公开(公告)号：US6410778B2

公开(公告)日：2002-06-25

申请号：US6836198

申请日：1998-05-07

Applicant: BASF AG

Inventor： LAQUA GERHARD ,  SCHONER ULRICH ,  OTTERBACH ANDREAS ,  SCHWARZ HANS VOLKMAR

IPC: B01J31/04 ,  B01J31/12 ,  B01J31/20 ,  C07B61/00 ,  C07C263/04 ,  C07C265/14 ,  C07C269/04 ,  C07C271/08 ,  C07C271/20 ,  C07C269/00

CPC classification number: C07C269/04

Abstract: Organic diurethanes and/or polyurethanes are prepared by reacting organic diamines and/or polyamines (a) with urea and/or alkyl cabamates (b) and alcohols (c) in the presence of soluble zirconium compounds, preferably zirconium alkoxides, zirconium acetate or zirconium acetylacetonate, as catalyst (d). They can be used for preparing diisocyanates and/or polyisocyanates by thermal dissociation.

Abstract translation: 有机二胺和/或聚氨酯通过有机二胺和/或多胺（a）与可溶性锆化合物，优选锆醇锆，乙酸锆或锆的存在下，与脲和/或烷基氯化物（b）和醇（c）反应来制备 乙酰丙酮化物作为催化剂（d）。 它们可用于通过热离解制备二异氰酸酯和/或多异氰酸酯。

公开(公告)号：MX9803613A

公开(公告)日：1998-09-30

申请号：MX9803613

申请日：1998-05-07

Applicant: BASF AG

Inventor： LAQUA GERHARD ,  SCHONER ULRICH ,  OTTERBACH ANDREAS ,  SCHWARZ HANS VOLKMAR

IPC: B01J31/04 ,  B01J31/12 ,  B01J31/20 ,  C07B61/00 ,  C07C263/04 ,  C07C265/14 ,  C07C269/04 ,  C07C271/08 ,  C07C271/20

Abstract: La invencion se refiere a un método para producir di-orgánico y/o poliuretano mediante la reaccion del di-orgánico y/o poliaminas (a) con urea y/o esteres de alquilo de ácido carbámico (b) y alcoholes (c) en la presencia de los compuestos de zirconia soluble, de preferencia los alcoholes de zirconia, acetato de zirconia y acetilaceto-nato de zirconia, como un catalizador (d). La invencion también se refiere al uso de estos componentes en la produccion del di y/o poliisocianatos mediante la descomposicion térmica.

公开(公告)号：DE59607733D1

公开(公告)日：2001-10-25

申请号：DE59607733

申请日：1996-10-30

Applicant: BASF AG

Inventor： LAQUA GERHARD ,  SCHONER ULRICH ,  OTTERBACH ANDREAS ,  SCHWARZ VOLKMAR

IPC: B01J31/04 ,  B01J31/12 ,  B01J31/20 ,  C07B61/00 ,  C07C263/04 ,  C07C265/14 ,  C07C269/04 ,  C07C271/08 ,  C07C271/20

Abstract: Organic diurethanes and/or polyurethanes are prepared by reacting organic diamines and/or polyamines (a) with urea and/or alkyl cabamates (b) and alcohols (c) in the presence of soluble zirconium compounds, preferably zirconium alkoxides, zirconium acetate or zirconium acetylacetonate, as catalyst (d). They can be used for preparing diisocyanates and/or polyisocyanates by thermal dissociation.

公开(公告)号：DE19627552A1

公开(公告)日：1998-01-15

申请号：DE19627552

申请日：1996-07-09

Applicant: BASF AG

Inventor： LAQUA GERHARD DR ,  SCHONER ULRICH ,  STROEFER ECKHARD DR ,  OTTERBACH ANDREAS DR ,  PFEFFINGER JOACHIM

IPC: C07C263/04 ,  C08G18/72 ,  C07C265/14 ,  C07C263/06 ,  C07C263/18

Abstract: The novel feature in the preparation of organic polyisocyanates by reaction of polyamines with carbamate esters and/or urea together with an alcohol to give urethane monomer which is then thermally dissociated to alcohol and polyisocyanate and distillatively separated is that the high-boiling sump fraction thus obtained is thermally dissociated with an alcohol to recover monomeric urethane which is then recycled to the dissociation stage.

