2.
    发明专利
    未知

    公开(公告)号:DE50102568D1

    公开(公告)日:2004-07-22

    申请号:DE50102568

    申请日:2001-03-08

    Applicant: BASF AG

    Abstract: Chiral 2,4,5-tri-substituted 1,3-dioxane compounds (I), with different substituents containing a mesogenic group, and their diastereomers are new. Chiral 2,4,5-tri-substituted 1,3-dioxane compounds of formula (I), with different substituents containing a mesogenic group, and their diastereomers are new: [Image] R1>[P-Y1>-(A1>)m-Y2>-]qM-Y3>-(A2>)n-Y4>- group; R2>, R3>[P-Y1>-(A1>)m-Y2>-]qM-Y3>-(A2>)n-Y4>'-; A1>, A2>spacers with 1-30 carbon atoms; M : a mesogenic group; Y1>, Y2>, Y3>, Y4>a single bond, -O-, -S-, -CO-, -CO-O-, -O-CO-, -CO-N(R)-, -(R)N-CO-, -O-CO-O-, -O-CO-N(R)-, -(R)N-CO-O- or -(R)N-CO-N(R)-; Y4>' : -O-, -O-CO-, -O-CO-O- or -O-CO-N(R)-, with the O atom attaching R2>, R3> to the 1,3-dioxane ring; R : hydrogen or 1-4C alkyl; P : H, 1-12C alkyl, a polymerizable group or a group containing a polymerizable group; m, n : 0 or 1; q : 1, 2 or 3. Independent claims are also included for: (a) liquid crystal (LC) compositions containing chiral compound(s) (I); (b) polymerizable LC compositions containing chiral compound(s) (I); (c) optical devices produced using these compositions; (d) printed or coated substrates, dispersions and emulsions, films or pigments prepared using the polymerizable LC compositions.

    6.
    发明专利
    未知

    公开(公告)号:DE59607179D1

    公开(公告)日:2001-08-02

    申请号:DE59607179

    申请日:1996-08-26

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/03756 Sec. 371 Date Mar. 2, 1998 Sec. 102(e) Date Mar. 2, 1998 PCT Filed Aug. 26, 1996 PCT Pub. No. WO97/00600 PCT Pub. Date Jan. 9, 1997Polymerizable liquid-crystalline compounds of the formula IZ1-Y1-A1-Y3-M-Y4-A2-Y2-Z2Iwhere Z1 and Z2 are radicals containing reactive groups via which polymerization can be effected, Y1-Y4 are a single chemical bond, oxygen, sulfur, -O-CO-, -CO-O-, -O-CO-O-, -CO-NR-, -NR-CO-, -O-CO-NR-, -NR-CO-O- or -NR-CO-NR-, where at least one of the groups Y3 and Y4 is -O-CO-O-, -O-CO-NR-, -NR-CO-O- or -NR-CO-NR-, A1 and A2 are spacers having 2 to 30 carbon atoms in which the carbon chain may be interrupted by ether oxygen, thioether sulfur or by nonadjacent imino or C1-C4-alkylimino groups, M is a mesogenic group, R is C1-C4-alkyl, and compositions comprising them are distinguished by favorable liquid-crystalline phase-temperature ranges and can be used in optical display devices and in cholesteric liquid-crystalline colorants.

    8.
    发明专利
    未知

    公开(公告)号:DE50002234D1

    公开(公告)日:2003-06-26

    申请号:DE50002234

    申请日:2000-02-23

    Applicant: BASF AG

    Abstract: New chiral doping agents (I) comprise dianhydrohexitol derivatives containing at least one polymerizable group. Chiral doping agents of formula (I) are new. Z1-Y1-(A1)m-Y2-M-Y3-X-Y4-(A2)n-Y5-Z 2 (I) A1, A2 = spacers having a chain length of 1-30C; Y1-Y5 = direct bond, O, S, C(O), C(O)O, OC(O), CH=CHC(O)O, OC(O)O, C(O)N(R), N(R)C(O), CH2O, CH=N, N=CH or N=N; M = mesogenic group; R = H or 1-4C alkyl; Z1, Z2 = H, 1-4C alkyl, polymerizable group (PG) or residue carrying a PG, provided that at least one is a PG or residue carrying a PG; X = dianhydrosorbitol, dianhydromannitol or dianhydroiditol residue; m, n = 0 or 1. An Independent claim is included for cholesteric liquid crystal compositions (A) (which preferably reflect left-circular polarized light in the UV region), comprising at least one chiral liquid crystalline monomer (I) which provides a cholesteric liquid crystalline phase having a pitch of less than 450 nm, optionally mixed with at least one achiral liquid crystalline monomer of formula (II). Z1-Y1-(A1)m-Y2-M-Y4-(A2)n-Y5-Z2 (II)

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