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1.发明专利
公开(公告)号：JP2000178280A
公开(公告)日：2000-06-27
申请号：JP26428499
申请日：1999-08-13
Applicant: BASF AG
Inventor： OKUDA JUN PROF DR , HULTZSCH KAI , GEPRAEGS MICHAEL DR
IPC: B01J31/22 , C07B61/00 , C07F5/00 , C07F7/08 , C07F17/00 , C08F4/14 , C08F4/42 , C08F4/52 , C08F20/00
Abstract: PROBLEM TO BE SOLVED: To obtain the subject complex suitable for the coordination polymerization of various monomers by reacting a mononuclear metal complex in the presence of hydrogen under a specific pressure and at a specific temperature. SOLUTION: A mononuclear metal complex expressed by formula I [M is Sc, Y, La, etc.; R is H, a halogen, a 1-20C alkyl or the like; Z is SiR'2(R' is a 1-20C alkyl or the like), O or the like; (m) is 1, 2; X is O, S or the like; L is a low molecular weight Lewis base; and (n) is 0 or l] is reacted in the presence of hydrogen, at 1.5-100 bar pressure and 0-100 deg.C temperature, preferably in an inactive solvent such as n-pentane or the likes to obtain a complex expressed by formula II, e.g. bis[tetramethylcyclopentadienyl(tert-butylamide) dimethylsilylyttrium hydride]. The side complex is useful as a catalyst for (co)polymerizing polar monomers.
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公开(公告)号：JP2000178293A
公开(公告)日：2000-06-27
申请号：JP26428399
申请日：1999-08-13
Applicant: BASF AG
Inventor： OKUDA JUN PROF DR , HULTZSCH KAI , GEPRAEGS MICHAEL DR
Abstract: PROBLEM TO BE SOLVED: To obtain a new semi-sandwich complex of a mononuclear bis- alkylmetal capable of obtaining a uniform high purity product in an industrial scale by coordinating and polymerizing various monomers such as a polar olefinic unsaturated monomer, lactone, etc. SOLUTION: This semi-sandwich complex of a non-cross-linked mononuclear bis-alkylmetal having a polymerization activity based on a rare earth metal, is expressed by the formula (M is scandium, yttrium, lanthanum, or lanthanide; R is H, a halogen, a 6-15 aryl or the like; R' and R" are each a 1-20C alkyl, a 3-10C cycloalkyl, a 6-15C aryl or the like; L is a low molecular weight organic compound of a Lewis base; (m) is 0-4; (n) is 0, 1), e.g. [(trimethylsilyl) cyclopentadienyl]yttrium. Further, the compound of the formula is obtained by reacting M[CH2-n(SiR"3)1+n]3(L)2 with CpR4(H)(SiR'3) in an inert solvent.
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Patent Agency Ranking
公开(公告)号：DE19836819A1
公开(公告)日：2000-02-17
申请号：DE19836819
申请日：1998-08-14
Applicant: BASF AG
Inventor： OKUDA JUN , HULTZSCH KAI , GEPRAEGS MICHAEL
IPC: B01J31/22 , C07B61/00 , C07F5/00 , C07F7/08 , C07F17/00 , C08F4/14 , C08F4/42 , C08F4/52 , C08F20/00 , C07F7/00 , C07F19/00
Abstract: BInuclear metal hydride complexes of scandium, yttrium, lanthanum or a lanthanoid metal are claimed. A binuclear metal hydride complex (I) is of formula (1). M = scandium, yttrium or a lanthanoid metal; R = H, halogen, 1-20C alkyl, 3-10C cycloalkyl, 6-15C aryl or 3-30C organosilyl or two neighboring R groups may form a 4-18C cyclic or heterocyclic group; Z = SiR'2, -CR'2-, -GeR'2-, -SnR'2-, -BR'- or -O-; m = 1 or 2; X = -O-, -S-, -NR''-, -PR''-, -OR''-, -SR''-, -NR''2 or -PR''2; R'' = H, 1-20C alkyl, 3-10C cycloalkyl, 6-15C aryl, 1-10C alkyl-6-10C aryl or 3-30C organosilyl; L = a low mol. wt. Lewis basic organic compound R' = 1-20C alkyl, 1-10C cycloalkyl, 6-15C aryl or 1-10C alkyl- 6-10C-aryl; Independent claims are included for: (i) a process for the preparation of (I) by reacting a mononuclear metal complex (II) of formula (2) in the presence of hydrogen at 1.5-100 bar and 0-100 degrees C; and (ii) a process for the production of (co)polymers by copolymerization of polar monomers in the presence of (I).