公开(公告)号：ES2164263T3

公开(公告)日：2002-02-16

申请号：ES96937292

申请日：1996-10-30

Applicant: BASF AG

Inventor： LAQUA GERHARD ,  SCHONER ULRICH ,  OTTERBACH ANDREAS ,  SCHWARZ HANS VOLKMAR

IPC: B01J31/04 ,  B01J31/12 ,  B01J31/20 ,  C07B61/00 ,  C07C263/04 ,  C07C265/14 ,  C07C269/04 ,  C07C271/08 ,  C07C271/20

Abstract: Organic diurethanes and/or polyurethanes are prepared by reacting organic diamines and/or polyamines (a) with urea and/or alkyl cabamates (b) and alcohols (c) in the presence of soluble zirconium compounds, preferably zirconium alkoxides, zirconium acetate or zirconium acetylacetonate, as catalyst (d). They can be used for preparing diisocyanates and/or polyisocyanates by thermal dissociation.

公开(公告)号：DE19541384A1

公开(公告)日：1997-05-15

申请号：DE19541384

申请日：1995-11-07

Applicant: BASF AG

Inventor： LAQUA GERHARD DR ,  SCHONER ULRICH ,  OTTERBACH ANDREAS DR ,  SCHWARZ HANS VOLKMAR DR

IPC: B01J31/04 ,  B01J31/12 ,  B01J31/20 ,  C07B61/00 ,  C07C263/04 ,  C07C265/14 ,  C07C269/04 ,  C07C271/08 ,  C07C271/20 ,  C07C271/24 ,  C07C271/06

Abstract: The invention concerns a method of producing organic di- and/or polyurethanes by reacting organic di- and/or polyamines (a) with urea and/or carbamic acid alkyl esters (b) and alcohols (c) in the presence of soluble zirconium compounds, preferably zirconium alcoholates, zirconium acetate or zirconium actylacetonate, as a catalyst (d). The invention also concerns the use of such compounds in the production of di- and/or polyisocyanates by thermal decomposition.

公开(公告)号：AT205826T

公开(公告)日：2001-10-15

申请号：AT96937292

申请日：1996-10-30

Applicant: BASF AG

Inventor： LAQUA GERHARD ,  SCHONER ULRICH ,  OTTERBACH ANDREAS ,  SCHWARZ HANS VOLKMAR

IPC: B01J31/04 ,  B01J31/12 ,  B01J31/20 ,  C07B61/00 ,  C07C263/04 ,  C07C265/14 ,  C07C269/04 ,  C07C271/08 ,  C07C271/20

Abstract: Organic diurethanes and/or polyurethanes are prepared by reacting organic diamines and/or polyamines (a) with urea and/or alkyl cabamates (b) and alcohols (c) in the presence of soluble zirconium compounds, preferably zirconium alkoxides, zirconium acetate or zirconium acetylacetonate, as catalyst (d). They can be used for preparing diisocyanates and/or polyisocyanates by thermal dissociation.

公开(公告)号：CA2235328A1

公开(公告)日：1997-05-15

申请号：CA2235328

申请日：1996-10-30

Applicant: BASF AG

Inventor： SCHWARZ HANS VOLKMAR ,  OTTERBACH ANDREAS ,  SCHONER ULRICH ,  LAQUA GERHARD

IPC: B01J31/04 ,  B01J31/12 ,  B01J31/20 ,  C07B61/00 ,  C07C263/04 ,  C07C265/14 ,  C07C269/04 ,  C07C271/08 ,  C07C271/20

Abstract: The invention concerns a method of producing organic di- and/or polyurethanes by reacting organic di- and/or polyamines (a) with urea and/or carbamic acid alkyl esters (b) and alcohols (c) in the presence of soluble zirconium compounds, preferably zirconium alcoholates, zirconium acetate or zirconium actylacetonate, as a catalyst (d). The invention also concerns the use of such compounds in the production of di- and/or polyisocyanates by thermal decomposition.

公开(公告)号：PT861232E

公开(公告)日：2002-03-28

申请号：PT96937292

申请日：1996-10-30

Applicant: BASF AG

Inventor： OTTERBACH ANDREAS ,  HANS VOLKMAR SCHWARZ DR ,  GERHARD LAQUA DR ,  SCHONER ULRICH

IPC: B01J31/04 ,  B01J31/12 ,  B01J31/20 ,  C07B61/00 ,  C07C263/04 ,  C07C265/14 ,  C07C269/04 ,  C07C271/08 ,  C07C271/20

Abstract: Organic diurethanes and/or polyurethanes are prepared by reacting organic diamines and/or polyamines (a) with urea and/or alkyl cabamates (b) and alcohols (c) in the presence of soluble zirconium compounds, preferably zirconium alkoxides, zirconium acetate or zirconium acetylacetonate, as catalyst (d). They can be used for preparing diisocyanates and/or polyisocyanates by thermal dissociation.