公开(公告)号：JPH10101590A

公开(公告)日：1998-04-21

申请号：JP23200997

申请日：1997-08-28

Applicant: BASF AG

Inventor： MUELLER HANS-JOACHIM DR ,  TRUEBENBACH PETER DR ,  RIEGER BERNHARD DR ,  WAGNER JUERGEN MATTHAEUS ,  DIETRICH ULF

IPC: B01J23/42 ,  B01J27/125 ,  C07B61/00 ,  C07C2/86 ,  C07C5/52 ,  C07C13/547 ,  C07C13/553 ,  C07C17/357 ,  C07C22/08

Abstract: PROBLEM TO BE SOLVED: To make it possible to simply obtain the subject compound useful as a precursor for a polymerization catalyst without using a toxic reactant, by reacting a specific aromatic compound with a specified substituted allyl compound and then dehydrogenating the resultant compound. SOLUTION: (A) A compound represented by formula I [A is a bridge, together with the adjacent carbon, forms an aliphatic aromatic ring which may be condensed with a 6-membered (hetero)aromatic ring or other aromatic rings] is reacted with (B) a compound represented by formula II [R is a 1-10C alkyl or a (1-4C alkyl-substituted)phenyl; X is Cl, Br or I] in the presence of (C) a Friedel-Crafts catalyst such as AlCl3 to provide a compound represented by formula III, which is then dehydrogenated to afford a compound represented by formula IV. Furthermore, the reaction is carried out by using the component C in an amount so as to provide (0.1:1) to (1.5:1), advantageously (0.2:1) to (1.0:1) molar ratio of the components C:B.

公开(公告)号：ES2112873T3

公开(公告)日：1998-04-16

申请号：ES92108558

申请日：1992-05-21

Applicant: BASF AG

Inventor： SCHLUND RUEGER DR ,  RIEGER BERNHARD DR

IPC: C08F4/02 ,  C08F4/60 ,  C08F4/622 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/649 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00

Abstract: Catalyst systems for the polymerisation of C2- to C10-alk-1-enes, containing, as active constituents, a complex compound of metals from sub-groups IV and V of the Periodic Table and an oligomeric aluminoxane compound, where first the complex compound of metals from sub-group IV and V of the Periodic Table is mixed with the oligomeric aluminoxane compound, and subsequently the resultant mixture is applied to finely divided polymer. The catalyst systems according to the invention are also particularly suitable for the gas-phase polymerisation of C2- to C10-alk-1-enes and can be isolated after their preparation.

公开(公告)号：DE19634684C1

公开(公告)日：1998-03-12

申请号：DE19634684

申请日：1996-08-28

Applicant: BASF AG

Inventor： MUELLER HANS-JOACHIM DR ,  TRUEBENBACH PETER DR ,  RIEGER BERNHARD DR ,  WAGNER JUERGEN MATTHAEUS ,  DIETRICH ULF

IPC: B01J23/42 ,  B01J27/125 ,  C07B61/00 ,  C07C2/86 ,  C07C5/52 ,  C07C13/547 ,  C07C13/553 ,  C07C17/357 ,  C07C22/08 ,  C07C2/66

Abstract: The preparation of indene derivatives of formula (I) comprises reacting a benzene derivative of formula (II) with an alkenyl halide of formula (III) in the presence of a Friedel-Crafts catalyst to an indan derivative of formula (IV), followed by dehydrogenation to (I). In the formulae, R = 1-10C alkyl, phenyl or 1-4C alkyl-phenyl; A = a bridging group completing a condensed 6-membered aromatic or 5- or 6-membered heteroaromatic or aliphatic ring, optionally with another condensed aromatic ring; and X = chlorine (Cl), bromine (Br) or iodine (I).

公开(公告)号：DE19637128C1

公开(公告)日：1997-10-23

申请号：DE19637128

申请日：1996-09-12

Applicant: BASF AG

Inventor： MUELLER HANS-JOACHIM DR ,  TRUEBENBACH PETER DR ,  RIEGER BERNHARD DR ,  WAGNER JUERGEN MATTHAEUS DR ,  DIETRICH ULF

IPC: B01J27/125 ,  C07B61/00 ,  C07C45/46 ,  C07C49/675 ,  C07C49/697 ,  C07F7/08 ,  C07C49/665

Abstract: A process for the production of substituted indanones of formula (Ia) and (Ib) comprises reacting compounds of formula (IIa) or (IIb) respectively in one step with a compound of formula (III) in the presence of a Friedel-Crafts catalyst. H2C=C(C(O)X)-R (III) R -R = hydrogen, 1-4C alkyl, 1 - 4 C fluoroalkyl or 1 - 4 C alkylsilyl, or silyl, phenyl or benzyl; or R and R plus attached carbon atoms may form a benzene ring; R = 1-10C alkyl, phenyl or (1-4C alkyl)-phenyl; and X = chlorine, bromine or iodine.

