Production of alkenones
    1.
    发明授权
    Production of alkenones 失效
    生产碱

    公开(公告)号:US3819713A

    公开(公告)日:1974-06-25

    申请号:US2808070

    申请日:1970-04-13

    Applicant: BASF AG

    CPC classification number: C07C45/75 C07C45/71 C07C49/203

    Abstract: ALKENONES WHOSE OLEFINIC DOUBLE BOND IS IN THE $,E-POSITION OR Y,&-POSITION TO THE KETO GROUP, ARE PREPARED BY REACTION OF AN OLEFIN WITH A B-HYDROXYKETONE IN THE LIQUID PHASE OR IN A SINGLE REACTION STAGE BY REACTION OF AN OLEFIN WITH FORMALDEHYDE OR A COMPOUND YIELDING FORMALDEHYDE AND AN ALIPHAIC KETONE IN THE LIQUID PHASE. ALKENONES ARE INTERMEDIATES FOR THE PRODUCTION OF PERFUMES AND VITAMINS.

    Production of triaryl phosphines
    2.
    发明授权
    Production of triaryl phosphines 失效
    三氯磷酸盐的生产

    公开(公告)号:US3723536A

    公开(公告)日:1973-03-27

    申请号:US3723536D

    申请日:1971-02-09

    Applicant: BASF AG

    CPC classification number: C07F9/5068

    Abstract: The production of triaryl phosphines from phosphorus halides and aryl halides in the presence of alkali metals in a Wurtz-Fittig type reaction. In order to carry out this reaction without risk, a dispersion of an alkali metal in an organic solvent is used which has been prepared with the addition of an aryl halide or a triaryl phosphine.

    Abstract translation: 在Wurtz-Fittig型反应中,在碱金属存在下,从卤化磷和芳基卤化物制备三芳基膦。 为了没有风险地进行该反应,使用碱金属在有机溶剂中的分散体,其通过加入芳基卤化物或三芳基膦制备。

    Manufacture of isoprene
    3.
    发明授权
    Manufacture of isoprene 失效
    ISOPRENE的制造

    公开(公告)号:US3792104A

    公开(公告)日:1974-02-12

    申请号:US3792104D

    申请日:1971-06-21

    Applicant: BASF AG

    Inventor: MUELLER H

    CPC classification number: C07C1/24 C07C11/18

    Abstract: MANUFACTURE OF ISPORENE BY DEHYDRATION OF 3-METHYL-3BUTEN-1OL WITH ACIDS COMPRISING TREATING THE 3-METHYL-3BUTEN-1-OL WITH ACIDS, OR SUBSTANCES WHICH FROM ACIDS IN AQUEOUS MEDIUM, IN THE PRESENCE OF WATER AND SALTS AND, OPTIONALLY, DILUENTS. THE SAID ACID-FORMING SUBSTANCES AND SALTS ARE SELECTED SO THAT THE ANION OF THE ACID AND/OR THE ANION OF THE SALT ARE HALIDES. THE ISOPRENE PROODUCT IS ISOLATED.

    Manufacture of alpha,beta-unsaturated carbonyl compounds
    4.
    发明授权
    Manufacture of alpha,beta-unsaturated carbonyl compounds 失效
    ALPHA,BETA不饱和碳化合物的制备

    公开(公告)号:US3778477A

    公开(公告)日:1973-12-11

    申请号:US3778477D

    申请日:1971-04-21

    Applicant: BASF AG

    Inventor: MUELLER H GOETZ N

    CPC classification number: C07C45/002

    Abstract: A PROCESS FOR THE MANUFACTURE OF A,B-UNSATURATED CARBONYL COMPOUNDS BY CONTACTING THE CORRESPONDIN B,$-UNSATURATED ALCOHOLS WITH A DEHYDROGENATION CATALYST AT TEMPERATURES RANGING FROM 150* TO 600*C. THE REACTION PROCEEDS PARTICUARLY WELL WHEN CARRIED OUT IN THE PRESENCE OF CATALYTIC AMOUNTS OF CERTAIN NUCLEOPHILIC SUBSTANCES.

    Manufacture of {62 -hydroxy carbonyl compounds and/or {60 -unsaturated carbonyl compounds
    5.
    发明授权
    Manufacture of {62 -hydroxy carbonyl compounds and/or {60 -unsaturated carbonyl compounds 失效
    {62-羟基碳化合物和/或{60-碳酸化碳化合物的制备

    公开(公告)号:US3759929A

    公开(公告)日:1973-09-18

    申请号:US3759929D

    申请日:1970-11-02

    Applicant: BASF AG

    CPC classification number: C07D211/74 C07C45/74 C07C59/76 C07C49/796 C07C49/82

    Abstract: The manufacture of Beta -hydroxy carbonyl compounds and/or Alpha -unsaturated carbonyl compounds by the reaction of ketones with derivatives of glyoxylic acid and derivatives of Alpha ketoaldehydes in the absence of catalysts at a temperature below 140* C. Some of the compounds obtainable by the process of the invention are solvents and valuable starting materials for the manufacture of dyes, plastics, adhesives and varnishes.

    Abstract translation: 在低于140℃的温度下,在不存在催化剂的情况下,通过酮与乙醛酸衍生物和α-酮醛衍生物的反应制备β-羟基羰基化合物和/或α-不饱和羰基化合物。

    Manufacture of isoprene
    6.
    发明授权
    Manufacture of isoprene 失效
    ISOPRENE的制造

    公开(公告)号:US3714285A

    公开(公告)日:1973-01-30

    申请号:US3714285D

    申请日:1971-06-21

    Applicant: BASF AG

    CPC classification number: B01J27/16 C07C1/24 C07C2527/173 C07C11/18

    Abstract: Manufacture of isoprene by catalytic dehydration of 3-methyl-3buten-1-ol in the presence of inorganic acids as catalysts at elevated temperatures, wherein 3-methyl-3-buten-1-ol is passed over a pumice-supported phosphoric acid catalyst.

    Abstract translation: 在无机酸作为催化剂存在下,在高温下,通过3-甲基-3-丁烯-1-醇的催化脱水制备异戊二烯,其中3-甲基-3-丁烯-1-醇通过浮石负载的磷酸 酸催化剂。

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