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公开(公告)号:WO0189591A3
公开(公告)日:2002-06-13
申请号:PCT/IB0101051
申请日:2001-05-03
Applicant: BASF AG
Inventor: MITCHELL MICHAEL A , ECKERT DAVID , BEIHOFFER THOMAS W
CPC classification number: C08J3/245 , A61L15/20 , A61L15/60 , B01J20/26 , C08J2300/14
Abstract: Surface-treated superabsorbent polymer particles obtained by mixing 100 parts by weight of superabsorbent polymer particles with 0.001 to 10 parts by weight of a hydroxyalkylurea, and heating the surface-treated superabsorbent polymer particles to crosslink molecular chains existing at least in the vicinity of the surfaces of the superabsorbent polymer particles is disclosed. Surface crosslinking the superabsorbent polymer particles with a hydroxyalkylurea substantially increases both the rate of liquid absorption and the quantity of liquid absorbed and retained by the superabsorbent particles.
Abstract translation: 通过将100重量份超吸收性聚合物颗粒与0.001至10重量份的羟烷基脲混合而获得的表面处理的超吸收性聚合物颗粒,并加热表面处理的超吸收聚合物颗粒以交联至少在表面附近存在的分子链 的超吸收性聚合物颗粒。 用羟烷基脲表面交联超吸收性聚合物颗粒基本上增加了液体吸收速率和被超吸收颗粒吸收和保留的液体量。
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公开(公告)号:WO0189592A3
公开(公告)日:2002-09-19
申请号:PCT/US0116169
申请日:2001-05-17
Applicant: BASF AG , MITCHELL MICHAEL A , ECKERT DAVID , BIEHOFFER THOMAS W
Inventor: MITCHELL MICHAEL A , ECKERT DAVID , BIEHOFFER THOMAS W
IPC: A61F13/53 , A61F5/44 , A61F13/49 , A61L15/42 , A61L15/60 , C08F8/30 , C08J3/12 , C08J3/24 , C08K5/20 , C08L101/14
CPC classification number: C08J3/245 , A61L15/42 , A61L15/60 , C08F8/30 , C08J2300/14 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998
Abstract: Surface-treated superabsorbent polymer particles obtained by mixing 100 parts by weight of superabsorbent polymer particles with 0.001 to 10 parts by weight of a hydroxyalkylamide, and heating the surface-treated superabsorbent polymer particles to crosslink molecular chains existing at least in the vicinity of the surfaces of the superabsorbent polymer particles is disclosed. Surface crosslinking the superabsorbent polymer particles with a hydroxyalkylamide substantially increases both the rate of liquid absorption and the quantity of liquid absorbed and retained by the superabsorbent particles.
Abstract translation: 通过将100重量份的超吸收性聚合物颗粒与0.001至10重量份的羟烷基酰胺混合而获得的表面处理的超吸收性聚合物颗粒,并加热表面处理的超吸收聚合物颗粒以交联至少在表面附近存在的分子链 的超吸收性聚合物颗粒。 用羟基烷基酰胺表面交联超吸收性聚合物颗粒基本上增加了液体吸收速率和被超吸收颗粒吸收和保留的液体的量。
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公开(公告)号:WO0191815A3
公开(公告)日:2002-06-20
申请号:PCT/IB0101057
申请日:2001-05-03
Applicant: BASF AG
Inventor: MITCHELL MICHAEL A , ECKERT DAVID , TOMLIN ANTHONY S
IPC: A61F5/44 , A61F13/53 , A61L15/20 , A61L15/42 , A61L15/60 , C08F8/30 , C08J3/12 , C08J3/24 , C08K5/19 , C08L101/14 , B01J20/26
Abstract: Surface-crosslinked superabsorbent polymer particles are obtained by treating 100 parts by weight of superabsorbent polymer particles with about 0.001 to about 10 parts by weight of an oxazolinium ion. The oxazolinium ion can be formed in situ by heating superabsorbent particles treated with an oxazolinium ion precursor, such as a hydroxyalkylamide. A stable oxazolinium ion also can be used to surface crosslink the SAP particle. Surface crosslinking the superabsorbent polymer particles with an oxazolinium ion increases both the rate of liquid absorption and the quantity of liquid absorbed and retained by the superabsorbent particles.
