METHOD FOR THE PRODUCTION OF A CATALYST SYSTEM FOR THE POLYMERISATION OF OLEFINS
    3.
    发明申请
    METHOD FOR THE PRODUCTION OF A CATALYST SYSTEM FOR THE POLYMERISATION OF OLEFINS 审中-公开
    用于生产催化剂体系的烯烃聚合

    公开(公告)号:WO0177187A3

    公开(公告)日:2002-03-28

    申请号:PCT/EP0103829

    申请日:2001-04-04

    CPC classification number: C08F110/02 C08F10/00 C08F2500/17 C08F4/7042

    Abstract: A method for the production of a catalyst system for the polymerisation of olefins is characterised in that one or several compounds of general formula (Ia) or (Ib) are deposited, then a molecularly defined activator of general formula (IIa to c) [(L H)] [(M')Q Q Q Q ]- (II a) [(CAr3)] [(M')Q Q Q Q ]- (II b) [(M')Q Q Q ] (II c) is added and finally an alkylating agent, selected from LiR R or A1R R R , is added.

    Abstract translation: 一种用于制备催化剂体系用于烯烃聚合,其特征在于,一个或多个一般式(Ia)(Ib)的化合物或方法最初引入,随后将式II a到c [(LH)]的分子定义的活化剂< +> [(M ')问<1> Q <2> Q <3> Q <4>] - (II A)[(的Car3)] <+> [(M')问<1> Q <2> Q <3> Q <4>] - (b II)[(M“)问<1> Q <2> Q <3>](II C)加入,最后从LIR <11>中选择的烷基化剂, Mg11R <12>或A1R <12> - [R <13> - [R <14>,增加了。

    METHOD FOR THE EMULSION POLYMERIZATION OF OLEFINS
    6.
    发明申请
    METHOD FOR THE EMULSION POLYMERIZATION OF OLEFINS 审中-公开
    方法烯烃乳液聚合

    公开(公告)号:WO02064638A2

    公开(公告)日:2002-08-22

    申请号:PCT/EP0201467

    申请日:2002-02-13

    CPC classification number: C08F10/00 C08F110/02 C08F2/24 C08F4/80

    Abstract: The invention relates to a method for the emulsion polymerization of one or more olefins by reacting a ligand according to the general formulae (Ia) to (Ic) or a mixture of at least two of the ligands (Ia) to (Ic), wherein M is a metal of the first group of the periodic table of elements or hydrogen, with a metal compound of the general formula (M(L )2 or M(L )2(L )z, wherein M is a transition metal of the 7 to 10 group of the periodic table of elements and preferably nickel, and immediately using the reaction product for the polymerization or copolymerization of olefins in water or in a solvent mixture that contains at least 50 % by volume of water, optionally in the presence of an activator and an emulsifier. The aqueous dispersions of polyolefins such as polyethylene and ethylene copolymerizates obtained according to the inventive method are suitable for applications in the paper industry such as paper coating or surface sizing, paint coatings, raw materials for adhesives, molded foams such as mattresses, textile or leather applications, carpet backings or pharmaceutical applications.

    Abstract translation: 由通式的配位体反应的乳液聚合过程I A至I C,或至少两个的配位体的混合物我一个至I C,其中M <1>是元素或氢的周期表第1族的金属,具有 (<2> L)2或通式M(L <2>)2(L <1>)Z,其中M是组7的的元素并且优选地,镍的周期表第10的过渡金属的M个金属化合物,和立即使用 用于烯烃在水中的聚合或共聚或至少含有50体积%的水,任选地在活化剂和乳化剂的存在下于溶剂混合物中的反应产物。 根据本发明的聚烯烃如聚乙烯和乙烯共聚物的水性分散体适合用于造纸的应用,如纸张涂层或表面施胶,涂清漆,粘合剂原材料,模塑泡沫,如床垫,纺织品和皮革应用,地毯背衬或药物应用的方法获得。

    9.
    发明专利
    未知

    公开(公告)号:DE10017660A1

    公开(公告)日:2001-10-11

    申请号:DE10017660

    申请日:2000-04-08

    Applicant: BASF AG

    Abstract: A method for the production of a catalyst system for the polymerisation of olefins is characterised in that one or several compounds of general formula (Ia) or (Ib) are deposited, then a molecularly defined activator of general formula (IIa to c) [(L H)] [(M')Q Q Q Q ]- (II a) [(CAr3)] [(M')Q Q Q Q ]- (II b) [(M')Q Q Q ] (II c) is added and finally an alkylating agent, selected from LiR R or A1R R R , is added.

    10.
    发明专利
    未知

    公开(公告)号:DE19955454A1

    公开(公告)日:2001-05-23

    申请号:DE19955454

    申请日:1999-11-17

    Applicant: BASF AG

    Abstract: Metal complexes (I), obtained from a metal precursor of a group 6-10 metal in the 0 or +2 oxidation state and a ortho-phosphinylphenol, -aniline or analogous ligand (II) are new. Metal complexes (I), obtained from a metal precursor of a group 6-10 metal in the 0 or +2 oxidation state and a ortho-phosphinylphenol, -aniline or analogous ligand of formula (II) are new; R , R , R = hydrogen (H), arylalkyl, alkenyl, alkoxy, aryloxy, thioether, silyloxy OSiR R R , halogen, amino NR1oR or (substituted) alkyl, cycloalkyl or aryl; R = alpha -branched or alpha -substituted alkyl, arylalkyl, alkenyl(alkyl), cycloalkyl, (substituted) aryl, alkoxy, aryloxy, thioether, OSiR R R , halogen or NR R ; 2 adjacent R groups may = a ring; R , R = (substituted) alpha -branched 3-12 C alkyl or 3-12 C cycloalkyl; X = oxygen (O), sulfur (S), selenium (Se), imino (NR ), phosphino (P-R ) or arsino (As-R ); Y = H, an alkali metal cation, alkylacyl or arylacyl anion or SiR R R ; R = H, alkyl, benzyl or aryl; R R or R R may = a ring. The full definitions are given in the DEFINITIONS (Full Definitions) Field. Independent claims are also included for: (a) catalysts of (I) immobilized on a solid support for the polymerization of 1-olefins; (b) the polymerization of 1-olefins in the presence of (I) or these catalysts; (c) (co)polymers obtained by polymerizing 1-olefin(s) with (I) or the catalyst system; (d) molding compositions obtained from the (co)polymers for making films, sheets, waxes, fibers or hollow moldings.

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