公开(公告)号：DE59102591D1

公开(公告)日：1994-09-29

申请号：DE59102591

申请日：1991-02-14

Applicant: BASF AG

Inventor： RIEGER BERNHARD DR ,  BRINTZINGER HANS PROF DR ,  ROELL WERNER DR ,  REINMUTH ANNETTE ,  BARSTIES ELKE

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/626 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/642 ,  C08F4/646 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

Abstract: The present invention relates to soluble catalyst systems for the polymerization of C2- to C10-alk-l-enes, containing, as active constituents, a) a metallocene complex of the general formula I (I) where R1 and R2 are branched C4- to C10-alkyl, 5- to 7-membered cycloalkyl, which may itself be substituted by C1- to C6-alkyl, or are C6- to C15-aryl or aralkyl; R3 to R6 are C1- to C8-alkyl, M is titanium, zirconium, hafnium or vanadium, Y is silicon or germanium, and X is halogen or C1- to C8-alkyl, b) and an open-chain or cyclic aluminoxane compound of the general formula II or III where R7 is C1-C4-alkyl, and m is from 5 to 30. These catalyst systems are particularly suitable for the preparation of polypropylene and copolymers of propylene with lesser amounts of other C2- to C10-alky-l-enes.

公开(公告)号：AT110392T

公开(公告)日：1994-09-15

申请号：AT91102054

申请日：1991-02-14

Applicant: BASF AG

Inventor： RIEGER BERNHARD DR ,  BRINTZINGER HANS PROF DR ,  ROELL WERNER DR ,  REINMUTH ANNETTE ,  BARSTIES ELKE

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/626 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/642 ,  C08F4/646 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

Abstract: The present invention relates to soluble catalyst systems for the polymerization of C2- to C10-alk-l-enes, containing, as active constituents, a) a metallocene complex of the general formula I (I) where R1 and R2 are branched C4- to C10-alkyl, 5- to 7-membered cycloalkyl, which may itself be substituted by C1- to C6-alkyl, or are C6- to C15-aryl or aralkyl; R3 to R6 are C1- to C8-alkyl, M is titanium, zirconium, hafnium or vanadium, Y is silicon or germanium, and X is halogen or C1- to C8-alkyl, b) and an open-chain or cyclic aluminoxane compound of the general formula II or III where R7 is C1-C4-alkyl, and m is from 5 to 30. These catalyst systems are particularly suitable for the preparation of polypropylene and copolymers of propylene with lesser amounts of other C2- to C10-alky-l-enes.

公开(公告)号：ES2057621T3

公开(公告)日：1994-10-16

申请号：ES91102054

申请日：1991-02-14

Applicant: BASF AG

Inventor： RIEGER BERNHARD DR ,  BRINTZINGER HANS PROF DR ,  ROELL WERNER DR ,  REINMUTH ANNETTE ,  BARSTIES ELKE

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/626 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/642 ,  C08F4/646 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

Abstract: The present invention relates to soluble catalyst systems for the polymerization of C2- to C10-alk-l-enes, containing, as active constituents, a) a metallocene complex of the general formula I (I) where R1 and R2 are branched C4- to C10-alkyl, 5- to 7-membered cycloalkyl, which may itself be substituted by C1- to C6-alkyl, or are C6- to C15-aryl or aralkyl; R3 to R6 are C1- to C8-alkyl, M is titanium, zirconium, hafnium or vanadium, Y is silicon or germanium, and X is halogen or C1- to C8-alkyl, b) and an open-chain or cyclic aluminoxane compound of the general formula II or III where R7 is C1-C4-alkyl, and m is from 5 to 30. These catalyst systems are particularly suitable for the preparation of polypropylene and copolymers of propylene with lesser amounts of other C2- to C10-alky-l-enes.

公开(公告)号：DE4005947A1

公开(公告)日：1991-08-29

申请号：DE4005947

申请日：1990-02-26

Applicant: BASF AG

Inventor： RIEGER BERNHARD DR ,  BRINTZINGER HANS PROF DR ,  ROELL WERNER DR ,  REINMUTH ANNETTE ,  BARSTIES ELKE

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/626 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/642 ,  C08F4/646 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

Abstract: The present invention relates to soluble catalyst systems for the polymerization of C2- to C10-alk-l-enes, containing, as active constituents, a) a metallocene complex of the general formula I (I) where R1 and R2 are branched C4- to C10-alkyl, 5- to 7-membered cycloalkyl, which may itself be substituted by C1- to C6-alkyl, or are C6- to C15-aryl or aralkyl; R3 to R6 are C1- to C8-alkyl, M is titanium, zirconium, hafnium or vanadium, Y is silicon or germanium, and X is halogen or C1- to C8-alkyl, b) and an open-chain or cyclic aluminoxane compound of the general formula II or III where R7 is C1-C4-alkyl, and m is from 5 to 30. These catalyst systems are particularly suitable for the preparation of polypropylene and copolymers of propylene with lesser amounts of other C2- to C10-alky-l-enes.