Abstract translation: 通过用约0.001至约10重量份的恶唑啉离子处理100重量份的超吸收性聚合物颗粒来获得表面交联的超吸收性聚合物颗粒。 恶唑啉离子可以通过加热用恶唑啉离子前体如羟烷基酰胺处理的超吸收颗粒而原位形成。 稳定的恶唑啉离子也可用于SAP颗粒的表面交联。 超级吸收性聚合物颗粒与恶唑啉离子的表面交联增加了液体吸收的速率和吸收并被超吸收颗粒保留的液体的量。
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公开(公告)号:MX239509B
公开(公告)日:2006-08-15
申请号:MXPA02011591
申请日:2001-05-17
Applicant: BASF AG
Inventor: MITCHELL MICHAEL A , ECKERT DAVID , BIEHOFFER THOMAS W
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公开(公告)号:ZA200502353B
公开(公告)日:2006-05-31
申请号:ZA200502353
申请日:2005-03-22
Applicant: BASF AG
Inventor: HERFERT NORBERT , AZAD MICHAEL M , MITCHELL MICHAEL A , WOODRUM GUY T , CHIANG WILLIAM G-J , BROWN PATRICIA D , ROBINSON JAMES C
IPC: A61F13/53 , A61F13/15 , A61F13/49 , A61L20060101 , A61L15/60 , B01J20060101 , B01J20/12 , B01J20/26 , C08F2/44 , C08J3/00 , C08J3/12 , C08J3/20 , C08J3/21 , C08J3/215 , C08K3/34 , C08L1/00 , C08L101/14
Abstract: Superabsorbent polymer (SAP) particels containing a clay are disclosed. The clay is added to an SAP hydrogel prior to SAP neutralization to provide particles having improved fluid acquisition rates and an improved permeability of a fluid through the swollen SAP-clay particles. Diaper cores and absorbent articles containing the SAP-clay particles also are disclosed.
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公开(公告)号:ES2258741T3
公开(公告)日:2006-09-01
申请号:ES03792228
申请日:2003-07-24
Applicant: BASF AG
Inventor: HERFERT NORBERT , MITCHELL MICHAEL A , AZAD MICHAEL M , WOODRUM GUY T , CHIANG WILLIAM G-J
IPC: A61F13/53 , A61F5/44 , A61F13/15 , A61F13/49 , A61L15/60 , B01J20/12 , B01J20/26 , C08J3/12 , C08J3/24 , C08K3/34 , A61L15/18
Abstract: Partículas superabsorbentes reticuladas en sus superficies, que comprenden: (i) 50% a 88% en peso de un polímero superabsorbente, comprendiendo dicho polímero superabsorbente de 0, 001% a 5% en peso de un agente de reticulación de dichas superficies; (ii) 12% a 35% en peso de una arcilla, estando presente dicha arcilla en proximidad a las superficies de las partículas superabsorbentes; y (iii) 0% a 25% en peso de un formador inorgánico de la red, siendo preparadas dichas partículas mediante un método que comprende las etapas de: (a) polimerizar uno o más monómeros capaces de proporcionar un polímero superabsorbente en presencia de un monómero de reticulación interna para formar un hidrogel de polímero superabsorbente; (b) desmenuzar el hidrogel de polímero superabsorbente para formar partículas de hidrogel de polímero superabsorbente; (c) secar las partículas de hidrogel de polímero superabsorbente de la etapa (b) para proporcionar partículas superabsorbentes secas; (d) aplicar a la superficie de las partículas superabsorbentes de la etapa (c) una mezcla que comprende un agente de reticulación de las superficies de tales partículas y una arcilla, para proporcionar partículas de polímero superabsorbente tratadas en sus superficies; y (e) calentar entonces las partículas de polímero superabsorbentes tratadas en sus superficies durante un tiempo suficiente y a una temperatura suficiente para reticular las superficies de las partículas de polímero superabsorbente tratadas en sus superficies y situar la arcilla en proximidad a las superficies de las partículas superabsorbentes reticuladas en tales superficies.
