Process for the preparation of polyaryl ether ketones

    公开(公告)号:DE3901072A1

    公开(公告)日:1990-07-19

    申请号:DE3901072

    申请日:1989-01-16

    Applicant: BASF AG

    Abstract: A process for the preparation of polyaryl ether ketones by nucleophilic polycondensation of aromatic dihydroxyl compounds with aromatic dihalogen compounds using alkali metal carbonates and other alkali, alkaline earth and/or sub-group metal salts other than the alkali metal carbonates, where a) the alkali metal carbonates are employed in an excess of 0.5-10 Mol %, based on the amount of aromatic dihydroxyl compounds, and b) at least one other alkali, alkaline earth and/or sub-group metal salt is added at the beginning of the polycondensation in an amount corresponding at least to the molar excess of alkali metal carbonate.

    3.
    发明专利
    未知

    公开(公告)号:DE3804159A1

    公开(公告)日:1989-08-24

    申请号:DE3804159

    申请日:1988-02-11

    Applicant: BASF AG

    Abstract: The polyaryl ether ketones are built up essentially from (A) 55 - 95 mol % of recurring units of the formula I or ring-substituted C1-C6-alkyl, C1-C6-alkoxy, aryl, chlorine or fluorine derivatives thereof, where s and t are each 0, 1, 2 or 3, and Q and T may each be -O- or -CO-, and (B) 5 - 45 mol % of recurring units of the formula II in which Ar , Ar , Ar , Ar and Ar , independently of one another, are each a phenylene, biphenylene or naphthylene group or a C1-C6-alkyl, C1-C6-alkoxy, aryl, chlorine or fluorine derivative thereof, Q' and T' may each be -O- or -CO-, and s' and t' are each 0, 1, 2 or 3, with the proviso that at least one of the substituents Ar , Ar , Ar , Ar and Ar is a biphenylene or naphthylene group or a C1-C6-alkyl, C1-C6-alkoxy, aryl, chlorine or fluorine derivative of such a group, and not all the parameters s, t, s' and t' are simultaneously 0 if Ar is a biphenylene group.

    6.
    发明专利
    未知

    公开(公告)号:DE3804393A1

    公开(公告)日:1989-08-24

    申请号:DE3804393

    申请日:1988-02-12

    Applicant: BASF AG

    Abstract: The polyaryl ether is built up essentially from… A) from 60 to 97 mol % of recurring units of the formula I … … or ring-substituted C1-C6-alkyl, C1-C6-alkoxy, aryl, chlorine or fluorine derivatives thereof, where l and m are 1 or 2,… B) from 3 to 40 mol % of recurring units of the formula II … … or ring-substituted C1-C6-alkyl, C1-C6-alkoxy, aryl, chlorine or fluorine derivatives thereof, where n is 1 or 2,… and in addition… C) from 0 to 15 mol % of recurring units of the formula III and/or IV … … or ring-substituted C1-C6-alkyl, C1-C6-alkoxy, aryl, chlorine or fluorine derivatives thereof, where Ar is … … or a C1-C6-alkyl, C1-C6-alkoxy, chlorine or fluorine derivative thereof, r is 0 or 1, and p, q and s are 1 or 2.

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