Production of alkenones
    1.
    发明授权
    Production of alkenones 失效
    生产碱

    公开(公告)号:US3819713A

    公开(公告)日:1974-06-25

    申请号:US2808070

    申请日:1970-04-13

    Applicant: BASF AG

    CPC classification number: C07C45/75 C07C45/71 C07C49/203

    Abstract: ALKENONES WHOSE OLEFINIC DOUBLE BOND IS IN THE $,E-POSITION OR Y,&-POSITION TO THE KETO GROUP, ARE PREPARED BY REACTION OF AN OLEFIN WITH A B-HYDROXYKETONE IN THE LIQUID PHASE OR IN A SINGLE REACTION STAGE BY REACTION OF AN OLEFIN WITH FORMALDEHYDE OR A COMPOUND YIELDING FORMALDEHYDE AND AN ALIPHAIC KETONE IN THE LIQUID PHASE. ALKENONES ARE INTERMEDIATES FOR THE PRODUCTION OF PERFUMES AND VITAMINS.

    Production of derivatives of omega-hydroxytiglaldehyde
    2.
    发明授权
    Production of derivatives of omega-hydroxytiglaldehyde 失效
    制备欧米茄 - 羟基甲醛的衍生物

    公开(公告)号:US3760004A

    公开(公告)日:1973-09-18

    申请号:US3760004D

    申请日:1969-09-08

    Applicant: BASF AG

    CPC classification number: C07C47/24 C07C45/515 C07C45/54 C07C45/63 C07C45/66

    Abstract: Production of 4-halogen-2-formylbutene-(2) or its lower alkyl acetals or lower fatty acid acylates by the action of certain halogenating agents on 2-formyl-2-hydroxybutene-(3) or its acetals or its acylates in the presence of tertiary amines such as trialkyl amines or N-alkyl derivatives of nitrogen containing heterocyclic compounds such as piperidine, morpholine, piperazine or similar compounds having 5 to 6 ring members.

    Abstract translation: 通过某些卤化剂在2-甲酰基-2-羟基丁烯 - (3)或其缩醛或其酰化物上的作用,生产4-卤代-2-甲酰基丁烯 - (2)或其低级烷基缩醛或低级脂肪酸酰化物 存在叔胺如三烷基胺或含氮杂环化合物如哌啶,吗啉,哌嗪或具有5至6个环成员的类似化合物的N-烷基衍生物。

    4.
    发明专利
    未知

    公开(公告)号:DK143444C

    公开(公告)日:1981-12-28

    申请号:DK432369

    申请日:1969-08-12

    Applicant: BASF AG

    Inventor: SCHUSTER L POMMER H

    Abstract: 1,268,653. Trimethylbenzoquinone. BADISCHE ANILIN- & SODA-FABRIK A.G. 12 Aug., 1969 [13 Aug., 1968], No. 40176/69. Heading C2C. Trimethyl-p-benzoquinone is prepared by reacting 2,3,6-trimethylphenol with oxygen in the presence of a cobalt complex of the formula where R 1 , R 2 , R 3 and R 4 are hydrogen or an aliphatic radical or R 2 and R 3 and the two adjacent carbon atoms form an aromatic ring and in the presence of an open or cyclic amide having two substituents other than hydrogen on the nitrogen atom as solvent.

    5.
    发明专利
    未知

    公开(公告)号:GB1258963A

    公开(公告)日:1972-01-05

    申请号:GB1258963D

    申请日:1969-03-07

    Applicant: BASF AG

    Abstract: 1,258,963. Trimethyl - 2 - cyclohexen -1 -ones. BADISCHE ANILIN- & SODA-FABRIK A.G. 7 March, 1969 [8 March, 1968; 26 July, 1968], No. 12117/69. Heading C2C. In a process for the production of a trimethyl - 2 - cyclohexen - 1 - one diethyl ketone is reacted in the presence of a basic reagent either (a) with crotonaldehyde or a compound which in the presence of a basic reagent is converted into crotonaldehyde, thereby yielding 2,5,6 - trimethyl - 2 - cyclohexen - 1 - one, or (b) with methyl vinyl ketone or a compound which in the presence of a basic reagent is converted into methyl vinyl ketone, thereby yielding 2,3,6 - trimethyl - 2 - cyclohexen- 1-one. 4 - Methyl - 3 - ethyl - 2 - cyclohexen- 1-one formed as a by-product is isomerized to 2,3,6 - trimethyl - 2 - cyclohexen - 1 - one by treatment with an aqueous base. 2,3,6 - Trimethylphenol is obtained by dehydrogenation of either 2,5,6- or 2,3,6-trimethyl-2-cyclohexen- 1-one produced by the above processes. The dehydrogenation is carried out by heating the cyclohexenones with sulphur, selenium or chloranil or in the presence of metals such as iron, cobalt, nickel, rhodium, platinum, palladium, copper and silver. Numerous compounds are specified which form crotonaldehyde or methyl vinyl ketone in the presence of a basic reagent.

    9.
    发明专利
    未知

    公开(公告)号:SE350025B

    公开(公告)日:1972-10-16

    申请号:SE375270

    申请日:1970-03-19

    Applicant: BASF AG

    Abstract: 1293041 Vitamin A palmitate BADISCHE ANILIN- & SODA-FABRIK AG 18 March 1970 [19 March 1969] 12973/70 Heading C2V Vitamin A palmitate is obtained by reacting Vitamin A alcohol with palmitoyl chloride in the presence of a tertiary amine at 40‹ to 65‹ C. in a continuous process, the reaction mixture being continuously removed and worked up after a residence time of not more than fifteen minutes. An example is given.

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