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公开(公告)号：ES2189321T3
公开(公告)日：2003-07-01
申请号：ES99115955
申请日：1999-08-13
Applicant: BASF AG
Inventor： OKUDA JUN PROF , HULTZSCH KAI , GEPRAGS MICHAEL
IPC: B01J31/22 , C07B61/00 , C07F5/00 , C07F7/08 , C07F17/00 , C08F4/14 , C08F4/42 , C08F4/52 , C08F20/00
Abstract: BInuclear metal hydride complexes of scandium, yttrium, lanthanum or a lanthanoid metal are claimed. A binuclear metal hydride complex (I) is of formula (1). M = scandium, yttrium or a lanthanoid metal; R = H, halogen, 1-20C alkyl, 3-10C cycloalkyl, 6-15C aryl or 3-30C organosilyl or two neighboring R groups may form a 4-18C cyclic or heterocyclic group; Z = SiR'2, -CR'2-, -GeR'2-, -SnR'2-, -BR'- or -O-; m = 1 or 2; X = -O-, -S-, -NR''-, -PR''-, -OR''-, -SR''-, -NR''2 or -PR''2; R'' = H, 1-20C alkyl, 3-10C cycloalkyl, 6-15C aryl, 1-10C alkyl-6-10C aryl or 3-30C organosilyl; L = a low mol. wt. Lewis basic organic compound R' = 1-20C alkyl, 1-10C cycloalkyl, 6-15C aryl or 1-10C alkyl- 6-10C-aryl; Independent claims are included for: (i) a process for the preparation of (I) by reacting a mononuclear metal complex (II) of formula (2) in the presence of hydrogen at 1.5-100 bar and 0-100 degrees C; and (ii) a process for the production of (co)polymers by copolymerization of polar monomers in the presence of (I).
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公开(公告)号：DE59903522D1
公开(公告)日：2003-01-09
申请号：DE59903522
申请日：1999-08-13
Applicant: BASF AG
Inventor： OKUDA PROF DR , HULTZSCH KAI , GEPRAEGS DR
IPC: B01J31/22 , C07B61/00 , C07F5/00 , C07F7/08 , C07F17/00 , C08F4/14 , C08F4/42 , C08F4/52 , C08F20/00
Abstract: BInuclear metal hydride complexes of scandium, yttrium, lanthanum or a lanthanoid metal are claimed. A binuclear metal hydride complex (I) is of formula (1). M = scandium, yttrium or a lanthanoid metal; R = H, halogen, 1-20C alkyl, 3-10C cycloalkyl, 6-15C aryl or 3-30C organosilyl or two neighboring R groups may form a 4-18C cyclic or heterocyclic group; Z = SiR'2, -CR'2-, -GeR'2-, -SnR'2-, -BR'- or -O-; m = 1 or 2; X = -O-, -S-, -NR''-, -PR''-, -OR''-, -SR''-, -NR''2 or -PR''2; R'' = H, 1-20C alkyl, 3-10C cycloalkyl, 6-15C aryl, 1-10C alkyl-6-10C aryl or 3-30C organosilyl; L = a low mol. wt. Lewis basic organic compound R' = 1-20C alkyl, 1-10C cycloalkyl, 6-15C aryl or 1-10C alkyl- 6-10C-aryl; Independent claims are included for: (i) a process for the preparation of (I) by reacting a mononuclear metal complex (II) of formula (2) in the presence of hydrogen at 1.5-100 bar and 0-100 degrees C; and (ii) a process for the production of (co)polymers by copolymerization of polar monomers in the presence of (I).
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公开(公告)号：AT228527T
公开(公告)日：2002-12-15
申请号：AT99115955
申请日：1999-08-13
Applicant: BASF AG
Inventor： OKUDA JUN PROF DR , HULTZSCH KAI , GEPRAEGS MICHAEL DR
IPC: B01J31/22 , C07B61/00 , C07F5/00 , C07F7/08 , C07F17/00 , C08F4/14 , C08F4/42 , C08F4/52 , C08F20/00
Abstract: BInuclear metal hydride complexes of scandium, yttrium, lanthanum or a lanthanoid metal are claimed. A binuclear metal hydride complex (I) is of formula (1). M = scandium, yttrium or a lanthanoid metal; R = H, halogen, 1-20C alkyl, 3-10C cycloalkyl, 6-15C aryl or 3-30C organosilyl or two neighboring R groups may form a 4-18C cyclic or heterocyclic group; Z = SiR'2, -CR'2-, -GeR'2-, -SnR'2-, -BR'- or -O-; m = 1 or 2; X = -O-, -S-, -NR''-, -PR''-, -OR''-, -SR''-, -NR''2 or -PR''2; R'' = H, 1-20C alkyl, 3-10C cycloalkyl, 6-15C aryl, 1-10C alkyl-6-10C aryl or 3-30C organosilyl; L = a low mol. wt. Lewis basic organic compound R' = 1-20C alkyl, 1-10C cycloalkyl, 6-15C aryl or 1-10C alkyl- 6-10C-aryl; Independent claims are included for: (i) a process for the preparation of (I) by reacting a mononuclear metal complex (II) of formula (2) in the presence of hydrogen at 1.5-100 bar and 0-100 degrees C; and (ii) a process for the production of (co)polymers by copolymerization of polar monomers in the presence of (I).
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