Basic aluminium nitrates, sulphates or bromides prodn. - by treating aluminium salts with organic solutions of amines as liquid ion-exchangers

    公开(公告)号:DE2628988A1

    公开(公告)日:1978-01-12

    申请号:DE2628988

    申请日:1976-06-28

    Applicant: BASF AG

    Abstract: In the prodn. of basic aluminium cpds. of the formula Al2(OH)n(A)6-n.1/x (I), (where n is 1,2,3,4 or 5; A is bromide, sulphate or nitrate; and x is the valence of A), (a) an aq. soln. of aluminium bromide, sulphate or nitrate contg. is not >25 g./l. Al is treated with a is not >1.05 mol./l. soln. of an amine of mol.wt. 250-500 in a water-immiscible organic solvent; and (b) the aq. and organic phases are sepd. from each other. (I) are useful as ingredients of antiperspirant and haemostatic prepns. They can also be used for hydrophobising textiles, as tanning agents, as flocculating and phosphate-pptg. agents in water purificn., and in the prodn. of fire-resistant materials. Use of liq. ion-exchangers (i.e., organic solns. of amines) permits more rapid ion-exchange and reduces appts. costs, while the liq. ion-exchange is less sensitive towards contamination and poisoning than solid ion-exchange resins. The amt. of chemicals and wash water required for regeneration of the ion-exchanger is smaller.

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