7.
    发明专利
    未知

    公开(公告)号:DE1768377A1

    公开(公告)日:1972-01-13

    申请号:DE1768377

    申请日:1968-05-07

    Applicant: BASF AG

    Abstract: 1,256,172. Production of 3-ketobutanol-(1). BADISCHE ANILIN- & SODA-FABRIK A.G. 6 May, 1969 [7 May, 1968], No. 23020/69. Addition to 1,191,006. Heading C2C. 3-Ketobutanol-(l) is prepared by reacting acetone with aqueous formaldehyde solution at superatmospheric pressure at a temperature above 210‹ up to 300‹ C. The reaction is preferably conducted at 220‹ to 280‹ C. at a pressure of 30-500 atmospheres in the presence of an alkaline catalyst such as a salt of an alkali metal with a carboxylic acid. Preferably 5 to 7 moles of acetone are used per mole of formaldehyde.

    8.
    发明专利
    未知

    公开(公告)号:DE1793183B1

    公开(公告)日:1972-03-16

    申请号:DE1793183

    申请日:1968-08-13

    Applicant: BASF AG

    Abstract: 1,268,653. Trimethylbenzoquinone. BADISCHE ANILIN- & SODA-FABRIK A.G. 12 Aug., 1969 [13 Aug., 1968], No. 40176/69. Heading C2C. Trimethyl-p-benzoquinone is prepared by reacting 2,3,6-trimethylphenol with oxygen in the presence of a cobalt complex of the formula where R 1 , R 2 , R 3 and R 4 are hydrogen or an aliphatic radical or R 2 and R 3 and the two adjacent carbon atoms form an aromatic ring and in the presence of an open or cyclic amide having two substituents other than hydrogen on the nitrogen atom as solvent.

Patent Agency Ranking