公开(公告)号：WO0205955A8

公开(公告)日：2002-03-14

申请号：PCT/EP0108162

申请日：2001-07-13

Applicant: BASF AG ,  AHLERS WOLFGANG ,  MACKEWITZ THOMAS ,  PACIELLO ROCCO ,  MATHEY FRANCOIS ,  LE FLOCH PASCAL ,  SAVA XAVIER

Inventor： AHLERS WOLFGANG ,  MACKEWITZ THOMAS ,  PACIELLO ROCCO ,  MATHEY FRANCOIS ,  LE FLOCH PASCAL ,  SAVA XAVIER

IPC: B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  C07C45/50 ,  C07C51/14 ,  C07C253/10 ,  C07F17/02 ,  C08F4/80 ,  C07F9/6568 ,  C07F15/00 ,  C07F17/00

CPC classification number: C07F17/02 ,  B01J31/2295 ,  B01J31/2419 ,  B01J31/2438 ,  B01J31/2461 ,  B01J2231/12 ,  B01J2231/20 ,  B01J2231/321 ,  B01J2231/323 ,  B01J2231/543 ,  B01J2231/645 ,  B01J2531/822 ,  B01J2531/842 ,  C07C45/50 ,  C07C51/14 ,  C07C253/10 ,  C07C57/15 ,  C07C57/04 ,  C07C57/145 ,  C07C57/08 ,  C07C47/02 ,  C07C255/04

Abstract: The invention relates to a method for producing addition products to the C=C double bond of ethylenic unsaturated compound in the presence of a catalyst, comprising at least one complex of a metal of the VIII sub-group with at least one bisphospholyl metallocene as ligand. The invention further relates to novel catalysts with phosphametallocenes as ligands.

Abstract translation: 本发明涉及一种方法，用于制备的加成产物的C = C双键在包含VIII的金属中的至少一种配合物的催化剂存在下烯属不饱和化合物的键。与至少一个Bisphospholylmetallocen作为配体亚类。 本发明还涉及基于磷杂茂基作为配体的新型催化剂。

公开(公告)号：DE19921730A1

公开(公告)日：2000-11-16

申请号：DE19921730

申请日：1999-05-12

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  MACKEWITZ THOMAS ,  ROEPER MICHAEL ,  MATHEY FRANCOIS ,  GANTER CHRISTIAN ,  BREIT BERNHARD

IPC: B01J31/18 ,  B01J31/20 ,  B01J31/22 ,  B01J31/24 ,  C07C45/50 ,  C07F17/00 ,  C07F17/02 ,  C07F9/6568 ,  C07F15/00

Abstract: Production of aldehydes by hydroformylation of olefins with CO/H2 uses a sub-Group VIII transition metal complex as catalyst at 20-200 deg C and atmospheric to 700 bar pressure. The catalyst has epsilon -phospholyl- or epsilon -polyphospholyl complex-formers as ligands. Some of these complexes are themselves new. An Independent claim is also included for new complexes of formula (I). M'L'n(CO)m (I) M' = sub-Group VIII element; L' = mono- or poly-dentate epsilon -phospholyl- and/or epsilon -polyphospholyl complex-forming ligands; and n and m \-1.

公开(公告)号：DE50001801D1

公开(公告)日：2003-05-22

申请号：DE50001801

申请日：2000-05-12

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  MACKEWITZ THOMAS ,  ROEPER MICHAEL ,  MATHEY FRANCOIS ,  GANTER CHRISTIAN ,  BREIT BERNHARD

IPC: B01J31/18 ,  B01J31/20 ,  B01J31/22 ,  B01J31/24 ,  C07C45/50 ,  C07F17/00 ,  C07F17/02

公开(公告)号：DE10033982A1

公开(公告)日：2002-01-24

申请号：DE10033982

申请日：2000-07-13

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  MACKEWITZ THOMAS ,  PACIELLO ROCCO ,  MATHEY FRANCOIS ,  LE FLOCH PASCAL ,  SAVA XAVIER

IPC: B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  C07C45/50 ,  C07C51/14 ,  C07C253/10 ,  C07F17/02 ,  C08F4/80 ,  C07F17/00 ,  B01J31/12 ,  C07B35/02 ,  C07B41/06 ,  C07B61/00 ,  C07C2/08 ,  C07C6/00 ,  C07C253/08 ,  C07F9/6568 ,  C07F19/00

Abstract: The invention relates to a method for producing addition products to the C=C double bond of ethylenic unsaturated compound in the presence of a catalyst, comprising at least one complex of a metal of the VIII sub-group with at least one bisphospholyl metallocene as ligand. The invention further relates to novel catalysts with phosphametallocenes as ligands.