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公开(公告)号:MXPA03007012A
公开(公告)日:2004-04-02
申请号:MXPA03007012
申请日:2002-02-06
Applicant: BASF AG
Inventor: NORBERT RIEBER
IPC: C07D301/12 , C07D301/19 , C07D301/32 , C07D303/04
Abstract: Un compuesto organico que tiene al menos un enlace doble C-C se epoxida por medio de peroxido de hidrogeno en presencia de al menos un compuesto con actividad catalitica y al menos un disolvente, en donde una mezcla de productos que contiene a-hidroperoxialcoholes se reduce utilizando al menos un agente reductor. El proceso consiste ventajosamente en al menos los siguientes pasos: (i) la reaccion de un compuesto organico que tenga al menos un doble enlace C-C con peroxido de hidrogeno en presencia de al menos un compuesto con actividad catalitica y al menos un disolvente para obtener una mezcla de productos P1 que contenga a-hidroperoxialcoholes; (ii) separar un epoxido formado en la reaccion del paso (i) y el compuesto organico sin reaccionar que tiene al menos un doble enlace C-C a partir de P1 o P1' para obtener una mezcla de productos P2 o P2', en donde P2 contiene los a-hidroperoxialcoholes formados como subproducto en la reaccion del paso (i), y P2' esta practicamente libre de a-hidroperoxialcoholes; iii) tratar P1 y/o P2 con al menos un agente reductor de modo que los a-hidroperoxialcoholes se conviertan en los glicoles correspondientes para obtener una mezcla de productos P1' o P3.
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公开(公告)号:MXPA04000782A
公开(公告)日:2004-05-21
申请号:MXPA04000782
申请日:2002-07-30
Applicant: BASF AG
Inventor: NORBERT RIEBER
IPC: C07D301/12 , C07D301/32
Abstract: Un proceso para preparar oxido de propileno comprende cuando menos los siguientes pasos: (a) se hace reaccionar propeno con peroxido de hidrogeno en un solvente en presencia de un catalizador apropiado para proporcionar una mezcla (M0) que comprende oxido de propileno, solvente, propeno no reaccionado, peroxido de hidrogeno no reaccionado y oxigeno, b) el oxido de propileno separa de la mezcla (M0) de manera de proporcionar una mezcla (M1) que comprende cuando menos propeno no reaccionado y oxigeno, y c) la mezcla de (M1) se utiliza.
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公开(公告)号:ZA200508966B
公开(公告)日:2007-04-25
申请号:ZA200508966
申请日:2005-11-07
Applicant: BASF AG
Inventor: ULRICH MUELLER , PETER BASSLER , TELES JOAQUIM H , NORBERT RIEBER
IPC: B01J20090101 , B01J8/04 , B01J8/20 , B01J19/24 , B01J29/40 , B01J29/70 , B01J29/89 , B01J35/00 , C07B20090101 , C07D20090101 , C07D301/12 , C07D301/19
Abstract: Process for the catalyzed reaction of an organic compound with a hydroperoxide in at least one reactor using at least two different zeolite catalysts, wherein at least two of the different zeolite catalysts are used physically separately from one another.
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公开(公告)号:MX243899B
公开(公告)日:2007-02-28
申请号:MXPA03007012
申请日:2002-02-06
Applicant: BASF AG
Inventor: NORBERT RIEBER
IPC: C07D301/12 , C07D301/19 , C07D301/32
Abstract: An organic compound having at least one C-C double bond is epoxidized by means of hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent, wherein a product mixture comprising alpha-hydroperoxyalcohols is reduced using at least one reducing agent. The process advantageously comprises at least the following steps: (i) reacting an organic compound having at least one C-C double bond with hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent to give a product mixture P1 comprising alpha-hydroperoxyalcohols; (ii) separating an epoxide formed in the reaction in step (i) and the unreacted organic compound having at least one C-C double bond from P1 or P1' to give a product mixture P2 or P2', where P2 comprises the alpha-hydroperoxyalcohols formed as by-product in the reaction in step (i) and P2' is largely free of alpha-hydroperoxyalcohols; (iii) treating P1 and/or P2 with at least one reducing agent so that the alpha-hydroperoxyalcohols are converted into corresponding glycols to give a product mixture P1' or P3.
