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公开(公告)号：CA2618869A1
公开(公告)日：2007-03-01
申请号：CA2618869
申请日：2006-08-16
Applicant: BASF AG
Inventor： MATTENHEIMER HENDRICK , MUELLER ULRICH , SCHUBERT MARKUS , TONIGOLD MARKUS
Abstract: The present invention relates to a porous metal-organic framework comprising AlIII and at least one at least bidentate compound, wherein the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR′, OR, SR, F, Cl and Br, where R, R′ are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(═O)O−, C(═S)O−, C(═O)S−, C(═S)S− or a protonated form thereof. The invention further provides a process for preparing it and provides for the use of the new porous metal-organic framework.
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公开(公告)号：CA2640300A1
公开(公告)日：2007-08-16
申请号：CA2640300
申请日：2007-02-08
Applicant: BASF AG
Inventor： MULLER ULRICH , SCHUBERT MARKUS , MATTENHEIMER HENDRICK
Abstract: The present invention relates to a process for preparing porous organic frameworks by reaction of a reaction mixture in a liquid phase comprising the appropriate starting compounds in the presence of a nonaqueous organic solvent in the presence of and/or with liberation of water, wherein the latter is withdrawn from the liquid phase of the reaction mixture during the reaction. Here, frameworks having relatively high specific surface areas can be obtained in a reproducible way.
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公开(公告)号：DE102005039654A1
公开(公告)日：2007-03-01
申请号：DE102005039654
申请日：2005-08-22
Applicant: BASF AG
Inventor： SCHUBERT MARKUS , MUELLER ULRICH , MATTENHEIMER HENDRICK , TONIGOLD MARKUS
Abstract: The present invention relates to a porous metal-organic framework comprising AlIII and at least one at least bidentate compound, wherein the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR′, OR, SR, F, Cl and Br, where R, R′ are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(═O)O−, C(═S)O−, C(═O)S−, C(═S)S− or a protonated form thereof. The invention further provides a process for preparing it and provides for the use of the new porous metal-organic framework.
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