07C101/18 , C07C99/00 , B01J23/78
Abstract: In an improved process for the preparation of 6-aminocaproates by reacting a 5-formylvalerate with ammonia and hydrogen using an alkanol as a solvent in the presence of a hydrogenation catalyst at elevated temperatures and under superatmospheric pressure, the improvement comprises carrying out the reaction at from 40 DEG to 95 DEG C.
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公开(公告)号:ES2043967T3
公开(公告)日:1994-01-01
申请号:ES89111529
申请日:1989-06-24
Applicant: BASF AG
Inventor: RICHTER WOLFGANG DR , HARDER WOLFGANG DR , FISCHER ROLF DR , VAGT UWE DR
IPC: C07C67/31 , C07C69/675
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公开(公告)号:AT68462T
公开(公告)日:1991-11-15
申请号:AT87110130
申请日:1987-07-14
Applicant: BASF AG
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公开(公告)号:DE3521381A1
公开(公告)日:1986-12-18
申请号:DE3521381
申请日:1985-06-14
Applicant: BASF AG
IPC: C07C69/533 , B01J29/00 , C07B61/00 , C07C67/333 , C07C69/52
Abstract: 4-Pentenoates are prepared by isomerization by a process in which isomeric pentenoates are treated with a zeolite of the pentasil type at from 50 DEG to 300 DEG C., and the 4-pentenoate is distilled off from the reaction mixture.
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公开(公告)号:DE3161044D1
公开(公告)日:1983-11-03
申请号:DE3161044
申请日:1981-10-22
Applicant: BASF AG
Inventor: RICHTER WOLFGANG DR , KUMMER RUDOLF DR , SCHWIRTEN KURT DR
IPC: C07C27/22 , B01J31/00 , B01J31/24 , B01J31/28 , C07B61/00 , C07C27/00 , C07C29/158 , C07C29/16 , C07C45/49 , C07C45/50 , C07C67/00
Abstract: A process for hydroformylating olefinically unsaturated compounds by means of rhodium/triphenylphosphine/carbonyl complexes formed in situ from rhodium acetate, triphenylphosphine and carbon monoxide, wherein the hydroformylation reaction is preceded by a starting phase in which the mixture of the hydroformylation medium, the triphenylphosphine and rhodium acetate is heated at from 90 DEG to 120 DEG C. under a CO/H2 pressure of from 5 to 20 bar and the acetic acid liberated is discharged from the reactor in gaseous form in a stream of CO and H2, until virtually no more acetic acid can be detected in this gaseous discharge.
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公开(公告)号:ES2051933T3
公开(公告)日:1994-07-01
申请号:ES89111531
申请日:1989-06-24
Applicant: BASF AG
Inventor: RICHTER WOLFGANG DR , FISCHER ROLF DR , VAGT UWE DR
IPC: C07D309/30 , B01J21/02 , B01J21/06 , B01J23/06 , C07D313/04 , C07D315/00
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公开(公告)号:DE3660625D1
公开(公告)日:1988-10-06
申请号:DE3660625
申请日:1986-06-12
Applicant: BASF AG
IPC: C07C69/533 , B01J29/00 , C07B61/00 , C07C67/333 , C07C69/52
Abstract: 4-Pentenoates are prepared by isomerization by a process in which isomeric pentenoates are treated with a zeolite of the pentasil type at from 50 DEG to 300 DEG C., and the 4-pentenoate is distilled off from the reaction mixture.
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公开(公告)号:DE3462246D1
公开(公告)日:1987-03-05
申请号:DE3462246
申请日:1984-09-03
Applicant: BASF AG
Inventor: REUVERS JOHANNES G DR , RICHTER WOLFGANG DR , KUMMER RUDOLF DR
Abstract: A process for the preparation of succinic acid diesters by carbonylation of acrylic acid esters in the presence of alcohols, using a cobalt carbonyl complex as the catalyst and a heterocyclic nitrogen base as the promoter, at 80 DEG -200 DEG C. and under a carbon monoxide pressure of 60-300 bar, wherein the reaction is carried out in the presence of not less than 20% by weight, based on the amount of all the liquid constituents of the reaction mixture, of an inert liquid and the concentration of the acrylic acid ester is kept, for the predominant part of the reaction time, at below 15% by weight, again based on the amount of all liquid constituents.
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