公开(公告)号：WO2008020012A2

公开(公告)日：2008-02-21

申请号：PCT/EP2007058388

申请日：2007-08-14

Applicant: BASF AG ,  PEPERS MICHEL ,  MUEHLBACH KLAUS ,  HAEHNLEIN MARC ,  SAUER MICHAEL ,  MITULLA KONRAD ,  OEPEN SABINE ,  SUWIER DAVY ROGER ,  NIESSNER NORBERT

Inventor： PEPERS MICHEL ,  MUEHLBACH KLAUS ,  HAEHNLEIN MARC ,  SAUER MICHAEL ,  MITULLA KONRAD ,  OEPEN SABINE ,  SUWIER DAVY ROGER ,  NIESSNER NORBERT

IPC: C08L25/12 ,  C08C1/07 ,  C08F6/22 ,  C08F220/12 ,  C08L55/02

CPC classification number: C08L55/02 ,  C08C1/07 ,  C08F6/22 ,  C08F279/04 ,  C08L33/08 ,  C08L2666/04 ,  C08L25/12 ,  C08L53/02

Abstract: Disclosed is a method for producing a thermoplastic ABS molding compound. According to said method, the thermoplastic copolymer A is produced from acrylonitrile and styrene by means of bulk polymerization or solution polymerization, while graft copolymer B, which is composed of a graft base (B1) and a graft shell (B2), is produced by means of emulsion polymerization using a redox initiator system, whereupon the thermoplastic copolymer A, graft copolymer B, and additional optional components K and/or additional thermoplastic polymers (TP) are mixed.

Abstract translation: 基于由本体聚合或溶液聚合的丙烯腈和苯乙烯，使用氧化还原引发剂体系通过乳液聚合构成的接枝基体，接枝共聚物B的热塑性共聚物A制备的事实生产热塑性ABS模制组合物（B1）的方法，和接枝外壳（B2 ），制造，然后将热塑性共聚物A和接枝共聚物B和，如果合适的话，另外的部件K和/或其它热塑性聚合物（TP）被混合。

公开(公告)号：WO2007017466A2

公开(公告)日：2007-02-15

申请号：PCT/EP2006065043

申请日：2006-08-03

Applicant: BASF AG ,  DUIJZINGS WIL ,  SUWIER DAVY ROGER ,  CZAUDERNA BERNHARD ,  NIESSNER NORBERT ,  SAUER MICHAEL ,  PEPERS MICHEL

Inventor： DUIJZINGS WIL ,  SUWIER DAVY ROGER ,  CZAUDERNA BERNHARD ,  NIESSNER NORBERT ,  SAUER MICHAEL ,  PEPERS MICHEL

IPC: C08F279/04 ,  C08F279/02 ,  C08L25/08 ,  C08L25/12 ,  C08L51/04 ,  C08L55/02

CPC classification number: C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08L55/02 ,  C08L2666/02

Abstract: A thermoplastic molding composition having reduced gloss sensitivity and no unpleasant odor is produced from a graft copolymer and a thermoplastic polymer. The graft copolymer is produced from a soft elastomeric particulate graft base obtained by emulsion polymerization of a conjugated diene alone or with a small amount of a mono- ethylenically unsaturated monomer, using an inorganic radical generating substance and a limited amount of chain transfer agent, upon which is grafted a vinyl aromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer using an inorganic radical generating substance while the use of a chain transfer agent is excluded. The thermoplastic polymer is a copolymer of a vinyl aromatic monomer and acrylonitrile and optionally an additional monoethylenically unsaturated monomer. The thermoplastic molding composition has a low level of unpleasant odor coupled with reduced gloss sensitivity and good mechanical properties.

Abstract translation: 由接枝共聚物和热塑性聚合物制备具有降低的光泽灵敏度和无异味的热塑性模塑组合物。 接枝共聚物由柔软的弹性体颗粒接枝基质制备，所述柔性弹性体颗粒接枝基质通过使用无机自由基产生物质和有限量的链转移剂将共轭二烯单独或与少量的单烯属不饱和单体乳液聚合而获得， 其使用无机自由基产生物质接枝乙烯基芳族单体和丙烯腈以及任选地另外的单烯属不饱和单体，同时不使用链转移剂。 热塑性聚合物是乙烯基芳族单体和丙烯腈和任选的另外的单烯属不饱和单体的共聚物。 热塑性模塑组合物具有低水平的令人不愉快的气味，同时具有降低的光泽敏感性和良好的机械性能。

公开(公告)号：DE102004019455A1

公开(公告)日：2005-11-03

申请号：DE102004019455

申请日：2004-04-19

Applicant: BASF AG

Inventor： GUENTHERBERG NORBERT ,  CZAUDERNA BERNHARD ,  SAUER MICHAEL ,  BARDON RAINER ,  HAEHNLEIN MARC ,  PEPERS MICHEL ,  MAC KEE GRAHAM EDMUND

IPC: B29B7/00 ,  C08F279/02 ,  C08F279/04 ,  C08F287/00 ,  C08J3/05 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02

Abstract: Preparation of molding materials (I) (comprising thermoplastic matrix (T) and a rubber (K1) dispersed within (T)) comprises mixing of (K1) with (T) under evaporation of processed water to form an emulsion and simultaneously removing the organic volatile components in the reaction mixture, where (K1) (added in the reaction) is formed in an emulsion without prior draining of the solid material containing fluid (mixture (M1)).