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公开(公告)号:WO03043712A8
公开(公告)日:2003-08-07
申请号:PCT/EP0213084
申请日:2002-11-21
Applicant: BASF AG , THIEL JOACHIM , SCHROEDER JUERGEN
Inventor: THIEL JOACHIM , SCHROEDER JUERGEN
Abstract: The invention relates to a column for the thermal treatment of mixtures containing at least one polymerisable compound. Said column comprises dual flow plates which are provided with openings, the diameter of each opening being constant inside a dual flow plate. The diameter of the openings of said dual flow plates decreases as the distance of the plates from the inlet of the mixture to be treated increases.
Abstract translation: 存在对包含一种或多种可聚合化合物的混合物,提出了双流塔板增加有开口,其直径为双流塔板,其中所述双流塔盘与内是恒定的热处理的柱 与待处理混合物入口的距离具有直径逐渐减小的开口。
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公开(公告)号:WO0107392A9
公开(公告)日:2003-04-03
申请号:PCT/EP0007199
申请日:2000-07-26
Applicant: BASF AG , AUER HEINZ , DAHLHAUS JUERGEN , FISCHER KARL , HAMMER HANS , KELLENBENZ JOCHEN , SCHULZ MICHAEL , THIEL JOACHIM , VICARI MAXIMILIAN
Inventor: AUER HEINZ , DAHLHAUS JUERGEN , FISCHER KARL , HAMMER HANS , KELLENBENZ JOCHEN , SCHULZ MICHAEL , THIEL JOACHIM , VICARI MAXIMILIAN
IPC: B01D3/00 , B01J3/00 , B01J3/02 , B01J19/00 , C07B61/00 , C07C29/80 , C07C31/04 , C07C67/36 , C07C69/06
Abstract: The invention relates to a method of producing methyl formiate by reacting excess methanol with carbon monoxide under increased pressure and increased temperature in the presence of an alkalimethylate or alkaline earth methylate as the catalyst in a pressure-proof reactor. The inventive method uses at least two reactor elements, preferably countercurrent reactors, at a temperature of approximately 100 DEG C and a pressure of approximately 100 bar in combination with a solid-matter free desalination of the reactor product. The inventive method provides a means for producing methyl formiate of any quality desired and with an excellent production capacity in a very economical and complication-free manner. The invention further relates to a method of solid-matter free desalination and to devices for carrying out the inventive method.
Abstract translation: 公开了一种用于由过量的甲醇与下在碱金属或碱土金属甲醇盐如在耐压反应器催化剂的存在超大气压力和升高的温度下一氧化碳反应,制备甲酸甲酯的方法,其中操作通过使用至少两个,优选在逆流反应器元件 温度至100℃,并在组合100巴的以任何所需质量非常经济的,无故障的主要生产甲酸甲酯和具有很好的生产能力成为可能的反应器的无固体的脱盐的压力。 此外,描述了用于执行该方法的无固体的脱盐和装置的过程。
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公开(公告)号:NO327885B1
公开(公告)日:2009-10-12
申请号:NO20020349
申请日:2002-01-23
Applicant: BASF AG
Inventor: AUER HEINZ , DAHLHAUS JUERGEN , FISCHER KARL , HAMMER HANS , KELLENBENZ JOCHEN , SCHULZ MICHAEL , THIEL JOACHIM , VICARI MAXIMILIAN
IPC: B01D3/00 , B01J3/00 , C07C67/36 , B01J3/02 , B01J19/00 , C07B61/00 , C07C29/80 , C07C31/04 , C07C69/06
Abstract: A description is given of a process for preparing methyl formate by reacting excess methanol with carbon monoxide under superatmospheric pressure and at elevated temperature in the presence of alkali metal methoxide or alkaline earth metal methoxide as catalyst in a pressure-rated reactor, in which the use of at least two reactor elements, preferably operated in countercurrent, at about 100° C. and a pressure of about 100 bar in combination with a solids-free desalting of the reaction product makes possible very economical, largely trouble-free production of methyl formate in any desired quality and with a very good production capacity. Furthermore, the process for solids-free desalting and apparatuses for carrying out this process are described.
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公开(公告)号:BRPI0412503A
公开(公告)日:2006-09-19
申请号:BRPI0412503
申请日:2004-07-09
Applicant: BASF AG
Inventor: ECK BERND , HAMMON ULRICH , MUELLER-ENGEL KLAUS JOACHIM , DER JUERGEN SCHR , THIEL JOACHIM , MARTAN HANS
Abstract: A thermal separating process for removing a stream containing enriched (meth)acrylic monomers from a mixture containing (meth)acrylic monomers, in which the liquid phases retained in the separating space at high temperature and high (meth)acrylic monomer content are minimized.