公开(公告)号：ES2097833T3

公开(公告)日：1997-04-16

申请号：ES92108888

申请日：1992-05-27

Applicant: BASF AG

Inventor： KARL EBERHARD ,  ROELL WERNER DR ,  BRINTZINGER HANS PROF DR ,  RIEGER BERNHARD DR ,  STEHLING UDO

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/642 ,  C08F4/622 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/646 ,  C08F4/649 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

Abstract: Polymers of 2-10C alk-1-ene are obtd. by polymerisation at 0.1-3000 bar and -20 to 300 degrees C in the presence of a catalyst system contg.: (a) a bis-cyclopentadienyl complex of formula (I), and (b) an open-chain or cyclic aluminoxane of formulae (II) or (III). (R )2Al-Ä-O-Al(R )-Üm-R (II) M = Ti, Zr, Hf, V, Nb or Ta; X = halo or 1-8C alkyl; Y = C, P, S, Si or Ge; Z = 1-8C alkyl, 3-10C cycloalkyl or 6-10C aryl; R , R = 1-4C alkyl; R -R = H or 1-4C alkyl; or R +R or R +R may form a 4-15C hydrocarbon ring system; n = 0, 1 or 2; R = 1-4C alkyl; and m = 5-30. The following cpds. are excluded: dimethylsilyl- bis-(2-methyl indenyl)-, phenyl(methyl)silyl- bis-(2-methyl indenyl)-, diphenylsilyl- bis-(2-methyl indenyl)-, dimethylsilyl- bis-(2-ethyl indenyl)- and isopropylidene- bis-(2-methyl indenyl)- zirconium dichloride, and dimethylsilyl- and phenyl(methyl)silyl- bis-(2-methyl indenyl)- zirconium-dimethyl.

公开(公告)号：DE59208029D1

公开(公告)日：1997-03-27

申请号：DE59208029

申请日：1992-05-27

Applicant: BASF AG

Inventor： KARL EBERHARD ,  ROELL WERNER DR ,  BRINTZINGER HANS PROF DR ,  RIEGER BERNHARD DR ,  STEHLING UDO

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/642 ,  C08F4/622 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/646 ,  C08F4/649 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

Abstract: Polymers of 2-10C alk-1-ene are obtd. by polymerisation at 0.1-3000 bar and -20 to 300 degrees C in the presence of a catalyst system contg.: (a) a bis-cyclopentadienyl complex of formula (I), and (b) an open-chain or cyclic aluminoxane of formulae (II) or (III). (R )2Al-Ä-O-Al(R )-Üm-R (II) M = Ti, Zr, Hf, V, Nb or Ta; X = halo or 1-8C alkyl; Y = C, P, S, Si or Ge; Z = 1-8C alkyl, 3-10C cycloalkyl or 6-10C aryl; R , R = 1-4C alkyl; R -R = H or 1-4C alkyl; or R +R or R +R may form a 4-15C hydrocarbon ring system; n = 0, 1 or 2; R = 1-4C alkyl; and m = 5-30. The following cpds. are excluded: dimethylsilyl- bis-(2-methyl indenyl)-, phenyl(methyl)silyl- bis-(2-methyl indenyl)-, diphenylsilyl- bis-(2-methyl indenyl)-, dimethylsilyl- bis-(2-ethyl indenyl)- and isopropylidene- bis-(2-methyl indenyl)- zirconium dichloride, and dimethylsilyl- and phenyl(methyl)silyl- bis-(2-methyl indenyl)- zirconium-dimethyl.

