6.
    发明专利
    未知

    公开(公告)号:DE2813873A1

    公开(公告)日:1979-10-11

    申请号:DE2813873

    申请日:1978-03-31

    Applicant: BASF AG

    Abstract: A process for the preparation of substituted oxazolidine-2,4-diones by treating a corresponding carbamate with a 2-hydroxycarboxylic acid ester at from 80 DEG to 250 DEG C.

    8.
    发明专利
    未知

    公开(公告)号:DE2650232A1

    公开(公告)日:1978-05-11

    申请号:DE2650232

    申请日:1976-11-02

    Applicant: BASF AG

    Abstract: Amines of the formula Ar-NH-CH2-R, where Ar is unsubstituted or substituted phenyl and R is alkyl of 3 to 6 carbon atoms substituted by hydroxyl groups, are manufactured by catalytic hydrogenation of a salt of an acid of the formula R-COOH in the presence of (a) a compound of the formula Ar-Z, where Z is a nitro or reduced nitro group, and a strong acid or (b) a salt of an amine of the formula Ar-NH2 and a strong acid, in an organic solvent.

    (N-3,4)-dimethylphenyl-D-ribamine prodn. - by catalytic hydrogenation of e.g. D-ribonic acid (3,4)-dimethyl anilide

    公开(公告)号:DE2558515A1

    公开(公告)日:1977-06-30

    申请号:DE2558515

    申请日:1975-12-24

    Applicant: BASF AG

    Abstract: Prepn. of N-(3,4-dimethylphenyl)-D-ribamine of formula (I): comprises catalytic hydrogenation in inert solvent at 100-155 degrees C of either (a) a mixt. of 3, -dimethylaniline and/or 3,4-dinitrobenzene and a D-ribonic deriv. (II) (where R' is H or one R' together with R" forms a bond; R" is OH or R'"-O-, or forms a bond with one R'; R'" is 1-10C hydrocarbyl opt. substd. by OH) or (b) D-ribonic acid 3,4-dimethylanilide (III) (I; -C(O)- is -CH2-). (I) is an intermediate to vitamin B2. Process gives good yields, of pure (I) more simply, and economically than prior processes. Pref. catalyst contains Cu and/or CuO. (II) is pref. D-ribonic acid gamma-lactone.

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