公开(公告)号：DE2729031A1

公开(公告)日：1979-01-18

申请号：DE2729031

申请日：1977-06-28

Applicant: BASF AG

Inventor： MERGER FRANZ DIPL CHEM DR ,  TOWAE FRIEDRICH DIPL CHEM DR ,  SCHROFF LUDWIG DIPL CHEM DR

IPC: C07C47/575 ,  C07C201/12 ,  C07C205/37 ,  C07C43/20 ,  C07C41/00 ,  C07C49/84 ,  C07C79/35

Abstract: Prepn. of aralkyl- and alkyl-phenol-ethers having formula (R1 is H, OH or -OR2, or both R1 gps. together with 2 adjacent C atoms of the benzene ring can form an aromatic gp.; R2 is an araliphatic or aliphatic gp.; R3 is an aliphatic, araliphatic or aromatic gp., H, halogen, -CN, -NO2, R4COO-, R4S- or R4O-; R4 is an aliphatic or aromatic gp.) comprises reacting phenols having formula (II) (where R5 is R1 or also OH if R1 is -OR2) with diaralkyl-carbonates or dialkyl-carbonates having formula (III) O = C(OR2)2 (III) in the presence of a tert. amine and/or tert. phosphine, above 100 degrees C. (I) are starting materials for the prepn. of dyes, plant protective agents and perfumes. Pure (I) are obtd. in high yields. Separation and neutralisation steps and corrosion problems are prevented. By-prods. are 1 mol alcohol and non-toxic O2. The alcohol can be re-converted to dialkyl carbonate or diaralkyl carbonate by reaction with CO and O2.

公开(公告)号：DE2526644A1

公开(公告)日：1976-12-30

申请号：DE2526644

申请日：1975-06-14

Applicant: BASF AG

Inventor： MERGER FRANZ DIPL CHEM DR ,  STROHMEYER MAX DIPL CHEM DR ,  SANDROCK GERHARD DIPL CHEM DR ,  HOHENSCHUTZ HEINZ DIPL CHEM DR ,  SCHROFF LUDWIG DIPL CHEM DR ,  NESTLER GERHARD DIPL CHEM DR

IPC: C07C27/00 ,  C07C37/14 ,  C07C67/00 ,  C07C39/06

公开(公告)号：DE2807762A1

公开(公告)日：1979-09-06

申请号：DE2807762

申请日：1978-02-23

Applicant: BASF AG

Inventor： MERGER FRANZ DIPL CHEM DR ,  TOWAE FRIEDRICH DIPL CHEM DR ,  SCHROFF LUDWIG DIPL CHEM DR

IPC: C07C47/575 ,  C07C201/12 ,  C07C205/37 ,  C07C43/20 ,  C07C49/175

Abstract: Prepn. of aralkyl- and alkyl-phenol-ethers having formula (R1 is H, OH or -OR2, or both R1 gps. together with 2 adjacent C atoms of the benzene ring can form an aromatic gp.; R2 is an araliphatic or aliphatic gp.; R3 is an aliphatic, araliphatic or aromatic gp., H, halogen, -CN, -NO2, R4COO-, R4S- or R4O-; R4 is an aliphatic or aromatic gp.) comprises reacting phenols having formula (II) (where R5 is R1 or also OH if R1 is -OR2) with diaralkyl-carbonates or dialkyl-carbonates having formula (III) O = C(OR2)2 (III) in the presence of a tert. amine and/or tert. phosphine, above 100 degrees C. (I) are starting materials for the prepn. of dyes, plant protective agents and perfumes. Pure (I) are obtd. in high yields. Separation and neutralisation steps and corrosion problems are prevented. By-prods. are 1 mol alcohol and non-toxic O2. The alcohol can be re-converted to dialkyl carbonate or diaralkyl carbonate by reaction with CO and O2.

公开(公告)号：DE2618033A1

公开(公告)日：1977-11-10

申请号：DE2618033

申请日：1976-04-24

Applicant: BASF AG

Inventor： MERGER FRANZ DIPL CHEM DR ,  SCHROFF LUDWIG DIPL CHEM DR

IPC: B01J27/00 ,  C07C67/00 ,  C07C209/00 ,  C07C209/18 ,  C07C209/22 ,  C07C211/48 ,  C07C213/00 ,  C07C213/02 ,  C07C227/00 ,  C07C227/18 ,  C07C229/54 ,  C07C87/62 ,  C07C85/08