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公开(公告)号:MX240869B
公开(公告)日:2006-10-09
申请号:MXPA04000099
申请日:2002-07-18
Applicant: BASF AG
Inventor: NORBERT RIEBER
IPC: C07D301/12
Abstract: A process for preparing propylene oxide comprises at least the following steps: (a) propene is reacted with a hydroperoxide in a solvent in the presence of a zeolite catalyst to give a mixture (M 0 ), where the mixture (M 0 ) comprises propylene oxide, solvent, unreacted propene, unreacted hydroperoxide and oxygen, (b) the propylene oxide is separated from the mixture (M 0 ) so as to give a mixture (M 1 ) which comprises unreacted propene and oxygen, (c) the mixture (M 1 ) is brought into contact with a liquid medium comprising at least a solvent to give the mixtures (M 2 ) and (M 3 ), where the mixture (M 3 ) comprises part of the unreacted propene and oxygen and the mixture (M 2 ) comprises solvent and residual propene, and the mixture (M 3 ) which has been separated off and comprises unreacted propene and oxygen has a ratio of oxygen to propene such that the mixture (M 3 ) is not ignitable, and the mixture (M 2 ) is fed to at least one reaction of propene with hydroperoxide.
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公开(公告)号:ZA8800955B
公开(公告)日:1989-10-25
申请号:ZA8800955
申请日:1988-02-11
Applicant: BASF AG
Inventor: WAGNER KLAUS , KLAUS WAGNER , RIEBER NORBERT , NORBERT RIEBER , POMMER ERNST-HEINRICH , ERNST-HEINRICH POMMER , DRESSEL JUERGEN , JUERGEN DRESSEL
IPC: C05G3/08 , C07D231/12 , C07D231/16 , C07D233/60 , C07D233/68 , C07D249/08 , C07D409/06 , C07D521/00 , C09K15/30 , C09K17/00 , C09K17/14 , C09K109/00 , C07D , C09K
CPC classification number: C07D231/12 , C05G3/08 , C07D231/16 , C07D233/56 , C07D233/68 , C07D249/08 , C09K15/30 , Y02P60/218 , Y10S71/902
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公开(公告)号:ZA874385B
公开(公告)日:1989-02-22
申请号:ZA874385
申请日:1987-06-18
Applicant: BASF AG
Inventor: WAGNER KLAUS , KLAUS WAGNER , RIEBER NORBERT , NORBERT RIEBER , POMMER ERNST-HEINRICH , ERNST-HEINRICH POMMER
IPC: A01N43/50 , A01N43/56 , A61K31/415 , A61P31/04 , C07D231/12 , C07D231/16 , C07D521/00 , C07D , A01N
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公开(公告)号:ZA8704385B
公开(公告)日:1989-02-22
申请号:ZA8704385
申请日:1987-06-18
Applicant: BASF AG
Inventor: WAGNER KLAUS , KLAUS WAGNER , RIEBER NORBERT , NORBERT RIEBER , POMMER ERNST-HEINRICH , ERNST-HEINRICH POMMER
IPC: A01N43/56 , A61K31/415 , A61P31/04 , C07D231/16 , C07D521/00 , C07D , A01N
CPC classification number: C07D231/12 , A01N43/56 , C07D231/16 , C07D233/56 , C07D249/08
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公开(公告)号:MX259402B
公开(公告)日:2008-08-08
申请号:MXPA04000782
申请日:2002-07-30
Applicant: BASF AG
Inventor: NORBERT RIEBER
IPC: C07D301/12 , C07D301/32
Abstract: A process for preparing propylene oxide comprises at least the following steps: (a) propene is reacted with hydrogen peroxide in a solvent in the presence of a suitable catalyst to give a mixture (M0) comprising propylene oxide, solvent, unreacted propene, unreacted hydrogen peroxide and oxygen, (b) the propylene oxide is separated off from the mixture (M0) so as to give a mixture (M1) comprising at least unreacted propene and oxygen, and (c) the mixture (M1) is utilized.
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公开(公告)号:ZA200400338B
公开(公告)日:2005-03-30
申请号:ZA200400338
申请日:2004-01-16
Applicant: BASF AG
Inventor: PETER BASSLER , NORBERT RIEBER , ALWIN REHFINGER , PETER RUDOLF , ANNE BERG , JOAQUIM HENRIQUE TELES
IPC: C07D20060101
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