公开(公告)号：JP2000178280A

公开(公告)日：2000-06-27

申请号：JP26428499

申请日：1999-08-13

Applicant: BASF AG

Inventor： OKUDA JUN PROF DR ,  HULTZSCH KAI ,  GEPRAEGS MICHAEL DR

IPC: B01J31/22 ,  C07B61/00 ,  C07F5/00 ,  C07F7/08 ,  C07F17/00 ,  C08F4/14 ,  C08F4/42 ,  C08F4/52 ,  C08F20/00

Abstract: PROBLEM TO BE SOLVED: To obtain the subject complex suitable for the coordination polymerization of various monomers by reacting a mononuclear metal complex in the presence of hydrogen under a specific pressure and at a specific temperature. SOLUTION: A mononuclear metal complex expressed by formula I [M is Sc, Y, La, etc.; R is H, a halogen, a 1-20C alkyl or the like; Z is SiR'2(R' is a 1-20C alkyl or the like), O or the like; (m) is 1, 2; X is O, S or the like; L is a low molecular weight Lewis base; and (n) is 0 or l] is reacted in the presence of hydrogen, at 1.5-100 bar pressure and 0-100 deg.C temperature, preferably in an inactive solvent such as n-pentane or the likes to obtain a complex expressed by formula II, e.g. bis[tetramethylcyclopentadienyl(tert-butylamide) dimethylsilylyttrium hydride]. The side complex is useful as a catalyst for (co)polymerizing polar monomers.

公开(公告)号：JP2000178293A

公开(公告)日：2000-06-27

申请号：JP26428399

申请日：1999-08-13

Applicant: BASF AG

Inventor： OKUDA JUN PROF DR ,  HULTZSCH KAI ,  GEPRAEGS MICHAEL DR

IPC: C07F5/00 ,  C07F17/00 ,  C08F4/42 ,  C08F4/52 ,  C08F4/58

Abstract: PROBLEM TO BE SOLVED: To obtain a new semi-sandwich complex of a mononuclear bis- alkylmetal capable of obtaining a uniform high purity product in an industrial scale by coordinating and polymerizing various monomers such as a polar olefinic unsaturated monomer, lactone, etc. SOLUTION: This semi-sandwich complex of a non-cross-linked mononuclear bis-alkylmetal having a polymerization activity based on a rare earth metal, is expressed by the formula (M is scandium, yttrium, lanthanum, or lanthanide; R is H, a halogen, a 6-15 aryl or the like; R' and R" are each a 1-20C alkyl, a 3-10C cycloalkyl, a 6-15C aryl or the like; L is a low molecular weight organic compound of a Lewis base; (m) is 0-4; (n) is 0, 1), e.g. [(trimethylsilyl) cyclopentadienyl]yttrium. Further, the compound of the formula is obtained by reacting M[CH2-n(SiR"3)1+n]3(L)2 with CpR4(H)(SiR'3) in an inert solvent.

公开(公告)号：JPH1081690A

公开(公告)日：1998-03-31

申请号：JP14515597

申请日：1997-06-03

Applicant: BASF AG

Inventor： STUERMER RAINER DR ,  OKUDA JUN PROF DR ,  RITTER KURT DR

IPC: B01J31/22 ,  B01J31/24 ,  C07B53/00 ,  C07B61/00 ,  C07C7/00 ,  C07C209/52 ,  C07C211/27 ,  C07F5/00 ,  C07F5/02 ,  C07F5/06 ,  C07F7/00 ,  C07F7/28 ,  C07F9/00 ,  C07F9/6596 ,  C07F9/80 ,  C07F9/90 ,  C07F9/94 ,  C07F17/00

Abstract: PROBLEM TO BE SOLVED: To obtain the subject new compound capable of being used as a catalyst for enantiomeric selective hydrogenation by a simple method. SOLUTION: A chiral compound of formula I [M is an element selected from titanium, zirconium, hafnium, etc.; X is F, Cl, Br, I, H, a 1-10C alkyl, etc.; R -R are each H, a (1-10C alkyl-substituted) five to seven-membered cycloalkyl, etc.; R is Ge, Sn, O, S, etc.; R , R are each a 1-10C alkyl, a 6-15C aryl, etc.; (n) is a number obtained by subtracting 2 from the atomic valency of the M], e.g. a compound of formula II. The compound of formula I is obtained by reacting a suitably substituted cyclopentadienyl with compounds of the formulas: R Z2 and MXn (Z is F, Cl, Br, I) and subsequently reacting the reaction product with a compound of formula III (R is H, an alkali metal, etc.). Thereby, the active catalyst component used for enantiomeric selective hydrogenation can be obtained by the simple method.

