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公开(公告)号:CA1239424A
公开(公告)日:1988-07-19
申请号:CA480861
申请日:1985-05-06
Applicant: BASF AG
Inventor: HOHENSCHUTZ HEINZ , SCHMIDT JOHANNES E , KIEFER HANS
IPC: C07C53/02 , B01J31/00 , B01J31/02 , C07B61/00 , C07C27/00 , C07C27/02 , C07C51/00 , C07C51/09 , C07C67/00 , C07C51/377
Abstract: Anhydrous or substantially anhydrous formic acid is prepared by hydrolyzing methyl formate in the presence of a formamide and then obtaining the formic acid from the hydrolysis mixture by distillation, by a method in which the hydrolysis is carried out in the presence of 0.5-3 moles, per mole of methyl formate, of a water-soluble formamide of the general formula I where R1 and R2 are each alkyl or together form an alkylene group, giving a 5-membered to 7-membered ring, with the proviso that the sum of the carbon atoms in R1 and R2 is 5 or 6 and, in the case of an alkylene group, a carbon atom which is not directly bonded to the N atom can be replaced by an oxygen atom.
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公开(公告)号:NO851895A
公开(公告)日:1985-11-15
申请号:NO851895
申请日:1985-05-13
Applicant: BASF AG
Inventor: HOHENSCHUTZ HEINZ , SCHMIDT JOHANNES E , KIEFER HANS
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公开(公告)号:CA1194030A
公开(公告)日:1985-09-24
申请号:CA421118
申请日:1983-02-08
Applicant: BASF AG
Inventor: DANZ ECKEHARD , DUEMBGEN GERD , MIESEN ERNEST , SCHMIDT JOHANNES E , WIRTH FRIEDRICH
IPC: C07D307/60 , C07C51/573 , C07D307/89
Abstract: A process for the continuous isolation of phthalic anhydride and maleic anhydride from the reaction gases obtained by catalytic oxidation of o-xylene or naphthalene with air, wherein the reaction gases are treated with a hydrocarbon of boiling range from 115 to 175.degree.C as the solvent in a column, and are then treated with an organic solvent of boiling range from 180 to 290.degree.C in a second column, the phthalic anhydride and maleic anhydride being isolated from the liquid bottom product of the first column.
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公开(公告)号:FI88027B
公开(公告)日:1992-12-15
申请号:FI851658
申请日:1985-04-26
Applicant: BASF AG
Inventor: HOHENSCHUTZ HEINZ , SCHMIDT JOHANNES E , KIEFER HANS
IPC: C07C53/02 , B01J31/00 , B01J31/02 , C07B61/00 , C07C27/00 , C07C27/02 , C07C51/00 , C07C51/09 , C07C67/00
Abstract: 1. A process for the preparation of anhydrous or substantially anhydrous formic acid by hydrolyzing methyl formate in the presence of a formamide and then obtaining the formic acid from the hydrolysis mixture by distillation, wherein the hydrolysis is carried out in the presence of 0.5-3 moles, per mole of methyl formate, of a water-soluble formamide of the formula I see diagramm : EP0161544,P5,F1 where R**1 and R**2 are each alkyl or together form an alkylene group, giving a 5-membered to 7-membered ring, with the proviso that the sum of the carbon atoms in R**1 and R**2 is 5 or 6 and that, in the case of an alkylene group, a carbon atom which is not directly bonded to the N atom can be replaced by an oxygen atom.
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公开(公告)号:FI851658L
公开(公告)日:1985-11-15
申请号:FI851658
申请日:1985-04-26
Applicant: BASF AG
Inventor: HOHENSCHUTZ HEINZ , SCHMIDT JOHANNES E , KIEFER HANS
IPC: C07C53/02 , B01J31/00 , B01J31/02 , C07B61/00 , C07C27/00 , C07C27/02 , C07C51/00 , C07C51/09 , C07C67/00 , C07C
Abstract: 1. A process for the preparation of anhydrous or substantially anhydrous formic acid by hydrolyzing methyl formate in the presence of a formamide and then obtaining the formic acid from the hydrolysis mixture by distillation, wherein the hydrolysis is carried out in the presence of 0.5-3 moles, per mole of methyl formate, of a water-soluble formamide of the formula I see diagramm : EP0161544,P5,F1 where R**1 and R**2 are each alkyl or together form an alkylene group, giving a 5-membered to 7-membered ring, with the proviso that the sum of the carbon atoms in R**1 and R**2 is 5 or 6 and that, in the case of an alkylene group, a carbon atom which is not directly bonded to the N atom can be replaced by an oxygen atom.
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公开(公告)号:NO148711B
公开(公告)日:1983-08-22
申请号:NO783298
申请日:1978-09-28
Applicant: BASF AG
Inventor: HOHENSCHUTZ HEINZ , SCHMIDT JOHANNES E , KIEFER HANS
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公开(公告)号:CA1062647A
公开(公告)日:1979-09-18
申请号:CA262623
申请日:1976-10-04
Applicant: BASF AG
Inventor: BUELOW HORST , HOHENSCHUTZ HEINZ , SCHMIDT JOHANNES E , SACHSZE WERNER
Abstract: Formic acid is purified by extractive distillation of its aqueous solutions using a basic extractant, followed by distillation of the bottom mixture first obtained, the extractant used being N-formylmorpholine.
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公开(公告)号:LT2268B
公开(公告)日:1993-12-15
申请号:LTRP775
申请日:1993-07-09
Applicant: BASF AG
Inventor: HOHENSCHUTZ HEINZ , SCHMIDT JOHANNES E , KIEFER HANS
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公开(公告)号:NO851895L
公开(公告)日:1985-11-15
申请号:NO851895
申请日:1985-05-13
Applicant: BASF AG
Inventor: HOHENSCHUTZ HEINZ , SCHMIDT JOHANNES E , KIEFER HANS
IPC: B01J31/00 , C07C53/02 , B01J31/02 , C07B61/00 , C07C27/00 , C07C27/02 , C07C51/00 , C07C51/09 , C07C67/00 , C07C
Abstract: 1. A process for the preparation of anhydrous or substantially anhydrous formic acid by hydrolyzing methyl formate in the presence of a formamide and then obtaining the formic acid from the hydrolysis mixture by distillation, wherein the hydrolysis is carried out in the presence of 0.5-3 moles, per mole of methyl formate, of a water-soluble formamide of the formula I see diagramm : EP0161544,P5,F1 where R**1 and R**2 are each alkyl or together form an alkylene group, giving a 5-membered to 7-membered ring, with the proviso that the sum of the carbon atoms in R**1 and R**2 is 5 or 6 and that, in the case of an alkylene group, a carbon atom which is not directly bonded to the N atom can be replaced by an oxygen atom.
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公开(公告)号:NO148068C
公开(公告)日:1983-08-03
申请号:NO763447
申请日:1976-10-08
Applicant: BASF AG
Inventor: HOHENSCHUTZ HEINZ , SCHMIDT JOHANNES E , KIEFER HANS
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