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公开(公告)号:BR0317583A
公开(公告)日:2005-11-22
申请号:BR0317583
申请日:2003-12-24
Applicant: BASF AG
Inventor: THIEL JOACHIM , DAMS ALBRECHT , SCHROEDER JUERGEN
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公开(公告)号:BR0314992A
公开(公告)日:2005-08-09
申请号:BR0314992
申请日:2003-10-06
Applicant: BASF AG
Inventor: THIEL JOACHIM , HAMMON ULRICH , BAUMANN DIETER , HEILEK JOERG , SCHROEDER JUERGEN , MUELLER-ENGEL KLAUS JOACHIM
Abstract: In a process for preparing acrylic acid, an acrylic acid-containing product gas mixture obtained by catalytic gas phase partial oxidation of a C 3 precursor of acrylic acid, after direct cooling with a quench liquid, is fractionally condensed in a separating column provided with internals, rising into itself with sidestream takeoff of crude acrylic acid, and the acrylic acid oligomers which form are dissociated and the resulting dissociation gas is subjected to a countercurrent rectification before it is recycled.
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公开(公告)号:DE10295317D2
公开(公告)日:2004-09-09
申请号:DE10295317
申请日:2002-11-21
Applicant: BASF AG
Inventor: THIEL JOACHIM , SCHROEDER JUERGEN
Abstract: A column for the thermal treatment of a mixture has dual-flow stages with openings having a constant diameter within a dual-flow stage. The dual-flow stages at an increasing distance from the addition point of the gases to be treated have openings of decreasing diameter. An Independent claim is also included for the thermal treatment of a mixture comprising at least one polymerizable compound in the column.
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公开(公告)号:DE10139588A1
公开(公告)日:2003-02-27
申请号:DE10139588
申请日:2001-08-11
Applicant: BASF AG
Inventor: BECHTEL MARCUS , THIEL JOACHIM
IPC: B01D3/00 , B01D3/20 , C07C303/44 , C07C309/04 , C07C303/02
Abstract: Glass apparatus to gather and distribute fluid in a column (1) has a gutter system (2) with blades (3) to collect the fluid, and a central tube (4) as an outflow for the fluid. The glass distributor (5) has several distribution gutters with fused glass tube(s) that project over the base of the gutters. Glass apparatus to gather and distribute fluid in a column (1) has a gutter system (2) with blades (3) to collect the fluid, and a central tube (4) as an outflow for the fluid. The glass distributor (5) has several distribution gutters with fused glass tube(s) that project over the base of the gutters, with a side opening for the fluid to flow into them with a drilling diameter of .
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公开(公告)号:DE10115277A1
公开(公告)日:2002-06-13
申请号:DE10115277
申请日:2001-03-28
Applicant: BASF AG
Inventor: MACHHAMMER OTTO , ADAMI CHRISTOPH , HECHLER CLAUS , SCHROEDER JUERGEN , SCHLIEPHAKE VOLKER , THIEL JOACHIM , DIEHL VOLKER
Abstract: The continuous recovery of (meth)acrylic acid (I) from a reaction gas (II), obtained by catalytic gas phase oxidation, includes quenching (II) by vapor cooling with a high-boiling solvent (III), separating (I) by absorption in (III), and separating the (I)-containing (III) by rectification into a first partial stream (PS1) containing mainly (I) and a second partial stream (PS2) containing mainly (III). The continuous recovery of (meth)acrylic acid (I) from a reaction gas (II), obtained by catalytic gas phase oxidation, comprises: (i) quenching (II) by vapor cooling with a high-boiling solvent (III), (ii) separating (I) by absorption in (III), (iii) separating the (I)-containing (III) into a first partial stream (PS1) containing mainly (I) and a second partial stream (PS2) containing mainly (III), (iv) recycling PS2 to step (ii) and (v) recovering (I) from PS1 by distillation and recycling liquid residual streams to step (i), Step (iii) is carried out by rectification.
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公开(公告)号:DE19924532A1
公开(公告)日:2000-11-30
申请号:DE19924532
申请日:1999-05-28
Applicant: BASF AG
Inventor: THIEL JOACHIM , SCHROEDER JUERGEN , NESTLER GERHARD
Abstract: A separating or rectifying column has both dual-flow- and hydraulically-sealed crossflow-plates. An Independent claim is also included for a process using such a column in fractionally condensing an acrylic acid-containing gas mixture obtained by heterogeneously-catalyzed, gas phase partial oxidation of C3 precursors of acrylic acid with molecular oxygen (see also WO200053560).
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