公开(公告)号：DE19622271A1

公开(公告)日：1997-12-04

申请号：DE19622271

申请日：1996-06-03

Applicant: BASF AG

Inventor： STUERMER RAINER DR ,  OKUDA JUN PROF DR ,  RITTER KURT DR

IPC: B01J31/22 ,  B01J31/24 ,  C07B53/00 ,  C07B61/00 ,  C07C7/00 ,  C07C209/52 ,  C07C211/27 ,  C07F5/00 ,  C07F5/02 ,  C07F5/06 ,  C07F7/00 ,  C07F7/28 ,  C07F9/00 ,  C07F9/6596 ,  C07F9/80 ,  C07F9/90 ,  C07F9/94 ,  C07F17/00 ,  C07C209/00

Abstract: Chiral compounds of formula (I) are new. M = Ti, Zr, Hf, V, Nb, Ta or a lanthanide element; X = halo, H, 1-10C alkyl, 6-15C aryl, 1-10C alkyl-(6-20C)-aryl, OR or NR R ; R , R = 1-10C alkyl, 6-15C aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoroaryl with 1-10C in the alkyl group and 6-20C in the aryl group; R -R = H, 1-10C alkyl, 5-7-membered cycloalkyl optionally substituted by 1-10C alkyl, 6-15C aryl or arylalkyl, or Si(R )3; and 2 adjacent groups may form a 4-15C optionally saturated cyclic group; R = 1-10C alkyl, 3-10C cycloalkyl or 6-15C aryl; R = M )R , M )(R )-M )(R )-, M )(R )-C(R )2, C(R )(R ), OM )(R ), C(R )(R )C(R )(R ), =BR , =AlR , Ge, Sn, O, S, =SO, =SO2, =NR , =CO, =PR or =P(O)R ; R -R = H, halo, 1-10C (fluoro)alkyl, 6-10C (fluoro)aryl, 1-10C alkoxy, 2-10C alkenyl, 7-40C arylalkyl, 8-40C arylalkyl or 7-40C alkylaryl or 2 adjacent groups complete a ring; M = Si, Ge or Sn; A = B, Al, Ga, In, Tl, N, P, As, Sb or Bi; R , R = 1-10C alkyl, 6-15C aryl, 5-7-membered cycloalkyl (optionally substituted by 1-10C alkyl or groups containing heteroatoms), (CR R )mOR , (CR R )mSR or CR R ; or R +R = a 4-20C optionally saturated cyclic group, (optionally substituted by 1-10C alkyl, 6-15C aryl, heteroatoms or groups containing heteroatoms); R -R = H, 1-10C alkyl, 3-10C cycloalkyl or 6-15C aryl; R , R = 3-10C cycloalkyl, 6-15C aryl or groups containing heteroatoms; m = 1-4; n = the valency of M minus 2. Also claimed is the enantioselective hydrogenation of imines in solution, using (I) as active catalyst component.

公开(公告)号：AT228527T

公开(公告)日：2002-12-15

申请号：AT99115955

申请日：1999-08-13

Applicant: BASF AG

Inventor： OKUDA JUN PROF DR ,  HULTZSCH KAI ,  GEPRAEGS MICHAEL DR

IPC: B01J31/22 ,  C07B61/00 ,  C07F5/00 ,  C07F7/08 ,  C07F17/00 ,  C08F4/14 ,  C08F4/42 ,  C08F4/52 ,  C08F20/00

Abstract: BInuclear metal hydride complexes of scandium, yttrium, lanthanum or a lanthanoid metal are claimed. A binuclear metal hydride complex (I) is of formula (1). M = scandium, yttrium or a lanthanoid metal; R = H, halogen, 1-20C alkyl, 3-10C cycloalkyl, 6-15C aryl or 3-30C organosilyl or two neighboring R groups may form a 4-18C cyclic or heterocyclic group; Z = SiR'2, -CR'2-, -GeR'2-, -SnR'2-, -BR'- or -O-; m = 1 or 2; X = -O-, -S-, -NR''-, -PR''-, -OR''-, -SR''-, -NR''2 or -PR''2; R'' = H, 1-20C alkyl, 3-10C cycloalkyl, 6-15C aryl, 1-10C alkyl-6-10C aryl or 3-30C organosilyl; L = a low mol. wt. Lewis basic organic compound R' = 1-20C alkyl, 1-10C cycloalkyl, 6-15C aryl or 1-10C alkyl- 6-10C-aryl; Independent claims are included for: (i) a process for the preparation of (I) by reacting a mononuclear metal complex (II) of formula (2) in the presence of hydrogen at 1.5-100 bar and 0-100 degrees C; and (ii) a process for the production of (co)polymers by copolymerization of polar monomers in the presence of (I).