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公开(公告)号:DE60304216D1
公开(公告)日:2006-05-11
申请号:DE60304216
申请日:2003-07-24
Applicant: BASF AG
Inventor: HERFERT NORBERT , MITCHELL MICHAEL A , AZAD MICHAEL M , WOODRUM GUY T , CHIANG WILLIAM G-J
IPC: A61F13/53 , A61L15/18 , A61F5/44 , A61F13/15 , A61F13/49 , A61L15/60 , B01J20/12 , B01J20/26 , C08J3/12 , C08J3/24 , C08K3/34
Abstract: Surface-crosslinked superabsorbent polymer (SAP) particles having a clay in the vicinity of the surfaces of the SAP particles a clay are disclosed. The clay is added to SAP particles during surface crosslinking to substantially reduce the generation, and recycling, of SAP fines, and to provide SAP particles having an improved acquisition rate of fluids and an improved permeability of a fluid through the swollen SAP particles. Diaper cores and absorbent articles containing the surface crosslinked SAP particles also are disclosed.
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公开(公告)号:AU2003250155A1
公开(公告)日:2004-03-11
申请号:AU2003250155
申请日:2003-07-24
Applicant: BASF AG
Inventor: HERFERT NORBERT , MITCHELL MICHAEL A , AZAD MICHAEL M , WOODRUM GUY T , CHIANG WILLIAM G-J
IPC: A61F13/53 , A61F5/44 , A61F13/15 , A61F13/49 , A61L15/60 , B01J20/12 , B01J20/26 , C08J3/12 , C08J3/24 , C08K3/34 , A61L15/18
Abstract: Surface-crosslinked superabsorbent polymer (SAP) particles having a clay in the vicinity of the surfaces of the SAP particles a clay are disclosed. The clay is added to SAP particles during surface crosslinking to substantially reduce the generation, and recycling, of SAP fines, and to provide SAP particles having an improved acquisition rate of fluids and an improved permeability of a fluid through the swollen SAP particles. Diaper cores and absorbent articles containing the surface crosslinked SAP particles also are disclosed.
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公开(公告)号:MXPA02011591A
公开(公告)日:2003-03-27
申请号:MXPA02011591
申请日:2001-05-17
Applicant: BASF AG
Inventor: MITCHELL MICHAEL A , ECKERT DAVID , BIEHOFFER THOMAS W
IPC: A61F13/53 , A61F5/44 , A61F13/49 , A61L15/42 , A61L15/60 , C08F8/30 , C08J3/12 , C08J3/24 , C08K5/20 , C08L101/14 , A61L15/00
Abstract: Se divulgan particulas de polimeros superabsorbentes con tratamiento superficial obtenidas mediante la mezcla de 100 partes en peso de particulas de polimeros superabsorbentes con de 0.001 a 10 partes en peso de una hidroxialquilamida, y el calentamiento de las particulas de polimeros superabsorbentes con tratamiento superficial para reticular cadenas moleculares existentes por lo menos en la cercania de las superficies de las particulas de polimeros superabsorbentes. La reticulacion superficial de las particulas de polimeros superabsorbentes con una hidroxialquilamida incrementa sustancialmente tanto la velocidad de absorcion de liquido como la cantidad de liquido absorbido y retenido por las particulas superabsorbentes.
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公开(公告)号:AU5313800A
公开(公告)日:2001-05-08
申请号:AU5313800
申请日:2000-05-31
Applicant: BASF AG
Inventor: MITCHELL MICHAEL A , BEIHOFFER THOMAS W , SPINDLER RALPH
IPC: C02F1/28 , B01J39/04 , B01J43/00 , B01J47/00 , C02F1/42 , C08G18/62 , C08G59/40 , C08K5/00 , C08L101/02
Abstract: Multicomponent ion exchange resin granules containing at least one acidic resin and at least one basic resin. Each granule contains at least one microdomain of the acidic resin in contact with, or in close proximity to, at least one microdomain of the basic resin.
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