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    6.
    发明专利
    未知

    公开(公告)号：DE1009808B

    公开(公告)日：1957-06-06

    申请号：DEB0032465

    申请日：1954-09-02

    Applicant: BASF AG

    Inventor： MEYER DR FERDINAND ,  DEMMLER DR KURT ,  LISSNER DIPL-ING OSKAR

    IPC: C08G59/50

    Abstract: Polyglycidyl ethers obtained by reacting polyhydric alcohols or phenols with halohydrins are hardened by addition of a diamine having the formula: H2N-A-R-BNHX where A and B are the same or different carbocyclic radicals, e.g. aromatic radicals, preferably phenyl radicals or cycloaliphatic radicals preferably hexyl radicals, and R is a bivalent bridge group, e.g. methylene, ethylene, &c. radicals, or -O-, -S-, -NH-, and -HN-CO-NH-while X is H or an aliphatic radical. The amino groups may be present in the ortho, meta or para positions. Suitable amines are: p,p - diaminodiphenylmethane, p,p1 - diamino diphenylamine, p,p1 - diaminodiphenylurea, p,p1 - diaminodiphenyl propane, o,o1 - diamino diphenylmethane, p,p1 - diaminodiphenyl sulphide; diaminodicyclohexyl methane, diaminodicyclohexylpropane, diaminodicyclohexylcyclohexylmethane, diaminodicyclohexylamine. Mixtures with other amines and mixtures of diprimary and primary-secondary amines may be used. The amines may be dissolved in the liquid ethers or in solvents, e.g. ketones, esters, alcohols, glycolethers and chlorinated aromatic hydrocarbons. Small amounts of phenol-aldehyde or urea-formaldehyde resins, amines of high molecular weight, or quaternary ammonia compounds may be added as fluxing agents, e.g. the reaction products of a fatty acid ester of diethyl ethanol amine with dimethyl sulphate. In examples: (1) 32.5 parts p,p1-diaminodiphenylmethane are added to 100 parts of the glycidylether obtained from butane triol and epichlorhydrin; the solution yields hard, clear films and can be used to impregnate glass fabrics. If 10 per cent of the amine is replaced by dipropylene triamine the hardening time is shortened; (2) an epoxy resin from bis-phenol and epichlorhydrin is dissolved in a mixture of butyl acetate, ethylene glycol monoethyl ether and toluene containing 1.5 per cent nonplasticized urea-formaldehyde resin and 10 per cent diaminodiphenylmethane in glycol ether is added; (3) epoxy resin from 4,41-dehydroxy diphenyl propane and 4,41-diaminodicyclohexyl methane; (4) butane triol triglycedyl ester and 4,41-diaminodiphenyl amine; (5) butane triol triglycidyl ether and 4,41-diaminodiphenyl sulphide; (6) as in (5) using 4,41-diaminodiphenyl urea; (7) as in (5) using 2,21-diaminodiphenyldimethyl methane; (8) as in (5) using 4,41-diamino-3,31-dimethyl diphenyl methane.

    7.
    发明专利
    未知

    公开(公告)号：DE1006991B

    公开(公告)日：1957-04-25

    申请号：DEB0032594

    申请日：1954-09-02

    Applicant: BASF AG

    Inventor： LISSNER DIPL-ING OSKAR ,  MEYER DR FERDINAND ,  DEMMLER DR KURT

    IPC: C08G59/50

    Abstract: Polyglycidyl ethers obtained by reacting polyhydric alcohols or phenols with halohydrins are hardened by addition of a diamine having the formula: H2N-A-R-BNHX where A and B are the same or different carbocyclic radicals, e.g. aromatic radicals, preferably phenyl radicals or cycloaliphatic radicals preferably hexyl radicals, and R is a bivalent bridge group, e.g. methylene, ethylene, &c. radicals, or -O-, -S-, -NH-, and -HN-CO-NH-while X is H or an aliphatic radical. The amino groups may be present in the ortho, meta or para positions. Suitable amines are: p,p - diaminodiphenylmethane, p,p1 - diamino diphenylamine, p,p1 - diaminodiphenylurea, p,p1 - diaminodiphenyl propane, o,o1 - diamino diphenylmethane, p,p1 - diaminodiphenyl sulphide; diaminodicyclohexyl methane, diaminodicyclohexylpropane, diaminodicyclohexylcyclohexylmethane, diaminodicyclohexylamine. Mixtures with other amines and mixtures of diprimary and primary-secondary amines may be used. The amines may be dissolved in the liquid ethers or in solvents, e.g. ketones, esters, alcohols, glycolethers and chlorinated aromatic hydrocarbons. Small amounts of phenol-aldehyde or urea-formaldehyde resins, amines of high molecular weight, or quaternary ammonia compounds may be added as fluxing agents, e.g. the reaction products of a fatty acid ester of diethyl ethanol amine with dimethyl sulphate. In examples: (1) 32.5 parts p,p1-diaminodiphenylmethane are added to 100 parts of the glycidylether obtained from butane triol and epichlorhydrin; the solution yields hard, clear films and can be used to impregnate glass fabrics. If 10 per cent of the amine is replaced by dipropylene triamine the hardening time is shortened; (2) an epoxy resin from bis-phenol and epichlorhydrin is dissolved in a mixture of butyl acetate, ethylene glycol monoethyl ether and toluene containing 1.5 per cent nonplasticized urea-formaldehyde resin and 10 per cent diaminodiphenylmethane in glycol ether is added; (3) epoxy resin from 4,41-dehydroxy diphenyl propane and 4,41-diaminodicyclohexyl methane; (4) butane triol triglycedyl ester and 4,41-diaminodiphenyl amine; (5) butane triol triglycidyl ether and 4,41-diaminodiphenyl sulphide; (6) as in (5) using 4,41-diaminodiphenyl urea; (7) as in (5) using 2,21-diaminodiphenyldimethyl methane; (8) as in (5) using 4,41-diamino-3,31-dimethyl diphenyl methane.

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