公开(公告)号：ES2096703T3

公开(公告)日：1997-03-16

申请号：ES92119651

申请日：1992-11-19

Applicant: BASF AG

Inventor： RIEGER BERNHARD DR ,  LILGE DIETER DR ,  EVERTZ KASPAR DR ,  KONRAD RAINER DR

IPC: C08F4/622 ,  C08F4/642 ,  C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/68 ,  C08F210/02 ,  C08F210/16

公开(公告)号：DE59102591D1

公开(公告)日：1994-09-29

申请号：DE59102591

申请日：1991-02-14

Applicant: BASF AG

Inventor： RIEGER BERNHARD DR ,  BRINTZINGER HANS PROF DR ,  ROELL WERNER DR ,  REINMUTH ANNETTE ,  BARSTIES ELKE

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/626 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/642 ,  C08F4/646 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

Abstract: The present invention relates to soluble catalyst systems for the polymerization of C2- to C10-alk-l-enes, containing, as active constituents, a) a metallocene complex of the general formula I (I) where R1 and R2 are branched C4- to C10-alkyl, 5- to 7-membered cycloalkyl, which may itself be substituted by C1- to C6-alkyl, or are C6- to C15-aryl or aralkyl; R3 to R6 are C1- to C8-alkyl, M is titanium, zirconium, hafnium or vanadium, Y is silicon or germanium, and X is halogen or C1- to C8-alkyl, b) and an open-chain or cyclic aluminoxane compound of the general formula II or III where R7 is C1-C4-alkyl, and m is from 5 to 30. These catalyst systems are particularly suitable for the preparation of polypropylene and copolymers of propylene with lesser amounts of other C2- to C10-alky-l-enes.

公开(公告)号：DE4120009A1

公开(公告)日：1992-12-24

申请号：DE4120009

申请日：1991-06-18

Applicant: BASF AG

Inventor： KARL EBERHARD ,  ROELL WERNER DR ,  BRINTZINGER HANS PROF DR ,  RIEGER BERNHARD DR ,  STEHLING UDO

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/622 ,  C08F4/639 ,  C08F4/642 ,  C08F4/6392 ,  C08F4/646 ,  C08F4/649 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

Abstract: Polymers of 2-10C alk-1-ene are obtd. by polymerisation at 0.1-3000 bar and -20 to 300 degrees C in the presence of a catalyst system contg.: (a) a bis-cyclopentadienyl complex of formula (I), and (b) an open-chain or cyclic aluminoxane of formulae (II) or (III). (R )2Al-Ä-O-Al(R )-Üm-R (II) M = Ti, Zr, Hf, V, Nb or Ta; X = halo or 1-8C alkyl; Y = C, P, S, Si or Ge; Z = 1-8C alkyl, 3-10C cycloalkyl or 6-10C aryl; R , R = 1-4C alkyl; R -R = H or 1-4C alkyl; or R +R or R +R may form a 4-15C hydrocarbon ring system; n = 0, 1 or 2; R = 1-4C alkyl; and m = 5-30. The following cpds. are excluded: dimethylsilyl- bis-(2-methyl indenyl)-, phenyl(methyl)silyl- bis-(2-methyl indenyl)-, diphenylsilyl- bis-(2-methyl indenyl)-, dimethylsilyl- bis-(2-ethyl indenyl)- and isopropylidene- bis-(2-methyl indenyl)- zirconium dichloride, and dimethylsilyl- and phenyl(methyl)silyl- bis-(2-methyl indenyl)- zirconium-dimethyl.

公开(公告)号：DE19714532A1

公开(公告)日：1998-10-15

申请号：DE19714532

申请日：1997-04-08

Applicant: BASF AG

Inventor： GEPRAEGS MICHAEL DR ,  QUEISSER JOACHIM DR ,  RIEGER BERNHARD DR ,  ABU-SURRAH ADNAN S

IPC: C08F4/26 ,  C08F4/60 ,  C08F4/70 ,  C08F4/80 ,  C08F32/00 ,  C08F297/06 ,  C08F32/04 ,  C07D215/04 ,  C07D209/08

Abstract: The invention relates to the production of homopolymers, co-copolymers or block copolymers from cycloolefinic monomer units characterized in that polymerization occurs in the presence of a catalyst of general formula (I), and optionally in the presence of an additive, wherein the substituents and indices have the following meaning: M is a metal from group VIII B of the periodic table of elements; E1, E2 are independently from each other an element from group V A of the periodic table of elements; Z is a bridging structural unit; Ar stands for annelated aryl units independent of each other; L1, L2 stands for formally uncharged Lewis base ligands; X means monovalent or bivalent anions; k means 1 or 2; l, m, n represent 1 or 2, whereby m x n = 1.