公开(公告)号：JP2000219989A

公开(公告)日：2000-08-08

申请号：JP37660199

申请日：1999-12-15

Applicant: BASF AG

Inventor： HUBER GUENTHER DIPL ING ,  PUETTER HERMANN ,  SCHIERLE A KERSTIN ,  SCHLAEFER DIETER DR ,  GUTH JOSEF ,  SCHUBE BERND ,  LENZ DIETHARD

IPC: C22B26/00 ,  C25C1/20 ,  C25C3/02

Abstract: PROBLEM TO BE SOLVED: To reduce the energy consumption in the manufacture by maintaining the dynamic condition of an alkali metal amalgam forming an anode. SOLUTION: A liquid anode preferably maintains its dynamic condition by the stirring under the atmospheric pressure or the pressure slightly higher than the atmospheric pressure, or the circulation by a pump, or the combination thereof. An anode area and a cathode area are separated from each other by a solid electrolyte which is an alkali metal ion conductor through which helium is impermeable. For example, appropriate solid electrolytes in manufacturing sodium include sodium β"-alumina, and sodium p-alumina. The manufacturing temperature is preferably 310-400 deg.C for sodium, and 260-400 deg.C for potassium. The current density during the manufacture is generally >=250 A/m2, but preferably 0.5-10 kA/m2 for sodium, and 0.3-3 kA/m2 for potassium.

公开(公告)号：DE19859563A1

公开(公告)日：2000-06-29

申请号：DE19859563

申请日：1998-12-22

Applicant: BASF AG

Inventor： HUBER GUENTHER ,  PUETTER HERMANN ,  SCHIERLE KERSTIN ,  SCHLAEFER DIETER ,  GUTH JOSEF ,  SCHUBE BERND ,  LENZ DIETHARD

IPC: C22B26/00 ,  C25C1/20 ,  C25C3/02

Abstract: Production of an alkali metal originating from alkali metal amalgam comprises using electrolysis using an anode containing an alkali metal amalgam, an alkali metal ion conducting solid electrolyte and a liquid alkali metal as cathode. An Independent claim is also included for an integrated process for the manufacture of chlorine comprising carrying out chloro-alkali electrolysis forming elementary chlorine and alkali metal amalgam, and then carrying out the above alkali metal production process.

公开(公告)号：AT338151T

公开(公告)日：2006-09-15

申请号：AT99124037

申请日：1999-12-09

Applicant: BASF AG

Inventor： HUBER GUENTER ,  PUETTER HERMANN DR ,  SCHIERLE KERSTIN DR ,  SCHLAEFER DIETER DR ,  GUTH JOSEF ,  SCHUBE BERND ,  LENZ DIETHARD

IPC: C22B26/00 ,  C25C1/20 ,  C25C3/02

Abstract: In a process for producing an alkali metal from alkali metal amalgam by electrolysis using an alkali metal amalgam as anode, a solid electrolyte which conducts alkali metal ions and a liquid alkali metal as cathode, the alkali metal amalgam as anode is kept in motion.

公开(公告)号：DE19859563B4

公开(公告)日：2008-01-24

申请号：DE19859563

申请日：1998-12-22

Applicant: BASF AG

Inventor： HUBER GUENTHER ,  PUETTER HERMANN ,  SCHIERLE KERSTIN ,  SCHLAEFER DIETER ,  GUTH JOSEF ,  SCHUBE BERND ,  LENZ DIETHARD

IPC: C22B26/00 ,  C25C3/02 ,  C25C1/20

Abstract: In a process for producing an alkali metal from alkali metal amalgam by electrolysis using an alkali metal amalgam as anode, a solid electrolyte which conducts alkali metal ions and a liquid alkali metal as cathode, the alkali metal amalgam as anode is kept in motion.

公开(公告)号：DE59913824D1

公开(公告)日：2006-10-12

申请号：DE59913824

申请日：1999-12-09

Applicant: BASF AG

Inventor： HUBER GUENTER ,  PUETTER HERMANN DR ,  SCHIERLE KERSTIN DR ,  SCHLAEFER DIETER DR ,  GUTH JOSEF ,  SCHUBE BERND ,  LENZ DIETHARD

IPC: C22B26/00 ,  C25C3/02 ,  C25C1/20

Abstract: In a process for producing an alkali metal from alkali metal amalgam by electrolysis using an alkali metal amalgam as anode, a solid electrolyte which conducts alkali metal ions and a liquid alkali metal as cathode, the alkali metal amalgam as anode is kept in motion.