High viscosity, curable, non-tacky vinyl ester (urethane) resin moulding materials

    公开(公告)号:DE4406646A1

    公开(公告)日:1995-09-07

    申请号:DE4406646

    申请日:1994-03-01

    Applicant: BASF AG

    Abstract: Curable, thickened moulding materials, contain the following components: (A) 100 pts.wt. vinyl ester (urethane) resin; (B) 0-80 pts.wt. unsatd. polyester resin compatible with (A); (C) 0.1-25 pts.wt. thickening agent; (D) 0.1-10 pts.wt. basic metal cpd. thickener; (E) 0.01-5 pts.wt. polymerisation initiator that breaks up into radicals above 50 deg.C; (F) 0-400 pts.wt. reinforcing fibres and/or fillers; and (G) opt. additional additives. (C) comprises a hemiester of an polyether polyol (mixt.) of formula (Ca) and a dicarboxylic acid anhydride; A(-R-O)x-OHy (Ca) A = polyol or polyamine with 3-6 functional gps.; R = 2-4C alkylenyl; x = 1-100; and y = 3-6. Also claimed are (i) the prepn. of the materials by mixing components (A),(B),(C),(E),(F) and (G), adding (D) at a temp. less than 50 deg C to commence thickening and opt. applying the runny material to reinforcing fibres, and then terminating thickening opt. by heating, and (ii) use of the materials for the prepn. of shaped articles by (injection) press moulding, injection moulding or deep drawing and then curing at temps. greater than 50 (80-200) deg C.

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