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    BRANCHED POLYMERS, METHOD FOR THE PRODUCTION THEREOF, AND THEIR USE
    1.
    发明申请
    BRANCHED POLYMERS, METHOD FOR THE PRODUCTION THEREOF, AND THEIR USE 审中-公开
    支化聚合物，其生产方法及其用途

    公开(公告)号：WO0224773A2

    公开(公告)日：2002-03-28

    申请号：PCT/EP0110906

    申请日：2001-09-20

    Applicant: BASF AG ,  RAETHER ROMAN BENEDIKT ,  NUYKEN OSKAR ,  WIELAND PHILIPP

    Inventor： RAETHER ROMAN BENEDIKT ,  NUYKEN OSKAR ,  WIELAND PHILIPP

    IPC: C08F212/14 ,  C08F246/00

    CPC classification number: C08F212/14 ,  C08F246/00

    Abstract: The invention relates to a polymer that can be obtained by radically polymerizing at least one monomer of general formula (I), wherein: R represents an alkylene radical having 1 to 44 C atoms, a cycloalkylene radical having 3 to 44 C atoms, an arylene radical having 4 to 40 C atoms, an aralkylene radical having 5 to 40 C atoms or a heteroaryl radical having 4 to 40 C atoms; R , R and R , independent of one another, represent H or an alkyl radical having 1 to 10 C atoms or an aryl radical having 4 to 12 C atoms, and; Z represents a substituent having at least one thermally induced homolytically cleavable bond, whereby the thermally induced homolytic cleaving of the bond in Z occurs at a temperature ranging from - 10 DEG C to 150 DEG C. The invention also relates to a method for producing the aforementioned polymer and to the use thereof.

    Abstract translation: 本发明涉及由通式（I）的至少一种单体的自由基聚合得到的聚合物，其中R <1>是亚烷基具有1至44个碳原子，具有3至44个碳原子，具有4个的亚芳基的亚环烷基 到40个碳原子，具有5至40个碳原子或具有4至40个碳原子，R <2>，R <3>和R杂芳亚芳烷基<4>各自独立为H或烷基具有1 是10个碳原子或具有4至12个碳原子和Z的芳基是具有至少一个热诱导的均裂可剪切键，该键与Z中的一个温度，其中所述热致均裂的取代基 - 10℃至150 DEGC，其制备和使用过程。

    2.
    发明专利
    未知

    公开(公告)号：DE102005038281A1

    公开(公告)日：2007-02-22

    申请号：DE102005038281

    申请日：2005-08-12

    Applicant: BASF AG

    Inventor： RATH HANS PETER ,  WALTER HANS-MICHAEL ,  NUYKEN OSKAR ,  KUEHN FRITZ ELMAR ,  ZHANG YANMEI ,  YEONG HUI YEE

    IPC: C08F4/00 ,  C08F10/10 ,  C08F12/08

    Abstract: The invention relates to a method for polymerising ethylenically unsaturated monomers, wherein ethylenically unsaturated monomers are polymerised in the presence of a solvent-stable transition metal complex having slightly co-ordinating anions as polymer catalysts. The invention also relates to specific solvent-stable transition metal complexes having slightly co-ordinating anions. The invention also relates to highly reactive copolymers which are made of monomers comprising isobutene and at least one vinylaromatic compound which can be obtained according to said inventive method.

    3.
    发明专利
    未知

    公开(公告)号：DE10142908A1

    公开(公告)日：2003-03-20

    申请号：DE10142908

    申请日：2001-09-03

    Applicant: BASF AG

    Inventor： HEISCHKEL YVONNE ,  STOECKEL NICOLAS ,  NUYKEN OSKAR ,  JORDAN RAINER

    IPC: C08F4/00 ,  C08F4/80 ,  C08F12/00

    Abstract: The invention relates to a method for the polymerisation of a mixture containing at least one radically polymerisable monomer and a transition metal complex, the transition metal of said complex being able to reversibly bind a halogen atom. The oxidation state of the transition metal is changed from a first oxidation state to a second oxidation state, in the presence of an initiator R-Y, wherein Y represents halogen and R represents alkyl, substituted alkyl, cycloalkyl (substituted or unsubstituted), aryl or -CHnHal3-n, wherein n = between 0 and 2 and Hal = halogen, in an aqueous system. The transition metal is linked, by means of suitable active groups, to the hydrophobic part of an amphiphilic polymer consisting of a hydrophilic part and a hydrophobic part. The invention also relates to a corresponding transition metal complex, a conversion product which can be obtained according to the inventive method, and to the use of the inventive transition metal complex for producing conversion products by means of radical polymerisation.

    6.
    发明专利
    未知

    公开(公告)号：DE102005038282A1

    公开(公告)日：2007-02-22

    申请号：DE102005038282

    申请日：2005-08-12

    Applicant: BASF AG

    Inventor： RATH HANS PETER ,  WALTER HANS-MICHAEL ,  NUYKEN OSKAR ,  KUEHN FRITZ ELMAR ,  ZHANG YANMEI ,  YEONG HUI YEE

    IPC: C08F4/00 ,  C08F10/10 ,  C08F12/08

    Abstract: The invention relates to a method for producing copolymers made from isobutene and at least one vinylaromatic component. Said method consists of polymerising isobutene or a hydrocarbon mixture containing isobutene with at least one vinylaromatic compound in the presence of a solvent-stable transistion metal complex comprising slightly co-ordinating anions as a polymerisation catalyst. The invention also relates to copolymers made of isobutene and at least one vinylaromatic compound, which can be obtained by means of said inventive method, in addition to specific functionalisation products therefrom.

    7.
    发明专利
    未知

    公开(公告)号：DE10232299A1

    公开(公告)日：2004-02-05

    申请号：DE10232299

    申请日：2002-07-16

    Applicant: BASF AG

    Inventor： HEISCHKEL YVONNE ,  STOECKEL NICOLAS ,  WIELAND PHILIPP ,  SCHAEFER MARCUS ,  NUYKEN OSKAR

    IPC: C08F212/32 ,  C08F287/00 ,  C08F293/00 ,  C08F297/00 ,  C08K5/01 ,  C08L51/00 ,  C09D151/00 ,  C09J151/00 ,  C08F212/14 ,  C08F220/18 ,  C08F220/06 ,  C08F218/08 ,  C08F265/00 ,  C08F257/00

    Abstract: Production of halo- or chlorosulfonyl-functional polymers (I) comprises radical polymerization of an aromatic monomer (IIa), a halo- or chlorosulfonyl-functional monomer (IIb) and another monomer (IIc). Production of halo- or chlorosulfonyl-functional polymers (I) comprises radical polymerization of a monomer of formula (IIa), a halo- or chlorosulfonyl-functional monomer (IIb) and another monomer (IIc). R1-R4 = H or optionally substituted alkyl, cycloalkyl, aralkyl or aryl, at least two being aryl, or R1+R2 or R3+R4 is an aryl-substituted functional group having a carbon-heteroatom multiple bond conjugated with the C=C group. Independent claims are also included for: (1) polymers (I) produced as above; (2) production of graft copolymers by reacting (I) with monomers; (3) graft copolymers produced as above.

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